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- ItemCrystal structure of (2S,4S,7S)-7,7-dichloro-4-(1-chloro-1-methylethyl)-1- (2,2,2-trichloroethyl)bicyclo[4.1.0]heptane, C12H16Cl 6(Berlin : de Gruyter, 2009) Boualy, B.; el Firdoussi, L.; Ali, M.A.; Karim, A.; Spannenberg, A.C12H16Cl6, orthorhombic, P2 12121 (no. 19), a = 6.0742(3) Å, b = 9.7189(6) Å, c = 26.700(1) Å, V = 1576.2 Å3, Z = 4, Rgt(F) = 0.019, wRref(F2) = 0.045, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
- ItemNickel-Catalyzed Carbonylative Synthesis of Functionalized Alkyl Iodides(Amsterdam : Elsevier B.V., 2018) Peng, J.-B.; Wu, F.-P.; Xu, C.; Qi, X.; Ying, J.; Wu, X.-F.Chemistry; Catalysis; Organic Synthesis © 2018 The Author(s)Functionalized alkyl iodides are important compounds in organic chemistry and biology. In this communication, we developed an interesting nickel-catalyzed carbonylative synthesis of functionalized alkyl iodides from aryl iodides and ethers. With Mo(CO)6 as the solid CO source, both cyclic and acyclic ethers were activated, which is also a challenging topic in organic synthesis. Functionalized alkyl iodides were prepared in moderate to excellent yields with outstanding functional group tolerance. Besides the high value of the obtained products, all the atoms from the starting materials were incorporated in the final products and the reaction had high atom efficiency as well.
- ItemCrystal structure of rac-[1, 2-ethylene-bis(η5-4, 5, 6, 7-tetrahydroindenyl)]1-hafna-4, 5-bis(trimethylsilyl)furan-3-one- tris(pentafluorophenyl)borane, (C20H24)Hf(Me 3SiC2SiMe3CO2)B(C6F 5)3(Berlin : de Gruyter, 2009) Beweries, T.; Burlakov, V.V.; Rosenthal, U.; Spannenberg, A.C47H42BF15HfO2Si2, monoclinic, P121/n1 (no. 14), a = 15.7496(4) Å = 20.4074(5) Å= 16.3115(5) Å, β = 96.313(2)°, V= 5210.9 Å3, Z = 4, Rgt(F) = 0.027, WRref(F 2) = 0.049, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
- ItemCrystal structure of (η4-cycloocta-1,5-dien)-N-(2- (diphenylphosphinooxy)-3-(naphthalen-1-yloxy)propyl)-N-(pentan-3-yl)-1, 1-diphenylphosphinamine-rhodium(I) tetrafluoroborate, [Rh(C8H 12)(C42H43NO2P2)][BF 4](Berlin : de Gruyter, 2007) Dai, Z.; Heller, D.; Preetz, A.; Drexler, H.-J.C50H55BF4NO2P2Rh, monoclinic, P1211 (no. 4), a = 12.722(3) Å, b = 15.248(3) Å, c = 12.818(3) Å, β = 115.80(3)°, V = 2238.7 Å3, Z = 2, Rgt(F) = 0.036, wRref(F 2) = 0.079, T = 200 K. © by Oldenbourg Wissenschaftsverlag.
- ItemCrystal structure of η5-3,6-di-tert-butyl-4- (tris(pentafluorophenyl)boranyloxycarbonyl)-5-(η5- tetramethylcyclopentadienyl-methyl-9,10,11-trimethyl-bicyclo(6.3.0) undeca-4-en-8,10-dienyl)titanium(III) toluene hemisolvate, Ti(C 51H47BF15O2) · 0.5C 7H8(Berlin : de Gruyter, 2008) Spannenberg, A.; Burlakov, V.V.; Rosenthal, U.C54.50H51BF15O2Ti, triclinic, P1̄ (no. 2), a = 11.603(2) Å, b = 12.872(3) Å, c = 18.142(4) Å, α = 76.47(3)°, β = 77.99(3)°, γ = 69.13(3)°, V = 2438.2 Å5, Z = 2, Rgt(F) = 0.048, wRobs(F2) = 0.114, T = 200 K. © by Oldenbourg Wissenchaftsverlag.
- ItemCrystal structure of (2,3-bis((2R,5R)-2,5-dimethylphosphonalyl)maleic anhydride)-(η4-norbornadiene)-rhodium(I) tetrafluoroborate, [Rh(C7H8)(C16H24O3P 2)] [BF4](Berlin : de Gruyter, 2007) Holz, J.; Börner, A.; Heller, D.; Drexler, H.-J.C23H32BF4O3P2Rh, orthorhombic, P212121 (no. 19), a = 10.147(2) Å, b = 13.246(3) Å, c = 18.827(4) Å, V = 2530.5 Å3, Z = 4, Rgt(F) = 0.025, wRref(F 2) = 0.067, T = 200 K. © by Oldenbourg Wissenschaftsverlag,.
- ItemCrystal structure of bis(π-allylvalencene)dichlorodipalIadium, [PdCl(C15H23)]2(Berlin : de Gruyter, 2009) El Farrouji, A.; El Firdoussi, L.; Ali, M.A.; Karim, A.; Spannenberg, A.C30H46Cl2Pd2, monoclinic, Cl21 (no. 5), a = 22.0083(6) Å, b = 6.1827(2) Å, c = 21.5654(7) Å, β = 91.252(2)°, V= 2933.7 Å3, Z = 4, Rgr(F) = 0.019, wRref(F2) = 0.039, T = 200K. © by Oldenbourg Wissenschaftsverlag, München.
- ItemCrystal structure of strontium praseodum gallium oxide, SrPrGaO4(München : R. Oldenbourg Verlag GmbH, 2000) Gesing, T.M.; Uecker, R.; Buhl, J.-C.GaO4PrSr, tetragonal, I4/mmm (No. 139), a = 3.822(1) Å, c = 12.622(2) Å, V = 184.4 Å3, Z = 2, Rgt(F) = 0.028, wR(F2) = 0.082, T = 293 K.
- ItemRefinement of the crystal structure of holmium tetranickel boride, HoNi4B(München : R. Oldenbourg Verlag GmbH, 2000) Geupel, S.; Belger, A.; Paufler, P.; Graw, G.BHoNi4, hexagonal, P6/mmm (No. 191), a = 4.9696(4) Å, c = 6.9419(5) Å, V= 148.5 Å3, Z= 2, ρm = 9.13(1) g·cm-3, R(P) = 0.072, wR(P) = 0.099, R(I) = 0.065, T= 300 K.
- ItemCrystal structure of (η4-cycloocta-1,5-dien)-((+)-1, 1′-bis((2R,4R)-2,4-diethyl-phosphotano)-ferrocene)-rhodium(I) tetrafluoroborate, [Rh(C8H12)Fe(C12H 18FeP)2][BF4](Berlin : de Gruyter, 2007) Dai, Z.; Heller, D.; Spannenberg, A.; Drexler, H.-J.C32H48BF4FeP2Rh, orthorhombic, P212121 (no. 19), a = 10.640(2) Å, b = 16.007(3) Å, c = 19.460(4) Å, V = 3314.3 Å3, Z = 4, Rgt(F) = 0.044, wRref(F2) = 0.089, T = 200 K. © by Oldenbourg Wissenschaftsverlag.