Search Results

Now showing 1 - 4 of 4
  • Item
    A gradient system with a wiggly energy and relaxed EDP-convergence
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Dondl, Patrick; Frenzel, Thomas; Mielke, Alexander
    If gradient systems depend on a microstructure, we want to derive a macroscopic gradient structure describing the effective behavior of the microscopic system. We introduce a notion of evolutionary Gamma-convergence that relates the microscopic energy and the microscopic dissipation potential with their macroscopic limits via Gammaconvergence. We call this notion relaxed EDP-convergence since the special structure of the dissipation functional may not be preserved under Gamma-convergence. However, by investigating the kinetic relation we derive the macroscopic dissipation potential.
  • Item
    Coarse-graining via EDP-convergence for linear fast-slow reaction systems
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2019) Mielke, Alexander; Stephan, Artur
    We consider linear reaction systems with slow and fast reactions, which can be interpreted as master equations or Kolmogorov forward equations for Markov processes on a finite state space. We investigate their limit behavior if the fast reaction rates tend to infinity, which leads to a coarse-grained model where the fast reactions create microscopically equilibrated clusters, while the exchange mass between the clusters occurs on the slow time scale. Assuming detailed balance the reaction system can be written as a gradient flow with respect to the relative entropy. Focusing on the physically relevant cosh-type gradient structure we show how an effective limit gradient structure can be rigorously derived and that the coarse-grained equation again has a cosh-type gradient structure. We obtain the strongest version of convergence in the sense of the Energy-Dissipation Principle (EDP), namely EDP-convergence with tilting.
  • Item
    EDP-convergence for nonlinear fast-slow reaction systems with detailed balance
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2020) Mielke, Alexander; Peletier, Mark A.; Stephan, Artur
    We consider nonlinear reaction systems satisfying mass-action kinetics with slow and fast reactions. It is known that the fast-reaction-rate limit can be described by an ODE with Lagrange multipliers and a set of nonlinear constraints that ask the fast reactions to be in equilibrium. Our aim is to study the limiting gradient structure which is available if the reaction system satisfies the detailed-balance condition. The gradient structure on the set of concentration vectors is given in terms of the relative Boltzmann entropy and a cosh-type dissipation potential. We show that a limiting or effective gradient structure can be rigorously derived via EDP convergence, i.e. convergence in the sense of the Energy-Dissipation Principle for gradient flows. In general, the effective entropy will no longer be of Boltzmann type and the reactions will no longer satisfy mass-action kinetics.
  • Item
    Effective diffusion in thin structures via generalized gradient systems and EDP-convergence
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2019) Frenzel, Thomas; Liero, Matthias
    The notion of Energy-Dissipation-Principle convergence (EDP-convergence) is used to derive effective evolution equations for gradient systems describing diffusion in a structure consisting of several thin layers in the limit of vanishing layer thickness. The thicknesses of the sublayers tend to zero with different rates and the diffusion coefficients scale suitably. The Fokker--Planck equation can be formulated as gradient-flow equation with respect to the logarithmic relative entropy of the system and a quadratic Wasserstein-type gradient structure. The EDP-convergence of the gradient system is shown by proving suitable asymptotic lower limits of the entropy and the total dissipation functional. The crucial point is that the limiting evolution is again described by a gradient system, however, now the dissipation potential is not longer quadratic but is given in terms of the hyperbolic cosine. The latter describes jump processes across the thin layers and is related to the Marcelin--de Donder kinetics.