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Type: Article × Subject: rheology ×

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    Electrical and melt rheological characterization of PC and co-continuous PC/SAN blends filled with CNTs: Relationship between melt-mixing parameters, filler dispersion, and filler aspect ratio
    (Hoboken, NJ [u.a.] : Wiley, 2018) Liebscher, Marco; Domurath, Jan; Krause, Beate; Saphiannikova, Marina; Heinrich, Gert; Pötschke, Petra
    Electrical and melt rheological properties of melt-mixed polycarbonate (PC) and co-continuous PC/poly(styrene–acrylonitrile) (SAN) blends with carbon nanotubes (CNTs) are investigated. Using two sets of mixing parameters, different states of filler dispersion are obtained. With increasing CNT dispersion, an increase in electrical resistivity near the percolation threshold of PC–CNT composites and (PC + CNT)/SAN blends is observed. This suggests that the higher mixing energies required for better dispersion also result in a more severe reduction of the CNT aspect ratio; this effect was proven by CNT length measurements. Melt rheological studies show higher reinforcing effects for composites with worse dispersion. The Eilers equation, describing the melt viscosity as function of filler content, was used to fit the data and to obtain information about an apparent aspect ratio change, which was in accordance with measured CNT length reduction. Such fitting could be also transferred to the blends and serves for a qualitatively based discussion. © 2017 Wiley Periodicals
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    Drivers of Pine Island Glacier speed-up between 1996 and 2016
    (Katlenburg-Lindau : Copernicus, 2021-1-7) De Rydt, Jan; Reese, Ronja; Paolo, Fernando S.; Gudmundsson, G. Hilmar
    Pine Island Glacier in West Antarctica is among the fastest changing glaciers worldwide. Over the last 2 decades, the glacier has lost in excess of a trillion tons of ice, or the equivalent of 3 mm of sea level rise. The ongoing changes are thought to have been triggered by ocean-induced thinning of its floating ice shelf, grounding line retreat, and the associated reduction in buttressing forces. However, other drivers of change, such as large-scale calving and changes in ice rheology and basal slipperiness, could play a vital, yet unquantified, role in controlling the ongoing and future evolution of the glacier. In addition, recent studies have shown that mechanical properties of the bed are key to explaining the observed speed-up. Here we used a combination of the latest remote sensing datasets between 1996 and 2016, data assimilation tools, and numerical perturbation experiments to quantify the relative importance of all processes in driving the recent changes in Pine Island Glacier dynamics. We show that (1) calving and ice shelf thinning have caused a comparable reduction in ice shelf buttressing over the past 2 decades; that (2) simulated changes in ice flow over a viscously deforming bed are only compatible with observations if large and widespread changes in ice viscosity and/or basal slipperiness are taken into account; and that (3) a spatially varying, predominantly plastic bed rheology can closely reproduce observed changes in flow without marked variations in ice-internal and basal properties. Our results demonstrate that, in addition to its evolving ice thickness, calving processes and a heterogeneous bed rheology play a key role in the contemporary evolution of Pine Island Glacier.