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DDC: 530 × Subject: ion ×

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    Single molecule magnet with an unpaired electron trapped between two lanthanide ions inside a fullerene
    (London : Nature Publishing Group, 2017) Liu, F.; Krylov, D.S.; Spree, L.; Avdoshenko, S.M.; Samoylova, N.A.; Rosenkranz, M.; Kostanyan, A.; Greber, T.; Wolter, A.U.B.; Büchner, B.; Popov, A.A.
    Increasing the temperature at which molecules behave as single-molecule magnets is a serious challenge in molecular magnetism. One of the ways to address this problem is to create the molecules with strongly coupled lanthanide ions. In this work, endohedral metallofullerenes Y 2 @C 80 and Dy 2 @C 80 are obtained in the form of air-stable benzyl monoadducts. Both feature an unpaired electron trapped between metal ions, thus forming a single-electron metal-metal bond. Giant exchange interactions between lanthanide ions and the unpaired electron result in single-molecule magnetism of Dy 2 @C 80 (CH 2 Ph) with a record-high 100 s blocking temperature of 18 K. All magnetic moments in Dy 2 @C 80 (CH 2 Ph) are parallel and couple ferromagnetically to form a single spin unit of 21 μ B with a dysprosium-electron exchange constant of 32 cm -1. The barrier of the magnetization reversal of 613 K is assigned to the state in which the spin of one Dy centre is flipped.
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    Ion dynamics in electron beam-plasma interaction: Particle-in-cell simulations
    (Göttingen : Copernicus, 2014) Baumgärtel, K.
    Electron beam-plasma interaction including ions is studied by particle-in-cell (PIC) simulations using a one-dimensional, electrostatic code. Evidence for Langmuir wave decay is given for sufficiently energetic beams, as in previous Vlasov-Maxwell simulations. The mechanism for the generation of localized finite-amplitude ion density fluctuations is analyzed. Amplitude modulation due to interference between the beam-generated Langmuir waves causes random wave localization including strong transient spikes in field intensity which create bursty ion density structures via ponderomotive forces. More dense beams may quench the decay instability and generate low-frequency variations dominated by the wave number of the fastest growing Langmuir mode.