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Beller, Matthias
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Junge, Kathrin
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Leischner, Thomas
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Liu, Weiping
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hydrogenation
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anti-Markovnikov
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cobalt
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homogeneous catalysis
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Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition 59 (2020), Nr. 28
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A General Regioselective Synthesis of Alcohols by Cobalt-Catalyzed Hydrogenation of Epoxides
(
Weinheim : Wiley-VCH,
2020
)
Liu, Weiping
;
Leischner, Thomas
;
Li, Wu
;
Junge, Kathrin
;
Beller, Matthias
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A straightforward methodology for the synthesis of anti-Markovnikov-type alcohols is presented. By using a specific cobalt triphos complex in the presence of Zn(OTf)2 as an additive, the hydrogenation of epoxides proceeds with high yields and selectivities. The described protocol shows a broad substrate scope, including multi-substituted internal and terminal epoxides, as well as a good functional-group tolerance. Various natural-product derivatives, including steroids, terpenoids, and sesquiterpenoids, gave access to the corresponding alcohols in moderate-to-excellent yields. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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