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- ItemUnsaturated deformable porous media flow with phase transition(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Krejčí, Pavel; Rocca, Elisabetta; Sprekels, JürgenIn the present paper, a continuum model is introduced for fluid flow in a deformable porous medium, where the fluid may undergo phase transitions. Typically, such problems arise in modeling liquid-solid phase transformations in groundwater flows. The system of equations is derived here from the conservation principles for mass, momentum, and energy and from the Clausius-Duhem inequality for entropy. It couples the evolution of the displacement in the matrix material, of the capillary pressure, of the absolute temperature, and of the phase fraction. Mathematical results are proved under the additional hypothesis that inertia effects and shear stresses can be neglected. For the resulting highly nonlinear system of two PDEs, one ODE and one ordinary differential inclusion with natural initial and boundary conditions, existence of global in time solutions is proved by means of cut-off techniques and suitable Moser-type estimates.
- ItemAnalysis of a thermodynamically consistent Navier--Stokes--Cahn--Hilliard model(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2020) Lasarzik, RobertIn this paper, existence of generalized solutions to a thermodynamically consistent Navier--Stokes--Cahn--Hilliard model introduced in [19] is proven in any space dimension. The generalized solvability concepts are measure-valued and dissipative solutions. The measure-valued formulation incorporates an entropy inequality and an energy inequality instead of an energy balance in a nowadays standard way, the Gradient flow of the internal variable is fulfilled in a weak and the momentum balance in a measure-valued sense. In the dissipative formulation, the distributional relations of the momentum balance and the energy as well as entropy inequality are replaced by a relative energy inequality. Additionally, we prove the weak-strong uniqueness of the proposed solution concepts and that all generalized solutions with additional regularity are indeed strong solutions.
- ItemModelling compressible electrolytes with phase transition(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2014) Dreyer, Wolfgang; Giesselmann, Jan; Kraus, ChristianeA novel thermodynamically consistent diffuse interface model is derived for compressible electrolytes with phase transitions. The fluid mixtures may consist of N constituents with the phases liquid and vapor, where both phases may coexist. In addition, all constituents may consist of polarizable and magnetizable matter. Our introduced thermodynamically consistent diffuse interface model may be regarded as a generalized model of Allen-Cahn/Navier-Stokes/Poisson type for multi-component flows with phase transitions and electrochemical reactions. For the introduced diffuse interface model, we investigate physically admissible sharp interface limits by matched asymptotic techniques. We consider two scaling regimes, i.e. a non-coupled and a coupled regime, where the coupling takes place between the smallness parameter in the Poisson equation and the width of the interface. We recover in the sharp interface limit a generalized Allen-Cahn/Euler/Poisson system for mixtures with electrochemical reactions in the bulk phases equipped with admissible interfacial conditions. The interfacial conditions satisfy, for instance, a generalized Gibbs-Thomson law and a dynamic Young-Laplace law.
- ItemA diffuse interface model for quasi-incrompressible flows : sharp interface limits and numerics(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2012) Aki, Gonca; Daube, Johannes; Dreyer, Wolfgang; Giesselmann, Jan; Kränkel, Mirko; Kraus, ChristianeIn this contribution, we investigate a diffuse interface model for quasi–incompressible flows. We determine corresponding sharp interface limits of two different scalings. The sharp interface limit is deduced by matched asymptotic expansions of the fields in powers of the interface. In particular, we study solutions of the derived system of inner equations and discuss the results within the general setting of jump conditions for sharp interface models. Furthermore, we treat, as a subproblem, the convective Cahn–Hilliard equation numerically by a Local Discontinuous Galerkin scheme.
- ItemInterface conditions for limits of the Navier-Stokes-Korteweg model(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2008) Hermsdörfer, Katharina; Kraus, Christiane; Kröner, DietmarIn this contribution we will study the behaviour of the pressure across phase boundaries in liquid-vapour flows. As mathematical model we will consider the static version of the Navier-Stokes-Korteweg model which belongs to the class of diffuse interface models. From this static equation a formula for the pressure jump across the phase interface can be derived. If we perform then the sharp interface limit we see that the resulting interface condition for the pressure seems to be inconsistent with classical results of hydrodynamics. Therefore we will present two approaches to recover the results of hydrodynamics in the sharp interface limit at least for special situ
- ItemSurface induced phase separation of a swelling hydrogel(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2018) Hennessy, Matthew G.; Münch, Andreas; Wagner, BarbaraWe present a formulation of the free boundary problem for a hydrogel that accounts for the interfacial free energy and finite strain due to the large deformation of the polymer network during solvent transport across the free boundary. For the geometry of an initially dry layer fixed at a rigid substrate, our model predicts a phase transition when a critical value of the solvent concentration has been reached near the free boundary. A one-dimensional case study shows that depending on the flux rate at the free boundary an initial saturation front is followed by spinodal decomposition of the hydrogel and the formation of an interfacial front that moves through the layer. Moreover, increasing the shear modulus of the elastic network delays or even suppresses phase separation.
- ItemA compressible mixture model with phase transition(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2013) Dreyer, Wolfgang; Giesselmann, Jan; Kraus, ChristianeWe introduce a new thermodynamically consistent diffuse interface model of AllenCahn/NavierStokes type for multi-component flows with phase transitions and chemical reactions. For the introduced diffuse interface model, we investigate physically admissible sharp interface limits by matched asymptotic techniques. We consider two scaling regimes, i.e. a non-dissipative and a dissipative regime, where we recover in the sharp interface limit a generalized Allen-Cahn/Euler system for mixtures with chemical reactions in the bulk phases equipped with admissible interfacial conditions. The interfacial conditions satify, for instance, a YoungLaplace and a Stefan type law.
- ItemA large-deviations approach to gelation(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2019) Andreis, Luisa; König, Wolfgang; Patterson, RobertA @large-deviations principle (LDP) is derived for the state, at fixed time, of the multiplicative coalescent in the large particle number limit. The rate function is explicit and describes each of the three parts of the state: microscopic, mesoscopic and macroscopic. In particular, it clearly captures the well known gelation phase transition given by the formation of a particle containing a positive fraction of the system mass at time t = 1. Via a standard map of the multiplicative coalescent onto a time-dependent version of the Erdos-Rényi random graph, our results can also be rephrased as an LDP for the component sizes in that graph. Our proofs rely on estimates and asymptotics for the probability that smaller Erdos-Rényi graphs are connected.
- ItemOn unwanted nucleation phenomena at the wall of a VGF chamber(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2008) Dreyer, Wolfgang; Duderstadt, Frank; Eichler, Stefan; Naldzhieva, MargaritaThis is preliminary study on a phenomenon that happens during crystal growth of GaAs in a vertical gradient freeze (VGF) device. Here unwanted polycrystals nucleate at the chamber wall and move into the interior of the crystal. This happens within an undercooled region in the vicinity of the triple point, where the liquid-solid interface meets the chamber wall. The size and shape of that region is modelled by the Gibbs-Thomson law, which will be rederived in this paper. Hereafter we identify the crucial parameter, whose proper adjustment may minimize the undercooled region.
- ItemBilinear coagulation equations(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2019) Heydecker, Daniel; Patterson, Robert I.A.We consider coagulation equations of Smoluchowski or Flory type where the total merge rate has a bilinear form π(y) · Aπ (x) for a vector of conserved quantities π, generalising the multiplicative kernel. For these kernels, a gelation transition occurs at a finite time tg ∈ (0,∞), which can be given exactly in terms of an eigenvalue problem in finite dimensions. We prove a hydrodynamic limit for a stochastic coagulant, including a corresponding phase transition for the largest particle, and exploit a coupling to random graphs to extend analysis of the limiting process beyond the gelation time.