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    Observing Mesospheric Turbulence with Specular Meteor Radars: a novel Method for Estimating Second-Order Statistics of Wind Velocity
    (Malden, Mass. : American Geophysical Union, 2019) Vierinen, J.; Chau, J.L.; Charuvil, H.; Urco, J.M.; Clahsen, M.; Avsarkisov, V.; Marino, R.; Volz, R.
    There are few observational techniques for measuring the distribution of kinetic energy within the mesosphere with a wide range of spatial and temporal scales. This study describes a method for estimating the three-dimensional mesospheric wind field correlation function from specular meteor trail echoes. Each radar echo provides a measurement of a one-dimensional projection of the wind velocity vector at a randomly sampled point in space and time. The method relies on using pairs of such measurements to estimate the correlation function of the wind with different spatial and temporal lags. The method is demonstrated using a multistatic meteor radar data set that includes ≈105 meteor echoes observed during a 24-hr time period. The new method is found to be in good agreement with the well-established technique for estimating horizontal mean winds. High-resolution correlation functions with temporal, horizontal, and vertical lags are also estimated from the data. The temporal correlation function is used to retrieve the kinetic energy spectrum, which includes the semidiurnal mode and a 3-hr period wave. The horizontal and vertical correlation functions of the wind are then used to derive second-order structure functions, which are found to be compatible with the Kolmogorov prediction for spectral distribution of kinetic energy in the turbulent inertial range. The presented method can be used to extend the capabilities of specular meteor radars. It is relatively flexible and has a multitude of applications beyond what has been shown in this study.
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    Ultrafast vibrational dynamics of the DNA backbone at different hydration levels mapped by two-dimensional infrared spectroscopy
    (Melville, NY : AIP Publishing LLC, 2015) Guchhait, Biswajit; Liu, Yingliang; Siebert, Torsten; Elsaesser, Thomas
    DNA oligomers are studied at 0% and 92% relative humidity, corresponding to N < 2 and N > 20 water molecules per base pair. Two-dimensional (2D) infrared spectroscopy of DNA backbone modes between 920 and 1120 cm(-1) maps fluctuating interactions at the DNA surface. At both hydration levels, a frequency fluctuation correlation function with a 300 fs decay and a slow decay beyond 10 ps is derived from the 2D lineshapes. The fast component reflects motions of DNA helix, counterions, and water shell. Its higher amplitude at high hydration level reveals a significant contribution of water to the fluctuating forces. The slow component reflects disorder-induced inhomogeneous broadening.