Search Results

Now showing 1 - 3 of 3
  • Item
    Topology- and Geometry-Controlled Functionalization of Nanostructured Metamaterials
    (Basel : MDPI, 2023) Fomin, Vladimir M.; Marquardt, Oliver
    [no abstract available]
  • Item
    Entropy Determination of Single-Phase High Entropy Alloys with Different Crystal Structures over a Wide Temperature Range
    (Basel : MDPI, 2018-8-30) Haas, Sebastian; Mosbacher, Mike; Senkov, Oleg N; Feuerbacher, Michael; Freudenberger, Jens; Gezgin, Senol; Völkl, Rainer; Glatzel, Uwe
    We determined the entropy of high entropy alloys by investigating single-crystalline nickel and five high entropy alloys: two fcc-alloys, two bcc-alloys and one hcp-alloy. Since the configurational entropy of these single-phase alloys differs from alloys using a base element, it is important to quantify the entropy. Using differential scanning calorimetry, cp-measurements are carried out from −170 °C to the materials’ solidus temperatures TS. From these experiments, we determined the thermal entropy and compared it to the configurational entropy for each of the studied alloys. We applied the rule of mixture to predict molar heat capacities of the alloys at room temperature, which were in good agreement with the Dulong-Petit law. The molar heat capacity of the studied alloys was about three times the universal gas constant, hence the thermal entropy was the major contribution to total entropy. The configurational entropy, due to the chemical composition and number of components, contributes less on the absolute scale. Thermal entropy has approximately equal values for all alloys tested by DSC, while the crystal structure shows a small effect in their order. Finally, the contributions of entropy and enthalpy to the Gibbs free energy was calculated and examined and it was found that the stabilization of the solid solution phase in high entropy alloys was mostly caused by increased configurational entropy.
  • Item
    Environment-Assisted Invariance Does Not Necessitate Born’s Rule for Quantum Measurement
    (Basel : MDPI, 2023) Mertens, Lotte; van Wezel, Jasper
    The argument of environment-assisted invariance (known as envariance) implying Born’s rule is widely used in models for quantum measurement to reason that they must yield the correct statistics, specifically for linear models. However, it has recently been shown that linear collapse models can never give rise to Born’s rule. Here, we address this apparent contradiction and point out an inconsistency in the assumptions underlying the arguments based on envariance. We use a construction in which the role of the measurement machine is made explicit and shows that the presence of envariance does not imply that every measurement will behave according to Born’s rule. Rather, it implies that every quantum state allows a measurement machine to be constructed, which yields Born’s rule when measuring that particular state. This resolves the paradox and is in agreement with the recent result of objective collapse models necessarily being nonlinear.