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- ItemGeometric models for isotropic random porous media: A review(London : Hindawi, 2014) Hermann, Helmut; Elsner, AntjeModels for random porous media are considered. The models are isotropic both from the local and the macroscopic point of view; that is, the pores have spherical shape or their surface shows piecewise spherical curvature, and there is no macroscopic gradient of any geometrical feature. Both closed-pore and open-pore systems are discussed. The Poisson grain model, the model of hard spheres packing, and the penetrable sphere model are used; variable size distribution of the pores is included. A parameter is introduced which controls the degree of open-porosity. Besides systems built up by a single solid phase, models for porous media with the internal surface coated by a second phase are treated. Volume fraction, surface area, and correlation functions are given explicitly where applicable; otherwise numerical methods for determination are described. Effective medium theory is applied to calculate physical properties for the models such as isotropic elastic moduli, thermal and electrical conductivity, and static dielectric constant. The methods presented are exemplified by applications: small-angle scattering of systems showing fractal-like behavior in limited ranges of linear dimension, optimization of nanoporous insulating materials, and improvement of properties of open-pore systems by atomic layer deposition of a second phase on the internal surface.
- ItemHigh-resolution net load forecasting for micro-neighbourhoods with high penetration of renewable energy sources(Amsterdam [u.a.] : Elsevier Science, 2020) Kobylinski, P.; Wierzbowski, M.; Piotrowski, K.Though extensive, the literature on electrical load forecasting lacks reports on studies focused on existing residential micro-neighbourhoods comprising small numbers of single-family houses equipped with solar panels. This paper provides a full description of an ANN-based model designed to predict short-term high-resolution (15-min intervals) micro-scale residential net load profiles. Since it seems especially relevant due to the specificity of local autocorrelations in load signal, in this paper we put stress on the systematic approach to feature selection in the context of lagged signal. We performed a case study of a real micro-neighbourhood comprising only 75 single-family houses. The obtained average prediction error was equivalent to 5.4 per cent of the maximal measured net load. The issues, i.e.: (1) the feasibility of micro-scale residential load forecasting taking into account renewable energy penetration, (2) the feasibility to predict net load with dense temporal resolution of 15 min, (3) the feature selection problem, (4) the proposed prosumption- and comparison-oriented prediction model key performance measure, could be of interest to engineers designing energy balancing systems for local smart grids. © 2019 The Authors
- ItemInfluence of the hydrophobicity of polyelectrolytes on polyelectrolyte complex formation and complex particle structure and shape(Basel : MDPI AG, 2011) Mende, M.; Schwarz, S.; Zschoche, S.; Petzold, G.; Janke, A.Polyelectrolyte complexes (PECs) were prepared by structural uniform and strongly charged cationic and anionic modified alternating maleic anhydride copolymers. The hydrophobicity of the polyelectrolytes was changed by the comonomers (ethylene, isobutylene and styrene). Additionally, the n -/n + ratio of the molar charges of the polyelectrolytes and the procedure of formation were varied. The colloidal stability of the systems and the size, shape, and structure of the PEC particles were investigated by turbidimetry, dynamic light scattering (DLS) and atomic force microscopy (AFM). Dynamic light scattering indicates that beside large PEC particle aggregates distinct smaller particles were formed by the copolymers which have the highest hydrophobicity (styrene). These findings could be proved by AFM. Fractal dimension (D), root mean square (RMS) roughness and the surface profiles of the PEC particles adsorbed on mica allow the following conclusions: the higher the hydrophobicity of the polyelectrolytes, the broader is the particle size distribution and the minor is the swelling of the PEC particles. Hence, the most compact particles are formed with the very hydrophobic copolymer.