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    Removal of hazardous pharmaceutical from water by photocatalytic treatment
    (Warsaw : Central European Science Journals, 2010) Choina, J.; Duwensee, H.; Flechsig, G.-U.; Kosslick, H.; Morawski, A.W.; Tuan, V.A.; Schulz, A.
    The photocatalytic abatement of hazardous pharmaceuticals has been investigated at very low concentration in the ppb range as found in wastewater and in environmental pollutants. Photocatalytic degradation of tetracycline as a model compound with titania catalysts has been studied using solarium UV-A and black light with differentially applied electric power, tetracycline and catalyst concentration. Abatement of up to 90% has been achieved after 1 hour. Adsorption of tetracycline and photochemical degradation contribute significantly to the abatement of tetracycline resulting in an immediate reduction during the initial period of treatment. Contribution of adsorption is high at very low concentration (500 ppb). Photocatalytic treatment with titania is even highly efficient in the abatement of very small concentrations of tetracycline in drinking water. © 2010 Versita Warsaw and Springer-Verlag Wien.
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    Carboxylic acids and esters as scaffold for cavities in porous single layer anti-reflective coatings of silica-titania with excellent optical and mechanical properties
    (Wuhan : Scientific Research Publishing, 2014) Menezes, E.; König, Peter; Jilavi, Mohammad H.; Oliveira de, Peter W.; Alves Junior, S.
    Anti-reflective (AR) single layer of silica-titania (SiO2-TiO2) coatings were obtained from sols containing pyromellitic dianhydride (PMDA) derivatives and Ti and Si precursors on glass substrate by dip-coating method. The coatings showed very high optical quality and the transmission was improved to up to 98.5%. Furthermore, the coatings also presented good mechanical stability.
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    TiO2 as Photosensitizer and Photoinitiator for Synthesis of Photoactive TiO2-PEGDA Hydrogel Without Organic Photoinitiator
    (Lausanne : Frontiers Media, 2018-8-7) Glass, Sarah; Trinklein, Betsy; Abel, Bernd; Schulze, Agnes
    The replacement of potentially toxic photoinitiators is of increasing interest regarding the synthesis of biomaterials by photopolymerization. Therefore, we present a new method for the preparation of UV polymerized hydrogels with TiO2 as a photoinitiator. Titania is known to be an excellent photoactive compound which is non-toxic, inert, and cheap. The so-formed hydrogels possess excellent mechanical properties, a high swelling ratio, and high thermal stability. Furthermore, no TiO2 is released from the hydrogels. Thus, the material is highly suitable for medical applications. Additionally, the present TiO2 in the hydrogels remains photoactive as demonstrated by degradation of methylene blue. This enables the application of TiO2-hydrogels in photodynamic therapy.