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    Soil Nutrient Detection for Precision Agriculture Using Handheld Laser-Induced Breakdown Spectroscopy (LIBS) and Multivariate Regression Methods (PLSR, Lasso and GPR)
    (Basel : MDPI, 2020) Erler, Alexander; Riebe, Daniel; Beitz, Toralf; Löhmannsröben, Hans-Gerd; Gebbers, Robin
    Precision agriculture (PA) strongly relies on spatially differentiated sensor information. Handheld instruments based on laser-induced breakdown spectroscopy (LIBS) are a promising sensor technique for the in-field determination of various soil parameters. In this work, the potential of handheld LIBS for the determination of the total mass fractions of the major nutrients Ca, K, Mg, N, P and the trace nutrients Mn, Fe was evaluated. Additionally, other soil parameters, such as humus content, soil pH value and plant available P content, were determined. Since the quantification of nutrients by LIBS depends strongly on the soil matrix, various multivariate regression methods were used for calibration and prediction. These include partial least squares regression (PLSR), least absolute shrinkage and selection operator regression (Lasso), and Gaussian process regression (GPR). The best prediction results were obtained for Ca, K, Mg and Fe. The coefficients of determination obtained for other nutrients were smaller. This is due to much lower concentrations in the case of Mn, while the low number of lines and very weak intensities are the reason for the deviation of N and P. Soil parameters that are not directly related to one element, such as pH, could also be predicted. Lasso and GPR yielded slightly better results than PLSR. Additionally, several methods of data pretreatment were investigated.
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    Airborne electromagnetic, magnetic, and radiometric surveys at the German North Sea coast applied to groundwater and soil investigations
    (Basel : MDPI, 2020) Siemon, Bernhard; Ibs-von Seht, Malte; Steuer, Annika; Deus, Nico; Wiederhold, Helga
    The knowledge of the subsurface down to about one hundred meters is fundamental for a variety of economic, ecological, and geoscientific tasks, particularly in coastal zones. Marine and terrestrial processes influence coastal zones and both seawater intrusion and submarine freshwater discharges may occur. The Federal Institute for Geosciences and Natural Resources (BGR) conducted airborne geophysical surveys in the coastal region of the German Bight between 2000 and 2014. The helicopter-borne system used simultaneously collected electromagnetic (HEM), magnetic (HMG), and radiometric (HRD) data. An area of about 5900 km2 was covered with parallel flight lines at 250 m line separation and additional tie-lines at larger separations. In total, about 25,000 km of data at sampling distances of 4 m (HEM, HMG) and 40 m (HRD) were acquired. The electrical resistivity (HEM), the anomalies of the magnetic field (HMG), and the exposure rate (HRD) are the resulting geophysical parameters derived from the data. The results are displayed as maps of the geophysical parameters as well as vertical resistivity sections (only HEM). Both data and products are publicly available via BGR’s product center. The airborne geophysical results helped to outline the fresh–saline groundwater interface, freshwater lenses on islands, submarine groundwater discharges, buried tunnel valleys, mires, and ancient landscapes.