3 results
Search Results
Now showing 1 - 3 of 3
- ItemGreen synthesis of hydrotalcite from untreated magnesium oxide and aluminum hydroxide(London [u.a.] : Taylor and Francis, 2018) Labuschagné, F.J.W.J.; Wiid, A.; Venter, H.P.; Gevers, B.R.; Leuteritz, A.The influence of reaction temperature and time on the hydrothermal dissolution-precipitation synthesis of hydrotalcite was investigated. Untreated MgO, Al(OH)3 and NaHCO3 were used. An industrially beneficial, economically favourable, environmentally friendly, zero effluent synthesis procedure was devised based on green chemistry principles, in which the salt-rich effluent typically produced was eliminated by regenerating the sodium bicarbonate in a full recycle process. It was found that the formation of hydromagnesite dominates at low temperatures independent of reaction time. With an increase in reaction time and temperature, hydromagnesite decomposes to form magnesite. At low temperatures, the formation of hydrotalcite is limited by the solubility of the Al(OH)3. To achieve a hydrotalcite yield of 96%, a reaction temperature of 160°C for 5 h is required. A yield higher than 99% was achieved at 180°C and 5 h reaction time, producing an layered double hydroxide with high crystallinity and homogeneity.
- ItemThe stratorotational instability of Taylor-Couette flows with moderate Reynolds numbers(London [u.a.] : Taylor and Francis, 2017) Rüdiger, G.; Seelig, T.; Schultz, M.; Gellert, M.; Egbers, C.; Harlander, U.In view of new experimental data the instability against adiabatic nonaxisymmetric perturbations of a Taylor-Couette flow with an axial density stratification is considered in dependence of the Reynolds number (Re) of rotation and the Brunt-Väisälä number (Rn) of the stratification. The flows at and beyond the Rayleigh limit become unstable between a lower and an upper Reynolds number (for fixed Rn). The rotation can thus be too slow or too fast for the stratorotational instability. The upper Reynolds number above which the instability decays, has its maximum value for the potential flow (driven by cylinders rotating according to the Rayleigh limit) and decreases strongly for flatter rotation profiles finally leaving only isolated islands of instability in the (Rn/Re) map. The maximal possible rotation ratio μmax only slightly exceeds the shear value of the quasi-uniform flow with Uφ≃const. Along and between the lines of neutral stability the wave numbers of the instability patterns for all rotation laws beyond the Rayleigh limit are mainly determined by the Froude number Fr which is defined by the ratio between Re and Rn. The cells are highly prolate for Fr > 1 so that measurements for too high Reynolds numbers become difficult for axially bounded containers. The instability patterns migrate azimuthally slightly faster than the outer cylinder rotates.
- ItemLaser additive manufacturing of Miura-origami tube inspired quasi-zero stiffness metamaterial with prominent longitudinal wave propagation(London [u.a.] : Taylor and Francis, 2023) Wan, Haoran; Chen, Hongyu; Wang, Yonggang; Fang, Xiang; Liu, Yang; Kosiba, KonradOrigami metamaterials have become frontiers of research in many disciplines due to their infinite design space, simple size variation, and topologically variable properties. In this study, a novel metamaterial inspired by Miura-origami tubes with a complex quasi-zero-stiffness (QZS) structure was fabricated via laser powder bed fusion (LPBF). The unit of the QZS metamaterial consists of a two-layer quadrilateral frame and two vertical springs attached to its diagonal points. The geometric accuracy, densification level and mechanical properties of the QZS parts fabricated at various processing conditions were investigated and the optimised processing parameters were determined. The displacement response of the QZS parts was analysed by experiments in conjunction with simulation analysis. The results show that the LPBF-fabricated QZS metamaterials form four extra-wide longitudinal wave band gaps under low frequencies from 660 Hz to 2500 Hz. The proposed LPBF-fabricated QZS metamaterial shows great potential in impeding the longitudinal vibration of engineering structures.