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Has files: Yes × Type: article × Version: publishedVersion × Sponsor: Leibniz_Fonds × WGL Institute: IFWD ×

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Now showing 1 - 10 of 22
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    Combining magnetic forces for contactless manipulation of fluids in microelectrode-microfluidic systems
    (London : Nature Publishing Group, 2019) Haehnel, V.; Khan, F.Z.; Mutschke, G.; Cierpka, C.; Uhlemann, M.; Fritsch, I.
    A novel method to drive and manipulate fluid in a contactless way in a microelectrode-microfluidic system is demonstrated by combining the Lorentz and magnetic field gradient forces. The method is based on the redox-reaction [Fe(CN) 6 ] 3− /[Fe(CN) 6 ] 4− performed in a magnetic field oriented perpendicular to the ionic current that crosses the gap between two arrays of oppositely polarized microelectrodes, generating a magnetohydrodynamic flow. Additionally, a movable magnetized CoFe micro-strip is placed at different positions beneath the gap. In this region, the magnetic flux density is changed locally and a strong magnetic field gradient is formed. The redox-reaction changes the magnetic susceptibility of the electrolyte near the electrodes, and the resulting magnetic field gradient exerts a force on the fluid, which leads to a deflection of the Lorentz force-driven main flow. Particle Image Velocity measurements and numerical simulations demonstrate that by combining the two magnetic forces, the flow is not only redirected, but also a local change of concentration of paramagnetic species is realized.
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    Improved kinetic behaviour of Mg(NH2)2-2LiH doped with nanostructured K-modified-LixTiyOz for hydrogen storage
    (London : Nature Publishing Group, 2020) Gizer, G.; Puszkiel, J.; Riglos, M.V.C.; Pistidda, C.; Ramallo-López, J.M.; Mizrahi, M.; Santoru, A.; Gemming, T.; Tseng, J.-C.; Klassen, T.; Dornheim, M.
    The system Mg(NH2)2 + 2LiH is considered as an interesting solid-state hydrogen storage material owing to its low thermodynamic stability of ca. 40 kJ/mol H2 and high gravimetric hydrogen capacity of 5.6 wt.%. However, high kinetic barriers lead to slow absorption/desorption rates even at relatively high temperatures (>180 °C). In this work, we investigate the effects of the addition of K-modified LixTiyOz on the absorption/desorption behaviour of the Mg(NH2)2 + 2LiH system. In comparison with the pristine Mg(NH2)2 + 2LiH, the system containing a tiny amount of nanostructured K-modified LixTiyOz shows enhanced absorption/desorption behaviour. The doped material presents a sensibly reduced (∼30 °C) desorption onset temperature, notably shorter hydrogen absorption/desorption times and reversible hydrogen capacity of about 3 wt.% H2 upon cycling. Studies on the absorption/desorption processes and micro/nanostructural characterizations of the Mg(NH2)2 + 2LiH + K-modified LixTiyOz system hint to the fact that the presence of in situ formed nanostructure K2TiO3 is the main responsible for the observed improved kinetic behaviour.
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    Triplet superconductivity in coupled odd-gon rings
    (London : Nature Publishing Group, 2019) Reja, S.; Nishimoto, S.
    Shedding light on the nature of spin-triplet superconductivity has been a long-standing quest in condensed matter physics since the discovery of superfluidity in liquid 3 He. Nevertheless, the mechanism of spin-triplet pairing is much less understood than that of spin-singlet pairing explained by the Bardeen-Cooper-Schrieffer theory or even observed in high-temperature superconductors. Here we propose a versatile mechanism for spin-triplet superconductivity which emerges through a melting of macroscopic spin polarization stabilized in weakly coupled odd-gon (e.g., triangle, pentagon, etc) systems. We demonstrate the feasibility of sustaining spin-triplet superconductivity with this mechanism by considering a new class of quasi-one-dimensional superconductors A 2 Cr 3 As 3 (A = K, Rb, and Cs). Furthermore, we suggest a simple effective model to easily illustrate the adaptability of the mechanism to general systems consisting of odd-gon units. This mechanism provides a rare example of superconductivity from on-site Coulomb repulsion.
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    Ordered states in the Kitaev-Heisenberg model: From 1D chains to 2D honeycomb
    (London : Nature Publishing Group, 2018) Agrapidis, Cliò Efthimia; van den Brink, Jeroen; Nishimoto, Satoshi
    We study the ground state of the 1D Kitaev-Heisenberg (KH) model using the density-matrix renormalization group and Lanczos exact diagonalization methods. We obtain a rich ground-state phase diagram as a function of the ratio between Heisenberg (J = cosϕ) and Kitaev (K = sinϕ) interactions. Depending on the ratio, the system exhibits four long-range ordered states: ferromagnetic-z, ferromagnetic-xy, staggered-xy, Néel-z, and two liquid states: Tomonaga-Luttinger liquid and spiral-xy. The two Kitaev points ϕ=π2 and φ=3π2 are singular. The ϕ-dependent phase diagram is similar to that for the 2D honeycomb-lattice KH model. Remarkably, all the ordered states of the honeycomb-lattice KH model can be interpreted in terms of the coupled KH chains. We also discuss the magnetic structure of the K-intercalated RuCl3, a potential Kitaev material, in the framework of the 1D KH model. Furthermore, we demonstrate that the low-lying excitations of the 1D KH Hamiltonian can be explained within the combination of the known six-vertex model and spin-wave theory.
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    Routes to control diffusive pathways and thermal expansion in Ti-alloys
    (London : Nature Publishing Group, 2020) Bönisch, M.; Stoica, M.; Calin, M.
    β-stabilized Ti-alloys present several unexplored and intriguing surprises in relation to orthorhombic α″ phases. Among them are (i) the diffusion-controlled formation of transitional α″iso, α″lean and α″rich phases and ii) the highly anisotropic thermal expansion of martensitic α″. Using the prototypical Ti-Nb system, we demonstrate that the thermodynamic energy landscape reveals formation pathways for the diffusional forms of α″ and may lead to a stable β-phase miscibility gap. In this way, we derive temperature-composition criteria for the occurrence of α″iso and resolve reaction sequences during thermal cycling. Moreover, we show that the thermal expansion anisotropy of martensitic α″ gives rise to directions of zero thermal strain depending on Nb content. Utilizing this knowledge, we propose processing routes to achieve null linear expansion in α″ containing Ti-alloys. These concepts are expected to be transferable to other Ti-alloys and offer new avenues for their tailoring and technological exploitation.
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    Coupling a single solid-state quantum emitter to an array of resonant plasmonic antennas
    (London : Nature Publishing Group, 2018) Pfeiffer, M.; Atkinson, P.; Rastelli, A.; Schmidt, O.G.; Giessen, H.; Lippitz, M.; Lindfors, K.
    Plasmon resonant arrays or meta-surfaces shape both the incoming optical field and the local density of states for emission processes. They provide large regions of enhanced emission from emitters and greater design flexibility than single nanoantennas. This makes them of great interest for engineering optical absorption and emission. Here we study the coupling of a single quantum emitter, a self-assembled semiconductor quantum dot, to a plasmonic meta-surface. We investigate the influence of the spectral properties of the nanoantennas and the position of the emitter in the unit cell of the structure. We observe a resonant enhancement due to emitter-array coupling in the far-field regime and find a clear difference from the interaction of an emitter with a single antenna.
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    Slow and fast single photons from a quantum dot interacting with the excited state hyperfine structure of the Cesium D1-line
    (London : Nature Publishing Group, 2019) Kroh, T.; Wolters, J.; Ahlrichs, A.; Schell, A.W.; Thoma, A.; Reitzenstein, S.; Wildmann, J.S.; Zallo, E.; Trotta, R.; Rastelli, A.; Schmidt, O.G.; Benson, O.
    Hybrid interfaces between distinct quantum systems play a major role in the implementation of quantum networks. Quantum states have to be stored in memories to synchronize the photon arrival times for entanglement swapping by projective measurements in quantum repeaters or for entanglement purification. Here, we analyze the distortion of a single-photon wave packet propagating through a dispersive and absorptive medium with high spectral resolution. Single photons are generated from a single In(Ga)As quantum dot with its excitonic transition precisely set relative to the Cesium D1 transition. The delay of spectral components of the single-photon wave packet with almost Fourier-limited width is investigated in detail with a 200 MHz narrow-band monolithic Fabry-Pérot resonator. Reflecting the excited state hyperfine structure of Cesium, “slow light” and “fast light” behavior is observed. As a step towards room-temperature alkali vapor memories, quantum dot photons are delayed for 5 ns by strong dispersion between the two 1.17 GHz hyperfine-split excited state transitions. Based on optical pumping on the hyperfine-split ground states, we propose a simple, all-optically controllable delay for synchronization of heralded narrow-band photons in a quantum network.
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    Strengthening of Al-Fe3Al composites by the generation of harmonic structures
    (London : Nature Publishing Group, 2018) Shahid, R.N.; Scudino, S.
    Strengthening of alloys can be efficiently attained by the creation of harmonic structures: bimodal microstructures generated by controlled milling of the particulate precursors, which consist of coarse-grained cores embedded in a continuous fine-grained matrix. Here, we extend the concept of harmonic structures to metal matrix composites and analyze the effectiveness of such bimodal microstructures for strengthening composites consisting of a pure Al matrix reinforced with Fe3Al particles. Preferential microstructural refinement limited to the surface of the particles, where the Fe3Al phase is progressively fragmented, occurs during ball milling of the Al-Fe3Al composite powder mixtures. The refined surface becomes the continuous fine-grained matrix that encloses macro-regions with coarser reinforcing particles in the harmonic composites synthesized during subsequent powder consolidation. The generation of the bimodal microstructure has a significant influence on the strength of the harmonic composites, which exceeds that of the conventional material by a factor of 2 while retaining considerable plastic deformation. Finally, modeling of the mechanical properties indicates that the strength of the harmonic composites can be accurately described by taking into account both the volume fraction of reinforcement and the characteristic microstructural features describing the harmonic structure.
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    In-situ tensile testing of ZrCu-based metallic glass composites
    (London : Nature Publishing Group, 2018) Sun, H.C.; Ning, Z.L.; Wang, G.; Liang, W.Z.; Pauly, S.; Huang, Y.J.; Guo, S.; Xue, X.; Sun, J.F.
    ZrCu-based bulk metallic glass composites (BMGCs) are well known for their plastic deformability, superior to traditional metallic glasses (MGs), which is attributed to a unique dual-phases structure, namely, the glassy matrix and unstable B2 phase. In the present study, in-situ tensile testing is used to trace the deformation process of a ZrCu-based BMGC. Three deformation stages of the BMGC, i.e., the elastic-elastic stage, the elastic-plastic stage, and the plastic-plastic stage are identified. In the elastic-elastic and elastic-plastic stages, the yield strength and elastic limit are major influenced by the volume fraction of the B2 crystals. In the plastic-plastic stage, the B2 phase stimulates the formation of multiple shear bands and deflects the direction of shear bands by disturbing the stress field in front of the crack tip. The deformation-induced martensitic transformation of the metastable B2 phase contributes to the plasticity and work hardening of the composite. This study highlights the formation and propagation of multiple shear bands and reveals the interactions of shear bands with structural heterogeneities in situ. Especially, the blocking of shear bands by crystals and the martensitic transformation of the B2 phase are critical for the mechanistic deformation process and illustrate the function of the B2 phase in the present BMGCs.
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    Calcite incorporated in silica/collagen xerogels mediates calcium release and enhances osteoblast proliferation and differentiation
    (London : Nature Publishing Group, 2020) Rößler, S.; Unbehau, R.; Gemming, T.; Kruppke, B.; Wiesmann, H.-P.; Hanke, T.
    Multiphasic silica/collagen xerogels are biomaterials designed for bone regeneration. Biphasic silica/collagen xerogels (B30) and triphasic xerogels (B30H20 or B30CK20) additionally containing hydroxyapatite or calcite were demonstrated to exhibit several structural levels. On the first level, low fibrillar collagen serves as template for silica nanoparticle agglomerates. On second level, this silica-enriched matrix phase is fiber-reinforced by collagen fibrils. In case of hydroxyapatite incorporation in B30H20, resulting xerogels exhibit a hydroxyapatite-enriched phase consisting of hydroxyapatite particle agglomerates next to silica and low fibrillar collagen. Calcite in B30CK20 is incorporated as single non-agglomerated crystal into the silica/collagen matrix phase with embedded collagen fibrils. Both the structure of multiphasic xerogels and the manner of hydroxyapatite or calcite incorporation have an influence on the release of calcium from the xerogels. B30CK20 released a significantly higher amount of calcium into a calcium-free solution over a three-week period than B30H20. In calcium containing incubation media, all xerogels caused a decrease in calcium concentration as a result of their bioactivity, which was superimposed by the calcium release for B30CK20 and B30H20. Proliferation of human bone marrow stromal cells in direct contact to the materials was enhanced on B30CK20 compared to cells on both plain B30 and B30H20.