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Has files: Yes × Publisher: Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik × Subject: phase transitions ×

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Now showing 1 - 10 of 24
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    Simulation der Strahlhärtung von Stahl mit WIAS-SHarP
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2002) Buchwalder, A.; Hömberg, D.; Jurke, Th.; Spies, H.-J.; Weiss, W.
    Die Software WIAS-SHarP zur Simulation der Oberflaechenhaertung von Stahl mit Laser- und Elektronenstrahl wurde im Rahmen eines zweijaehrigen interdisziplinaeren Forschungsprojektes entwickelt. Das zugrunde liegende mathematische Modell besteht aus einem System gewoehnlicher Differentialgleichungen zur Beschreibung der Gefuegeumwandlungen, gekoppelt mit einer nichtlinearen Waermeleitungsgleichung sowie Komponenten zur Beschreibung der Energieeinkopplung. Um eine moeglichst breite Anwendbarkeit der Software zu gewaehrleisten, wurden werkstoffspezifische Kennwerte zum Umwandlungsverhalten fuer eine grosse Anzahl praxisrelevanter Staehle bereitgestellt. Zur Modellverifikation wurden experimentelle Untersuchungen bei beteiligten Industriepartnern durchgefuehrt und mit den entsprechenden Simulationsrechnungen verglichen.
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    Hysteresis and phase transition in many-particle storage systems
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2010) Dreyer, Wolfgang; Guhlke, Clemens; Herrmann, Michael
    We study the behavior of systems consisting of ensembles of interconnected storage particles. Our examples concern the storage of lithium in many-particle electrodes of rechargeable lithium-ion batteries and the storage of air in a system of interconnected rubber balloons. We are particularly interested in those storage systems whose constituents exhibit non-monotone material behavior leading to transitions between two coexisting phases and to hysteresis. In the current study we consider the case that the time to approach equilibrium of a single storage particle is much smaller than the time for full charging of the ensemble. In this regime the evolution of the probability to find a particle of the ensemble in a certain state, may be described by a nonlocal conservation law of Fokker-Planck type. Two constant parameter control whether the ensemble transits the 2-phase region along a Maxwell line or along a hysteresis path or if the ensemble shows the same non-monotone behavior as its constituents.
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    Dynamical phase transitions for flows on finite graphs
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2020) Gabrielli, Davide; Renger, D. R. Michiel
    We study the time-averaged flow in a model of particles that randomly hop on a finite directed graph. In the limit as the number of particles and the time window go to infinity but the graph remains finite, the large-deviation rate functional of the average flow is given by a variational formulation involving paths of the density and flow. We give sufficient conditions under which the large deviations of a given time averaged flow is determined by paths that are constant in time. We then consider a class of models on a discrete ring for which it is possible to show that a better strategy is obtained producing a time-dependent path. This phenomenon, called a dynamical phase transition, is known to occur for some particle systems in the hydrodynamic scaling limit, which is thus extended to the setting of a finite graph.
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    Site-monotonicity properties for reflection positive measures with applications to quantum spin systems
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2020) Lees, Benjamin; Taggi, Lorenzo
    We consider a general statistical mechanics model on a product of local spaces and prove that, if the corresponding measure is reflection positive, then several site-monotonicity properties for the two-point function hold. As an application of such a general theorem, we derive site-monotonicity properties for the spin-spin correlation of the quantum Heisenberg antiferromagnet and XY model, we prove that such spin-spin correlations are point-wise uniformly positive on vertices with all odd coordinates -- improving previous positivity results which hold for the Cesàro sum -- and we derive site-monotonicity properties for the probability that a loop connects two vertices in various random loop models, including the loop representation of the spin O(N) model, the double-dimer model, the loop O(N) model, lattice permutations, thus extending the previous results of Lees and Taggi (2019).
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    A mathematical model for case hardening of steel
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2007) Fasano, Antonio; Hömberg, Dietmar; Panizzi, Lucia
    A mathematical model for the gas carburizing of steel is presented. Carbon is dissolved in the surface layer of a low-carbon steel part at a temperature sufficient to render the steel austenitic, followed by quenching to form a martensitic microstructure. The model consists of a nonlinear evolution equation for the temperature, coupled with a nonlinear evolution equation for the carbon concentration, both coupled with two ordinary differential equations to describe the phase fractions. We prove existence and uniqueness of a solution and finally present some numerical simulations.
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    Phase transition and hysteresis in a rechargeable lithium battery
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2007) Dreyer, Wolfgang; Gaberšček, Miran; Jamnik, Janko
    We represent a model which describes the evolution of a phase transition that occurs in some part of a rechargeable lithium battery during the process of charging/discharging. The model is capable to simulate the hysteretic behavior of the voltage - charge characteristics. During discharging of the battery, the interstitial lattice sites of a small crystalline host system are filled up with lithium atoms and these are released again during charging. We show within the context of a sharp interface model that two mechanical phenomena go along with a phase transition that appears in the host system during supply and removal of lithium. At first the lithium atoms need more space than it is available by the interstitial lattice sites, which leads to a maximal relative change of the crystal volume of about $6%$. Furthermore there is an interface between two adjacent phases that has very large curvature of the order of magnitude 100 m, which evoke here a discontinuity of the normal component of the stress. In order to simulate the dynamics of the phase transitions and in particular the observed hysteresis we establish a new initial and boundary value problem for a nonlinear PDE system that can be reduced in some limiting case to an ODE system.
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    Mayer and virial series at low temperature
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2011) Jansen, Sabine
    We analyze the Mayer pressure-activity and virial pressure-density series for a classical system of particles in continuous configuration space at low temperature. Particles interact via a finite range potential with an attractive tail. We propose physical interpretations of the Mayer and virial series' radius of convergence, valid independently of the question of phase transition: the Mayer radius corresponds to a fast increase from very small to finite density, and the virial radius corresponds to a cross-over from monatomic to polyatomic gas. Our results have consequences for the search of a low density, low temperature solid-gas phase transition, consistent with the Lee-Yang theorem for lattice gases and with the continuum Widom-Rowlinson mode.
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    Exact solutions to the Riemann problem for compressible isothermal Euler equations for two phase flows with and without phase transition
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2011) Dreyer, Wolfgang; Hantke, Maren; Warnecke, Gerald
    We consider the isothermal Euler equations with phase transition between a liquid and a vapor phase. The mass transfer is modeled by a kinetic relation. We prove existence and uniqueness results. Further, we construct the exact solution for Riemann problems. We derive analogous results for the cases of initially one phase with resulting condensation by compression or evaporation by expansion. Further we present numerical results for these cases. We compare the results to similar problems without phase transition.
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    Stochastic model for LFP-electrodes
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2016) Dreyer, Wolfgang; Friz, Peter K.; Gajewski, Paul; Guhlke, Clemens; Maurelli, Mario
    In the framework of non-equilibrium thermodynamics we derive a new model for porous electrodes. The model is applied to LiFePO4 (LFP) electrodes consisting of many LFP particles of nanometer size. The phase transition from a lithium-poor to a lithium-rich phase within LFP electrodes is controlled by surface fluctuations leading to a system of stochastic differential equations. The model is capable to derive an explicit relation between battery voltage and current that is controlled by thermodynamic state variables. This voltage-current relation reveals that in thin LFP electrodes lithium intercalation from the particle surfaces into the LFP particles is the principal rate limiting process. There are only two constant kinetic parameters in the model describing the intercalation rate and the fluctuation strength, respectively. The model correctly predicts several features of LFP electrodes, viz. the phase transition, the observed voltage plateaus, hysteresis and the rate limiting capacity. Moreover we study the impact of both the particle size distribution and the active surface area on the voltagecharge characteristics of the electrode. Finally we carefully discuss the phase transition for varying charging/discharging rates.
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    Planelike interfaces in long-range Ising models and connections with nonlocal minimal surfaces
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2016) Cozzi, Matteo; Dipierro, Serena; Valdinoci, Enrico
    This paper contains three types of results: the construction of ground state solutions for a long-range Ising model whose interfaces stay at a bounded distance from any given hyperplane, the construction of nonlocal minimal surfaces which stay at a bounded distance from any given hyperplane, the reciprocal approximation of ground states for long-range Ising models and nonlocal minimal surfaces. In particular, we establish the existence of ground state solutions for long-range Ising models with planelike interfaces, which possess scale invariant properties with respect to the periodicity size of the environment. The range of interaction of the Hamiltonian is not necessarily assumed to be finite and also polynomial tails are taken into account (i.e. particles can interact even if they are very far apart the one from the other). In addition, we provide a rigorous bridge between the theory of long-range Ising models and that of nonlocal minimal surfaces, via some precise limit result.