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- ItemRound robin comparison on quantitative nanometer scale magnetic field measurements by magnetic force microscopy(Amsterdam : Elsevier B.V., 2020) Hu, X.; Dai, G.; Sievers, S.; Fernández-Scarioni, A.; Corte-León, H.; Puttock, R.; Barton, C.; Kazakova, O.; Ulvr, M.; Klapetek, P.; Havlíček, M.; Nečas, D.; Tang, Y.; Neu, V.; Schumacher, H.W.Magnetic force microscopy (MFM) can be considered as a standard tool for nano-scale investigation of magnetic domain structures by probing the local stray magnetic field landscape of the measured sample. However, this generally provides only qualitative data. To quantify the stray magnetic fields, the MFM system must be calibrated. To that end, a transfer function (TF) approach was proposed, that, unlike point probe models, fully considers the finite extent of the MFM tip. However, albeit being comprehensive, the TF approach is not yet well established, mainly due to the ambiguities concerning the input parameters and the measurement procedure. Additionally, the calibration process represents an ill-posed problem which requires a regularization that introduces further parameters. In this paper we propose a guideline for quantitative stray field measurements by standard MFM tools in ambient conditions. All steps of the measurement and calibration procedure are detailed, including reference sample and sample under test (SUT) measurements and the data analysis. The suitability of the reference sample used in the present work for calibrated measurements on a sub-micron scale is discussed. A specific regularization approach based on a Pseudo-Wiener Filter is applied and combined with criteria for the numerical determination of a unique regularization parameter. To demonstrate the robustness of such a defined approach, a round robin comparison of magnetic field measurements was conducted by four laboratories. The guideline, the reference sample and the results of the round robin are discussed.
- ItemStructural properties of magnetic nanoparticles determine their heating behavior - an estimation of the in vivo heating potential(New York, NY [u.a.] : Springer, 2014) Ludwig, R.; Stapf, M.; Dutz, S.; Müller, R.; Teichgräber, U.; Hilger, I.Magnetically induced heating of magnetic nanoparticles (MNP) in an alternating magnetic field (AMF) is a promising minimally invasive tool for localized tumor treatment by sensitizing or killing tumor cells with the help of thermal stress. Therefore, the selection of MNP exhibiting a sufficient heating capacity (specific absorption rate, SAR) to achieve satisfactory temperatures in vivo is necessary. Up to now, the SAR of MNP is mainly determined using ferrofluidic suspensions and may distinctly differ from the SAR in vivo due to immobilization of MNP in tissues and cells. The aim of our investigations was to study the correlation between the SAR and the degree of MNP immobilization in dependence of their physicochemical features.In this study, the included MNP exhibited varying physicochemical properties and were either made up of single cores or multicores. Whereas the single core MNP exhibited a core size of approximately 15 nm, the multicore MNP consisted of multiple smaller single cores (5 to 15 nm) with 65 to 175 nm diameter in total. Furthermore, different MNP coatings, including dimercaptosuccinic acid (DMSA), polyacrylic acid (PAA), polyethylenglycol (PEG), and starch, wereinvestigated. SAR values were determined after the suspension of MNP in water. MNP immobilization in tissues was simulated with 1% agarose gels and 10% polyvinyl alcohol (PVA) hydrogels.The highest SAR values were observed in ferrofluidic suspensions, whereas a strong reduction of the SAR after the immobilization of MNP with PVA was found. Generally, PVA embedment led to a higher immobilization of MNP compared to immobilization in agarose gels. The investigated single core MNP exhibited higher SAR values than the multicore MNP of the same core size within the used magnetic field parameters. Multicore MNP manufactured via different synthesis routes (fluidMAG-D, fluidMAG/12-D) showed different SAR although they exhibited comparable core and hydrodynamic sizes. Additionally, no correlation between ζ-potential and SAR values after immobilization was observed.Our data show that immobilization of MNP, independent of their physicochemical properties, can distinctly affect their SAR. Similar processes are supposed to take place in vivo, particularly when MNP are immobilized in cells and tissues. This aspect should be adequately considered when determining the SAR of MNP for magnetic hyperthermia.
- ItemHolographic vector field electron tomography of three-dimensional nanomagnets(London : Nature Publishing Group, 2019) Wolf, D.; Biziere, N.; Sturm, S.; Reyes, D.; Wade, T.; Niermann, T.; Krehl, J.; Warot-Fonrose, B.; Büchner, B.; Snoeck, E.; Gatel, C.; Lubk, A.Complex 3D magnetic textures in nanomagnets exhibit rich physical properties, e.g., in their dynamic interaction with external fields and currents, and play an increasing role for current technological challenges such as energy-efficient memory devices. To study these magnetic nanostructures including their dependency on geometry, composition, and crystallinity, a 3D characterization of the magnetic field with nanometer spatial resolution is indispensable. Here we show how holographic vector field electron tomography can reconstruct all three components of magnetic induction as well as the electrostatic potential of a Co/Cu nanowire with sub 10 nm spatial resolution. We address the workflow from acquisition, via image alignment to holographic and tomographic reconstruction. Combining the obtained tomographic data with micromagnetic considerations, we derive local key magnetic characteristics, such as magnetization current or exchange stiffness, and demonstrate how magnetization configurations, such as vortex states in the Co-disks, depend on small structural variations of the as-grown nanowire.
- ItemSingle-crystalline FeCo nanoparticle-filled carbon nanotubes: Synthesis, structural characterization and magnetic properties(Frankfurt am Main : Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2018) Ghunaim, R.; Scholz, M.; Damm, C.; Rellinghaus, B.; Klingeler, R.; Büchner, B.; Mertig, M.; Hampel, S.In the present work, we demonstrate different synthesis procedures for filling carbon nanotubes (CNTs) with equimolar binary nanoparticles of the type Fe-Co. The CNTs act as templates for the encapsulation of magnetic nanoparticles and provide a protective shield against oxidation as well as prevent nanoparticle agglomeration. By variation of the reaction parameters, we were able to tailor the sample purity, degree of filling, the composition and size of the filling particles, and therefore, the magnetic properties. The samples were analyzed by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), superconducting quantum interference device (SQUID) and thermogravimetric analysis (TGA). The Fe-Co-filled CNTs show significant enhancement in the coercive field as compared to the corresponding bulk material, which make them excellent candidates for several applications such as magnetic storage devices.
- ItemMagnetoelectricity induced by rippling of magnetic nanomembranes and wires(College Park, MD : APS, 2023) Ortix, Carmine; van den Brink, JeroenMagnetoelectric crystals have the interesting property that they allow electric fields to induce magnetic polarizations, and vice versa, magnetic fields to generate ferroelectric polarizations. Having such a magnetoelectric coupling usually requires complex types of magnetic textures, e.g., of spiraling type. Here, we establish a previously unknown approach to generate linear magnetoelectric coupling in ferromagnetic insulators with intrinsic Dzyaloshinskii-Moriya interaction (DMI). We show that the effect of nanoscale curved geometries combined with the intrinsic DMI of the magnetic shell lead to a reorganization of the magnetic texture that spontaneously breaks inversion symmetry and thereby induces macroscopic magnetoelectric multipoles. Specifically, we prove that structural deformation in the form of controlled ripples activates a magnetoelectric monopole in the recently synthesized two-dimensional magnets. We also demonstrate that in zigzag-shaped ferromagnetic wires in planar architectures, a magnetic toroidal moment triggers direct linear magnetoelectric coupling.