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DDC: 530 × Subject: high energy density ×

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    Recovery of release cloud from laser shock-loaded graphite and hydrocarbon targets: in search of diamonds
    (Bristol : IOP Publ., 2022) Schuster, A.K.; Voigt, K.; Klemmed, B.; Hartley, N.J.; Lütgert, J.; Zhang, M.; Bähtz, C.; Benad, A.; Brabetz, C.; Cowan, T.; Döppner, T.; Erb, D.J.; Eychmüller, A.; Facsko, S.; Falcone, R.W.; Fletcher, L.B.; Frydrych, S.; Ganzenmüller, G.C.; Gericke, D.O.; Glenzer, S.H.; Grenzer, J.; Helbig, U.; Hiermaier, S.; Hübner, R.; Laso Garcia, A.; Lee, H.J.; MacDonald, M.J.; McBride, E.E.; Neumayer, P.; Pak, A.; Pelka, A.; Prencipe, I.; Prosvetov, A.; Rack, A.; Ravasio, A.; Redmer, R.; Reemts, D.; Rödel, M.; Schoelmerich, M.; Schumacher, D.; Tomut, M.; Turner, S.J.; Saunders, A.M.; Sun, P.; Vorberger, J.; Zettl, A.; Kraus, D.
    This work presents first insights into the dynamics of free-surface release clouds from dynamically compressed polystyrene and pyrolytic graphite at pressures up to 200 GPa, where they transform into diamond or lonsdaleite, respectively. These ejecta clouds are released into either vacuum or various types of catcher systems, and are monitored with high-speed recordings (frame rates up to 10 MHz). Molecular dynamics simulations are used to give insights to the rate of diamond preservation throughout the free expansion and the catcher impact process, highlighting the challenges of diamond retrieval. Raman spectroscopy data show graphitic signatures on a catcher plate confirming that the shock-compressed PS is transformed. First electron microscopy analyses of solid catcher plates yield an outstanding number of different spherical-like objects in the size range between ten(s) up to hundreds of nanometres, which are one type of two potential diamond candidates identified. The origin of some objects can unambiguously be assigned, while the history of others remains speculative.
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    Comparative Study of Onion-like Carbons Prepared from Different Synthesis Routes towards Li-Ion Capacitor Application
    (Basel : MDPI, 2022) Permana, Antonius Dimas Chandra; Ding, Ling; Gonzalez-Martinez, Ignacio Guillermo; Hantusch, Martin; Nielsch, Kornelius; Mikhailova, Daria; Omar, Ahmad
    Li-ion capacitors (LIC) have emerged as a promising hybrid energy storage system in response to increasing energy demands. However, to achieve excellent LIC performance at high rates, along with cycling stability, an alternative anode to graphite is needed. Porous high-surface-area carbons, such as onion-like carbons (OLCs), have been recently found to hold high potential as high-rate-capable LIC anodes. However, a systematic understanding of their synthesis route and morphology is lacking. In this study, OLCs prepared from self-made metal organic frameworks (MOFs) Fe-BTC and Fe-MIL100 by a simple pyrolysis method were compared to OLCs obtained via high-temperature annealing of nanodiamonds. The LICs with OLCs produced from Fe-BTC achieved a maximum energy density of 243 Wh kg−1 and a power density of 20,149 W kg−1. Furthermore, excellent capacitance retention of 78% after 10,000 cycles was demonstrated. LICs with MOF-derived OLCs surpassed the energy and power density of LICs with nanodiamond-derived OLCs. We determined the impact of the MOF precursor structure and morphology on the resulting OLC properties, as well as on the electrochemical performance. Thus, MOF-derived OLCs offer significant potential toward high-performance anode material for LICs, enabling control over structure and morphology, as well as easy scalability for industrial implementation.