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DDC: 600 × Subject: degradation ×

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    The Many Deaths of Supercapacitors: Degradation, Aging, and Performance Fading
    (Weinheim : Wiley-VCH, 2023) Pameté, Emmanuel; Köps, Lukas; Kreth, Fabian Alexander; Pohlmann, Sebastian; Varzi, Alberto; Brousse, Thierry; Balducci, Andrea; Presser, Volker
    High-performance electrochemical applications have expedited the research in high-power devices. As such, supercapacitors, including electrical double-layer capacitors (EDLCs) and pseudocapacitors, have gained significant attention due to their high power density, long cycle life, and fast charging capabilities. Yet, no device lasts forever. It is essential to understand the mechanisms behind performance degradation and aging so that these bottlenecks can be addressed and tailored solutions can be developed. Herein, the factors contributing to the aging and degradation of supercapacitors, including electrode materials, electrolytes, and other aspects of the system, such as pore blocking, electrode compositions, functional groups, and corrosion of current collectors are examined. The monitoring and characterizing of the performance degradation of supercapacitors, including electrochemical methods, in situ, and ex situ techniques are explored. In addition, the degradation mechanisms of different types of electrolytes and electrode materials and the effects of aging from an industrial application standpoint are analyzed. Next, how electrode degradations and electrolyte decompositions can lead to failure, and pore blocking, electrode composition, and other factors that affect the device's lifespan are examined. Finally, the future directions and challenges for reducing supercapacitors' performance degradation, including developing new materials and methods for characterizing and monitoring the devices are summarized.
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    Bioactive glass–ceramics containing fluorapatite, xonotlite, cuspidine and wollastonite form apatite faster than their corresponding glasses
    ([London] : Macmillan Publishers Limited, 2024) Kirste, Gloria; Contreras Jaimes, Altair; de Pablos-Martín, Araceli; de Souza e Silva, Juliana Martins; Massera, Jonathan; Hill, Robert G.; Brauer, Delia S.
    Crystallisation of bioactive glasses has been claimed to negatively affect the ion release from bioactive glasses. Here, we compare ion release and mineralisation in Tris–HCl buffer solution for a series of glass–ceramics and their parent glasses in the system SiO2–CaO–P2O5–CaF2. Time-resolved X-ray diffraction analysis of glass–ceramic degradation, including quantification of crystal fractions by full pattern refinement, show that the glass–ceramics precipitated apatite faster than the corresponding glasses, in agreement with faster ion release from the glass–ceramics. Imaging by transmission electron microscopy and X-ray nano-computed tomography suggest that this accelerated degradation may be caused by the presence of nano-sized channels along the internal crystal/glassy matrix interfaces. In addition, the presence of crystalline fluorapatite in the glass–ceramics facilitated apatite nucleation and crystallisation during immersion. These results suggest that the popular view of bioactive glass crystallisation being a disadvantage for degradation, apatite formation and, subsequently, bioactivity may depend on the actual system study and, thus, has to be reconsidered.