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- ItemThe second ACTRIS inter-comparison (2016) for Aerosol Chemical Speciation Monitors (ACSM): Calibration protocols and instrument performance evaluations(Philadelphia, Pa.: Taylor & Francis, 2019) Freney, Evelyn; Zhang, Yunjiang; Croteau, Philip; Amodeo, Tanguy; Williams, Leah; Truong, François; Petit, Jean-Eudes; Sciare, Jean; Sarda-Esteve, Roland; Bonnaire, Nicolas; Arumae, Tarvo; Aurela, Minna; Bougiatioti, Aikaterini; Mihalopoulos, Nikolaos; Coz, Esther; Artinano, Begoña; Crenn, Vincent; Elste, Thomas; Heikkinen, Liine; Poulain, Laurent; Wiedensohler, Alfred; Herrmann, Hartmut; Priestman, Max; Alastuey, Andres; Stavroulas, Iasonas; Tobler, Anna; Vasilescu, Jeni; Zanca, Nicola; Canagaratna, Manjula; Carbone, Claudio; Flentje, Harald; Green, David; Maasikmets, Marek; Marmureanu, Luminita; Cruz Minguillon, Maria; Prevot, Andre S.H.; Gros, Valerie; Jayne, John; Favez, OlivierThis work describes results obtained from the 2016 Aerosol Chemical Speciation Monitor (ACSM) intercomparison exercise performed at the Aerosol Chemical Monitor Calibration Center (ACMCC, France). Fifteen quadrupole ACSMs (Q_ACSM) from the European Research Infrastructure for the observation of Aerosols, Clouds and Trace gases (ACTRIS) network were calibrated using a new procedure that acquires calibration data under the same operating conditions as those used during sampling and hence gets information representative of instrument performance. The new calibration procedure notably resulted in a decrease in the spread of the measured sulfate mass concentrations, improving the reproducibility of inorganic species measurements between ACSMs as well as the consistency with co-located independent instruments. Tested calibration procedures also allowed for the investigation of artifacts in individual instruments, such as the overestimation of m/z 44 from organic aerosol. This effect was quantified by the m/z (mass-to-charge) 44 to nitrate ratio measured during ammonium nitrate calibrations, with values ranging from 0.03 to 0.26, showing that it can be significant for some instruments. The fragmentation table correction previously proposed to account for this artifact was applied to the measurements acquired during this study. For some instruments (those with high artifacts), this fragmentation table adjustment led to an “overcorrection” of the f44 (m/z 44/Org) signal. This correction based on measurements made with pure NH4NO3, assumes that the magnitude of the artifact is independent of chemical composition. Using data acquired at different NH4NO3 mixing ratios (from solutions of NH4NO3 and (NH4)2SO4) we observe that the magnitude of the artifact varies as a function of composition. Here we applied an updated correction, dependent on the ambient NO3 mass fraction, which resulted in an improved agreement in organic signal among instruments. This work illustrates the benefits of integrating new calibration procedures and artifact corrections, but also highlights the benefits of these intercomparison exercises to continue to improve our knowledge of how these instruments operate, and assist us in interpreting atmospheric chemistry. © 2019, © 2019 Author(s). Published with license by Taylor & Francis Group, LLC.
- ItemFirst in situ measurement of the vertical distribution of ice volume in a mesospheric ice cloud during the ECOMA/MASS rocket-campaign(München : European Geopyhsical Union, 2009) Rapp, M.; Strelnikova, I.; Strelnikov, B.; Latteck, R.; Baumgarten, G.; Li, Q.; Megner, L.; Gumbel, J.; Friedrich, M.; Hoppe, U.-P.; Robertson, S.We present in situ observations of mesospheric ice particles with a new particle detector which combines a classical Faraday cup with the active photoionization of particles and subsequent detection of photoelectrons. Our observations of charged particles and free electrons within a decaying PMSE-layer reveal that the presence of charged particles is a necessary but not sufficient condition for the presence of PMSE. That is, additional requirements like a sufficiently large electron density – which we here estimate to be on the order of ~100 cm−3 – and the presence of small scale structures (commonly assumed to be caused by turbulence) need to be satisfied. Our photoelectron measurements reveal a very strong horizontal structuring of the investigated ice layer, i.e., a very broad layer (82–88 km) seen on the upleg is replaced by a narrow layer from 84.5–86 km only 50 km apart on the downleg of the rocket flight. Importantly, the qualitative structure of these photoelectron profiles is in remarkable qualitative agreement with photometer measurements on the same rocket thus demonstrating the reliability of this new technique. We then show that the photoelectron currents are a unique function of the ice particle volume density (and hence ice mass) within an uncertainty of only 15% and we derive corresponding altitude profiles of ice volume densities. Derived values are in the range ~2–8×10−14 cm3/cm3 (corresponding to mass densities of ~20–80 ng/m3, and water vapor mixing ratios of 3–12 ppm) and are the first such estimates with the unique spatial resolution of an in situ measurement.
- ItemEarthCARE Aerosol and Cloud Layer and Column Products(Les Ulis : EDP Sciences, 2018) Wandinger, Ulla; Hünerbein, Anja; Horn, Stefan; Schneider, Florian; Donovan, David; van Zadelhoff, Gerd-Jan; Daou, David; Docter, Nicole; Fischer, Jürgen; Filipitsch, Florian; Nicolae, D.; Makoto, A.; Vassilis, A.; Balis, D.; Behrendt, A.; Comeron, A.; Gibert, F.; Landulfo, E.; McCormick, M.P.; Senff, C.; Veselovskii, I.; Wandinger, U.We introduce the development of EarthCARE Level 2 layer products derived from profile measurements of the high-spectral-resolution lidar ATLID and column products obtained from combined information of ATLID and the Multi-Spectral Imager (MSI). Layer products include cloud top height as well as aerosol layer boundaries and mean optical properties along the satellite nadir track. Synergistic column products comprise cloud top height, Ångström exponent, and aerosol type both along-track and across the MSI swath.