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- ItemGradual pressure-induced enhancement of magnon excitations in CeCoSi(Woodbury, NY : Inst., 2020) Nikitin, S.E.; Franco, D.G.; Kwon, J.; Bewley, R.; Podlesnyak, A.; Hoser, A.; Koza, M.M.; Geibel, C.; Stockert, O.CeCoSi is an intermetallic antiferromagnet with a very unusual temperature-pressure phase diagram: At ambient pressure it orders below TN=8.8K, while application of hydrostatic pressure induces a new magnetically ordered phase with exceptionally high transition temperature of ∼40K at 1.5 GPa. We studied the magnetic properties and the pressure-induced magnetic phase of CeCoSi by means of elastic and inelastic neutron scattering (INS) and heat capacity measurements. At ambient pressure CeCoSi orders into a simple commensurate AFM structure with a reduced ordered moment of only mCe=0.37(6)μB. Specific heat and low-energy INS indicate a significant gap in the low-energy magnon excitation spectrum in the antiferromagnetic phase, with the CEF excitations located above 10 meV. Hydrostatic pressure gradually shifts the energy of the magnon band towards higher energies and the temperature dependence of the magnons measured at 1.5 GPa is consistent with the phase diagram. Moreover, the CEF excitations are also drastically modified under pressure. © 2020 authors.
- ItemInternal and external green-blue agricultural water footprints of nations, and related water and land savings through trade(Chichester : John Wiley and Sons Ltd, 2011) Fader, M.; Gerten, D.; Thammer, M.; Heinke, J.; Lotze-Campen, H.; Lucht, W.; Cramer, W.The need to increase food production for a growing world population makes an assessment of global agricultural water productivities and virtual water flows important. Using the hydrology and agro-biosphere model LPJmL, we quantify at 0.5° resolution the amount of blue and green water (irrigation and precipitation water) needed to produce one unit of crop yield, for 11 of the world's major crop types. Based on these, we also quantify the agricultural water footprints (WFP) of all countries, for the period 1998-2002, distinguishing internal and external WFP (virtual water imported from other countries) and their blue and green components, respectively. Moreover, we calculate water savings and losses, and for the first time also land savings and losses, through international trade with these products. The consistent separation of blue and green water flows and footprints shows that green water globally dominates both the internal and external WFP (84 % of the global WFP and 94 % of the external WFP rely on green water). While no country ranks among the top ten with respect to all water footprints calculated here, Pakistan and Iran demonstrate high absolute and per capita blue WFP, and the US and India demonstrate high absolute green and blue WFPs. The external WFPs are relatively small (6 % of the total global blue WFP, 16 % of the total global green WFP). Nevertheless, current trade of the products considered here saves significant water volumes and land areas (∼263 km3 and ∼41 Mha, respectively, equivalent to 5 % of the sowing area of the considered crops and 3.5 % of the annual precipitation on this area). Relating the proportions of external to internal blue/green WFP to the per capita WFPs allows recognizing that only a few countries consume more water from abroad than from their own territory and have at the same time above-average WFPs. Thus, countries with high per capita water consumption affect mainly the water availability in their own country. Finally, this study finds that flows/savings of both virtual water and virtual land need to be analysed together, since they are intrinsically related.
- ItemImpacts of a capillary barrier on infiltration and subsurface stormflow in layered slope deposits monitored with 3-D ERT and hydrometric measurements(Munich : EGU, 2017) Hübner, Rico; Günther, Thomas; Heller, Katja; Noell, Ursula; Kleber, ArnoIdentifying principles of water movement in the shallow subsurface is crucial for adequate process-based hydrological models. Hillslopes are the essential interface for water movement in catchments. The shallow subsurface on slopes typically consists of different layers with varying characteristics. The aim of this study was to draw conclusions about the infiltration behaviour, to identify water flow pathways and derive some general interpretations for the validity of the water movement on a hillslope with periglacial slope deposits (cover beds), where the layers differ in their sedimentological and hydrological properties. Especially the described varying influence of the basal layer (LB) as an impeding layer on the one hand and as a remarkable pathway for rapid subsurface stormflow on the other. We used a time lapse 3-D electrical resistivity tomography (ERT) approach combined with punctual hydrometric data to trace the spreading and the progression of an irrigation plume in layered slope deposits during two irrigation experiments. This multi-technical approach enables us to connect the high spatial resolution of the 3-D ERT with the high temporal resolution of the hydrometric devices. Infiltration through the uppermost layer was dominated by preferential flow, whereas the water flow in the deeper layers was mainly matrix flow. Subsurface stormflow due to impeding characteristic of the underlying layer occurs in form of "organic layer interflow" and at the interface to the first basal layer (LB1). However, the main driving factor for subsurface stormflow is the formation of a capillary barrier at the interface to the second basal layer (LB2). The capillary barrier prevents water from entering the deeper layer under unsaturated conditions and diverts the seepage water according to the slope inclination. With higher saturation, the capillary barrier breaks down and water reaches the highly conductive deeper layer. This highlights the importance of the capillary barrier effect for the prevention or activation of different flow pathways under variable hydrological conditions.