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Now showing 1 - 10 of 211
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    Optically stimulated luminescence dating of young fluvial deposits of the Middle Elbe River Flood Plains using different age models
    (Warsaw : De Gruyter, 2014) Kunz, Alexander; Pflanz, Dorthe; Weniger, Tobias; Urban, Brigitte; Krüger, Frank; Chen, Yue-Gau
    In the last few decades optically stimulated luminescence (OSL) dating has become an im-portant tool in geochronological studies. The great advantage of the method, i.e. dating the deposi-tional age of sediments directly, can be impaired by incomplete bleaching of grains. This can result in a scattered distribution of equivalent doses (DE), leading to incorrect estimation of the depositional age. Thoroughly tested protocols as well as good data analysis with adequate statistical methods are important to overcome this problem. In this study, samples from young fluvial sand and flood plain deposits from the Elbe River in northern Germany were investigated to compare its depositional ages from different age models with well-known historical dates. Coarse grain quartz (100-200 μm and 150-250 μm) and polymineral fine grains (4-11 μm) were dated using the single aliquot regenerative (SAR) dose protocol. The paleodose (DP) was calculated from the DE data set using different ap-proaches. Results were compared with the development of the Elbe River, which is well-documented by historical records and maps covering the last 1,000 years. Depending on the statistical approach it can be demonstrated that depositional ages significantly differ from the most likely depositional age. For the investigated coarse grain quartz samples all ages calculated from the MAM-3UL, including their uncertainties, are within the historical documented age. Results of the polymineral fine grain samples are overestimating the historically documented depositional age, indicating undetectable in-complete bleaching. This study shows the importance of using an adequate statistical approach to cal-culate reliable OSL ages from fluvial sediments. © 2013 Silesian University of Technology, Gliwice, Poland. All rights reserved.
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    Understanding Business Environments and Success Factors for Emerging Bioeconomy Enterprises through a Comprehensive Analytical Framework
    (Basel : MDPI, 2020) Adamseged, Muluken Elias; Grundmann, Philipp
    The development toward the bioeconomy requires, among others, generating and institutionalizing knowledge that contributes to technical and nontechnical inventions and innovations. Efforts to support innovation are often linked with the development of business models that facilitate the development in bioeconomy. However, the interdependences between the business models and their business environments are not sufficiently well understood in a way where misalignments that can obstruct the development can be dealt with adequately. Given this lacuna, this research aims to contribute to the development of a comprehensive analytical framework for better understanding the conditions of business environment as well as empirically apply the framework in an empirical study on cases of bioeconomy enterprises in Europe. In this paper, a comprehensive business environment framework is developed and applied for analyzing over 80 cases, thereby allowing for critical action arenas and crucial success factors to be identified. The findings are derived from a systematic application of the framework to relevant action arenas for business development: institutional development, technology and knowledge, consumers’ agency, market structure, funding, resource and infrastructure, and training and education. The results show that businesses in the bioeconomy, unlike other businesses, have to deal with more and very specific constraining legislative issues, infant and non-adapted technology and knowledge, as well as unclear values and perceptions of consumers. Due to this, businesses have to develop new forms of cooperation with different stakeholders. Successful businesses are characterized by the fact that they develop specific strategies, steering structures, and processes with a particular focus on learning and innovation to overcome misalignments between the business environment and their business models. Focusing efforts on learning and innovation in institutional development, technology and knowledge, consumers’ agency, and funding are especially promising as these turned out to be particularly critical and in particular need of institutional alignment for reducing different kinds of transaction costs in the development of bioeconomy.
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    Analysing Interlinked Frequency Dynamics of the Urban Acoustic Environment
    (Basel : MDPI AG, 2022) Haselhoff, Timo; Braun, Tobias; Hornberg, Jonas; Lawrence, Bryce T.; Ahmed, Salman; Gruehn, Dietwald; Moebus, Susanne
    As sustainable metropolitan regions require more densely built-up areas, a comprehensive understanding of the urban acoustic environment (AE) is needed. However, comprehensive datasets of the urban AE and well-established research methods for the AE are scarce. Datasets of audio recordings tend to be large and require a lot of storage space as well as computationally expensive analyses. Thus, knowledge about the long-term urban AE is limited. In recent years, however, these limitations have been steadily overcome, allowing a more comprehensive analysis of the urban AE. In this respect, the objective of this work is to contribute to a better understanding of the time-frequency domain of the urban AE, analysing automatic audio recordings from nine urban settings over ten months. We compute median power spectra as well as normalised spectrograms for all settings. Additionally, we demonstrate the use of frequency correlation matrices (FCMs) as a novel approach to access large audio datasets. Our results show site-dependent patterns in frequency dynamics. Normalised spectrograms reveal that frequency bins with low power hold relevant information and that the AE changes considerably over a year. We demonstrate that this information can be captured by using FCMs, which also unravel communities of interlinked frequency dynamics for all settings.
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    Improving the Accuracy of Hydrodynamic Simulations in Data Scarce Environments Using Bayesian Model Averaging: A Case Study of the Inner Niger Delta, Mali, West Africa
    (Basel : MDPI, 2019) Haque, Md Mominul; Seidou, Ousmane; Mohammadian, Abdolmajid; Djibo, Abdouramane Gado; Liersch, Stefan; Fournet, Samuel; Karam, Sara; Perera, Edangodage Duminda Pradeep; Kleynhans, Martin
    In this paper, the study area was the Inner Niger Delta (IND) in Mali, West Africa. The IND is threatened by climate change, increasing irrigation, and dam operations. 2D hydrodynamic modelling was used to simulate water levels, discharge, and inundation extent in the IND. Three different digital elevation models (DEM) (SRTM, MERIT, and a DEM derived from satellite images were used as a source of elevation data. Six different models were created, with different sources of elevation data and different downstream boundary conditions. Given that the performance of the models varies according to the location in the IND, the variable under consideration and the performance criteria, Bayesian Model Averaging (BMA) was used to assess the relative performance of each of the six models. The BMA weights, along with deterministic performance measures, such as the Nash Sutcliffe coefficient (NS) and the Pearson’s correlation coefficient (r), provide quantitative evidence as to which model is the best when simulating a particular hydraulic variable at a particular location. After the models were combined with BMA, both discharge and water levels could be simulated with reasonable precision (NS > 0.8). The results of this work can contribute to the more efficient management of water resources in the IND.
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    Degradation of glyphosate in water by the application of surface corona discharges
    (Bristol : IWA Publishing, 2021) Zocher, Katja; Gros, Peter; Werneburg, Matthias; Brüser, Volker; Kolb, Juergen F.; Leinweber, Peter
    Glyphosate (GLP) is one of the most widely applied herbicides, and is found ubiquitously in the environment. The removal of glyphosate from waste water and soil is challenging and can be achieved with chemical or biological methods, which, nevertheless, suffer from different disadvantages. The application of a physical plasma for the removal of GLP in water was examined by the application of surface corona discharges in a wire-to-cylinder setup filled with argon. The plasma was ignited at the liquid surface without any additives. By applying a photometric method, GLP was detected after derivatisation with fluorenyl methoxycarbonyl chloride, whereas phosphate was determined with ammonium molybdate. A GLP degradation rate of 90.8% could be achieved within a treatment time of 30 minutes with an estimated energy efficiency of 0.32 g/kWh.
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    Synergistic use of peat and charred material in growing media–an option to reduce the pressure on peatlands?
    (Vilnius : Technika, 2017) Kern, Jürgen; Tammeorg, Priit; Shanskiy, Merrit; Sakrabani, Ruben; Knicker, Heike; Kammann, Claudia; Tuhkanen, Eeva-Maria; Smidt, Geerd; Prasad, Munoo; Tiilikkala, Kari; Sohi, Saran; Gascó, Gabriel; Steiner, Christoph; Glaser, Bruno
    Peat is used as a high quality substrate for growing media in horticulture. However, unsustainable peat extraction damages peatland ecosystems, which disappeared to a large extent in Central and South Europe. Furthermore, disturbed peatlands are becoming a source of greenhouse gases due to drainage and excavation. This study is the result of a workshop within the EU COST Action TD1107 (Biochar as option for sustainable resource management), held in Tartu (Estonia) in 2015. The view of stakeholders were consulted on new biochar-based growing media and to what extent peat may be replaced in growing media by new compounds like carbonaceous materials from thermochemical conversion. First positive results from laboratory and greenhouse experiments have been reported with biochar content in growing media ranging up to 50%. Various companies have already started to use biochar as an additive in their growing media formulations. Biochar might play a more important role in replacing peat in growing media, when biochar is available, meets the quality requirements, and their use is economically feasible. © 2017 The Author(s) Published by VGTU Press and Informa UK Limited, [trading as Taylor & Francis Group].
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    Thermo-responsive cell culture carriers based on poly(vinyl methyl ether) - The effect of biomolecular ligands to balance cell adhesion and stimulated detachment
    (Abingdon : Taylor & Francis, 2015) Teichmann, Juliane; Nitschke, Mirko; Pette, Dagmar; Valtink, Monika; Gramm, Stefan; Härtel, Frauke V.; Noll, Thomas; Funk, Richard H.W.; Engelmann, Katrin; Werner, Carsten
    Two established material systems for thermally stimulated detachment of adherent cells were combined in a cross-linked polymer blend to merge favorable properties. Through this approach poly(N-isopropylacrylamide) (PNiPAAm) with its superior switching characteristic was paired with a poly(vinyl methyl ether)-based composition that allows adjusting physico-chemical and biomolecular properties in a wide range. Beyond pure PNiPAAm, the proposed thermo-responsive coating provides thickness, stiffness and swelling behavior, as well as an apposite density of reactive sites for biomolecular functionalization, as effective tuning parameters to meet specific requirements of a particular cell type regarding initial adhesion and ease of detachment. To illustrate the strength of this approach, the novel cell culture carrier was applied to generate transplantable sheets of human corneal endothelial cells (HCEC). Sheets were grown, detached, and transferred onto planar targets. Cell morphology, viability and functionality were analyzed by immunocytochemistry and determination of transepithelial electrical resistance (TEER) before and after sheet detachment and transfer. HCEC layers showed regular morphology with appropriate TEER. Cells were positive for function-associated marker proteins ZO-1, Na+/K+-ATPase, and paxillin, and extracellular matrix proteins fibronectin, laminin and collagen type IV before and after transfer. Sheet detachment and transfer did not impair cell viability. Subsequently, a potential application in ophthalmology was demonstrated by transplantation onto de-endothelialized porcine corneas in vitro. The novel thermo-responsive cell culture carrier facilitates the generation and transfer of functional HCEC sheets. This paves the way to generate tissue engineered human corneal endothelium as an alternative transplant source for endothelial keratoplasty.
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    From Upstream to Purification : Production of Lactic Acid from the Organic Fraction of Municipal Solid Waste
    ([Dordrecht] : Springer Netherlands, 2020) López‑Gómez, José Pablo; Unger, Peter; Schneider, Roland; Venus, Joachim
    The implementation of an efficient and sustainable management of the organic fraction of municipal solid wastes (OFMSW) is a topic of intensive discussion in EU countries. Recently, the OFMSW has been investigated as a potential substrate for the production of lactic acid (LA) through fermentation. Nevertheless, none of the reports available in the literature covers all the stages of the conversion process. The present research article is a comprehensive study which includes the upstream, fermentation and downstream for the conversion of OFMSW into LA. Several batches of OFMSW were analysed for the evaluation of sugars released and LA content before the fermentation. Fermentations were performed to study the effect of hydrolysate quality on the LA production using Bacillus coagulans A166. Purification of LA, based on electrodialysis, was carried out after pilot scale fermentation of OFMSW hydrolysates. Results showed that variations in the concentrations of sugars and LA are observed from batch to batch of OFMSW. More specifically, LA can reach high concentrations even before the substrates are hydrolysed, limiting the potential applications of the final product due to low enantiomeric purities. In general, fermentations of the hydrolysate were efficient, with conversion yields of 0.65 g g−1 without the addition of extra nutrients. Downstream is still a challenging stage of the process. A LA recovery of 55% was obtained, with the most significant losses observed during the micro- and nanofiltrations. Overall, a conversion of 10% from OFMSW substrate (dry basis) to LA was achieved.
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    Representativeness of European biochar research: part II–pot and laboratory studies
    (Vilnius : Technika, 2017) Sakrabani, Ruben; Kern, Jürgen; Mankasingh, Utra; Zavalloni, Costanza; Zanchettin, Giulia; Bastos, Ana Catarina; Tammeorg, Priit; Jeffery, Simon; Glaser, Bruno; Verheijen, Frank G. A.
    Biochar research is extensive and there are many pot and laboratory studies carried out in Europe to investigate the mechanistic understanding that govern its impact on soil processes. A survey was conducted in order to find out how representative these studies under controlled experimental conditions are of actual environmental conditions in Europe and biomass availability and conversion technologies. The survey consisted of various key questions related to types of soil and biochar used, experimental conditions and effects of biochar additions on soil chemical, biological and physical properties. This representativeness study showed that soil texture and soil organic carbon contents used by researchers are well reflected in the current biochar research in Europe (through comparison with published literature), but less so for soil pH and soil type. This study provides scope for future work to complement existing research findings, avoiding unnecessary repetitions and highlighting existing research gaps. © 2017 The Author(s) Published by VGTU Press and Informa UK Limited, [trading as Taylor & Francis Group].
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    Luminescence dating of volcanogenic outburst flood sediments from Aso volcano and tephric loess deposits, southwest Japan
    (Warsaw : De Gruyter, 2013) Tsukamoto, Sumiko; Kataoka, Kyoko; Miyabuchi, Yasuo
    Luminescence dating has been applied to volcanogenic outburst flood sediments (Takuma gravel bed) from Aso volcano, Japan, and tephric loess deposits overlying the gravel bed. The poly-mineral fine grains (4-11 μm) from loess deposits were measured with pulsed optically stimulated luminescence (pulsed OSL) and post-IR infrared stimulated luminescence (pIRIR) methods, whereas the Takuma gravel bed containing no quartz, was measured with IRSL and pIRIR methods using sand sized (150-200 μm) plagioclase. The loess deposits date back at least to ∼50 ka by consistent IRSL, pIRIR and pulsed OSL ages from the lowermost part of the loess deposits from one section. The ages obtained from the bottom part of the other loess section are not consistent each other. However, we consider that the pIRIR age (72±6 ka) which showed negligible anomalous fading is most reliable, and regard as a preliminary minimum age of the Takuma gravel bed. The equivalent doses (De) for the plagioclase from the Takuma gravel bed have a narrow distribution and the weighted mean of the three samples yield an age of 89±3 ka. This age is in agreement with the last caldera-forming eruption of Aso volcano (∼87 ka) and it is likely that the pIRIR signal has not been bleached before the deposi-tion. IRSL dating without applying pIRIR using small aliquots was also conducted, however, the IRSL signal shows no clear evidence of an additional bleaching during the event of outburst flood from the caldera lake. © 2013 Silesian University of Technology, Gliwice, Poland. All rights reserved.