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- ItemRecent advances in single molecule magnetism of dysprosium-metallofullerenes(Cambridge : Royal Society of Chemistry, 2019) Spree, L.; Popov, A.A.This article outlines the magnetic properties of single molecule magnets based on Dy-encapsulating endohedral metallofullerenes. The factors that govern these properties, such as the influence of different non-metal species in clusterfullerenes, the cage size, and cage isomerism are discussed, as well as the recent successful isolation of dimetallofullerenes with unprecedented magnetic properties. Finally, recent advances towards the organization of endohedral metallofullerenes in 1D, 2D, and 3D ordered structures with potential for devices are reviewed.
- ItemMagnetic flux-trapping of anisotropic-grown Y-Ba-Cu-O bulk superconductors during and after pulsed-field magnetizing processes(Milton Park : Taylor & Francis, 2014) Oka, T.; Yamada, Y.; Horiuchi, T.; Ogawa, J.; Fukui, S.; Sato, T.; Yokoyama, K.; Langer, M.The magnetic flux penetration into the melt-textured Y-Ba-Cu-O high temperature superconducting bulk magnets were precisely evaluated during and after the pulsed field magnetization processes operated at 30 K. The bulk magnets were carefully fabricated by the cold seeding method with use of a single and a pair of seed crystals composed of the Nd-Ba-Cu-O thin films. These seed crystals were put on the top surfaces of the precursors to let the large grains grow during the heat treatments. We observed the flux penetrations which occurred in the lower applied-field regions at around 3.1 T for the samples bearing the twin seeds than those of the single-seeded crystals at around 3.8 T. This means that the magnetic fluxes are capable of invading into the twin-seeded samples more easily than the single-seeds. It suggests that the anisotropic grain growths of parallel and normal to the rows of seed crystals affects the variations of Jc values with different distributions of the pinning centers, results in the preferential paths for the invading magnetic fluxes.
- ItemRobust metastable skyrmions with tunable size in the chiral magnet FePtMo3 N(Woodbury, NY : Inst., 2020) Sukhanov, A.S.; Heinemann, A.; Kautzsch, L.; Bocarsly, J.D.; Wilson, S.D.; Felser, C.; Inosov, D.S.The synthesis of new materials that can host magnetic skyrmions and their thorough experimental and theoretical characterization are essential for future technological applications. The β-Mn-type compound FePtMo3N is one such novel material that belongs to the chiral space group P4132, where the antisymmetric Dzyaloshinskii-Moriya interaction is allowed due to the absence of inversion symmetry. We report the results of small-angle neutron scattering (SANS) measurements of FePtMo3N and demonstrate that its magnetic ground state is a long-period spin helix with a Curie temperature of 222 K. The magnetic field-induced redistribution of the SANS intensity showed that the helical structure transforms to a lattice of skyrmions at ∼13 mT at temperatures just below TC. Our key observation is that the skyrmion state in FePtMo3N is robust against field cooling down to the lowest temperatures. Moreover, once the metastable state is prepared by field cooling, the skyrmion lattice exists even in zero field. Furthermore, we show that the skyrmion size in FePtMo3N exhibits high sensitivity to the sample temperature and can be continuously tuned between 120 and 210 nm. This offers different prospects in the control of topological properties of chiral magnets. © 2020 authors. Published by the American Physical Society.
- ItemField-Angle-Resolved Magnetic Excitations as a Probe of Hidden-Order Symmetry in CeB6(College Park, Md. : APS, 2020) Portnichenko, P.Y.; Akbari, A.; Nikitin, S.E.; Cameron, A.S.; Dukhnenko, A.V.; Filipov, V.B.; Shitsevalova, N.Yu.; Čermák, P.; Radelytskyi, I.; Schneidewind, A.; Ollivier, J.; Podlesnyak, A.; Huesges, Z.; Xu, J.; Ivanov, A.; Sidis, Y.; Petit, S.; Mignot, J.-M.; Thalmeier, P.; Inosov, D.S.In contrast to magnetic order formed by electrons' dipolar moments, ordering phenomena associated with higher-order multipoles (quadrupoles, octupoles, etc.) are more difficult to characterize because of the limited choice of experimental probes that can distinguish different multipolar moments. The heavy-fermion compound CeB6 and its La-diluted alloys are among the best-studied realizations of the long-range-ordered multipolar phases, often referred to as "hidden order."Previously, the hidden order in phase II was identified as primary antiferroquadrupolar and field-induced octupolar order. Here, we present a combined experimental and theoretical investigation of collective excitations in phase II of CeB6. Inelastic neutron scattering (INS) in fields up to 16.5 T reveals a new high-energy mode above 14 T in addition to the low-energy magnetic excitations. The experimental dependence of their energy on the magnitude and angle of the applied magnetic field is compared to the results of a multipolar interaction model. The magnetic excitation spectrum in a rotating field is calculated within a localized approach using the pseudospin representation for the Γ8 states. We show that the rotating-field technique at fixed momentum can complement conventional INS measurements of the dispersion at a constant field and holds great promise for identifying the symmetry of multipolar order parameters and the details of intermultipolar interactions that stabilize hidden-order phases. © 2020 authors. Published by the American Physical Society.
- ItemTwo-dimensional ferromagnetic extension of a topological insulator(College Park, MD : APS, 2023) Kagerer, P.; Fornari, C. I.; Buchberger, S.; Tschirner, T.; Veyrat, L.; Kamp, M.; Tcakaev, A. V.; Zabolotnyy, V.; Morelhão, S. L.; Geldiyev, B.; Müller, S.; Fedorov, A.; Rienks, E.; Gargiani, P.; Valvidares, M.; Folkers, L. C.; Isaeva, A.; Büchner, B.; Hinkov, V.; Claessen, R.; Bentmann, H.; Reinert, F.Inducing a magnetic gap at the Dirac point of the topological surface state (TSS) in a three-dimensional (3D) topological insulator (TI) is a route to dissipationless charge and spin currents. Ideally, magnetic order is present only at the surface, as through proximity of a ferromagnetic (FM) layer. However, experimental evidence of such a proximity-induced Dirac mass gap is missing, likely due to an insufficient overlap of TSS and the FM subsystem. Here, we take a different approach, namely ferromagnetic extension (FME), using a thin film of the 3D TI Bi2Te3, interfaced with a monolayer of the lattice-matched van der Waals ferromagnet MnBi2Te4. Robust 2D ferromagnetism with out-of-plane anisotropy and a critical temperature of Tc≈15 K is demonstrated by x-ray magnetic dichroism and electrical transport measurements. Using angle-resolved photoelectron spectroscopy, we observe the opening of a sizable magnetic gap in the 2D FM phase, while the surface remains gapless in the paramagnetic phase above Tc. Ferromagnetic extension paves the way to explore the interplay of strictly 2D magnetism and topological surface states, providing perspectives for realizing robust quantum anomalous Hall and chiral Majorana states.
- ItemMagnetic warping in topological insulators(College Park, MD : APS, 2022) Naselli, Gabriele; Moghaddam, Ali G.; Di Napoli, Solange; Vildosola, Verónica; Fulga, Ion Cosma; van den Brink, Jeroen; Facio, Jorge I.We analyze the electronic structure of topological surface states in the family of magnetic topological insulators MnBi2nTe3n+1. We show that, at natural-cleavage surfaces, the Dirac cone warping changes its symmetry from hexagonal to trigonal at the magnetic ordering temperature. In particular, an energy splitting develops between the surface states of the same band index but opposite surface momenta upon formation of the long-range magnetic order. As a consequence, measurements of such energy splittings constitute a simple protocol to detect the magnetic ordering via the surface electronic structure, alternative to the detection of the surface magnetic gap. Interestingly, while the latter signals a nonzero surface magnetization, the trigonal warping predicted here is, in addition, sensitive to the direction of the surface magnetic flux. Our results may be particularly useful when the Dirac point is buried in the projection of the bulk states, caused by certain terminations of the crystal or in hole-doped systems, since in both situations the surface magnetic gap itself is not accessible in photoemission experiments.
- ItemReversible magnetism switching of iron oxide nanoparticle dispersions by controlled agglomeration(Cambridge : Royal Society of Chemistry, 2021) Müssig, Stephan; Kuttich, Björn; Fidler, Florian; Haddad, Daniel; Wintzheimer, Susanne; Kraus, Tobias; Mandel, KarlThe controlled agglomeration of superparamagnetic iron oxide nanoparticles (SPIONs) was used to rapidly switch their magnetic properties. Small-angle X-ray scattering (SAXS) and dynamic light scattering showed that tailored iron oxide nanoparticles with phase-changing organic ligand shells agglomerate at temperatures between 5 °C and 20 °C. We observed the concurrent change in magnetic properties using magnetic particle spectroscopy (MPS) with a temporal resolution on the order of seconds and found reversible switching of magnetic properties of SPIONs by changing their agglomeration state. The non-linear correlation between magnetization amplitude from MPS and agglomeration degree from SAXS data indicated that the agglomerates' size distribution affected magnetic properties.
- ItemPhotoemission electron microscopy of magneto-ionic effects in La0.7Sr0.3MnO3(Melville, NY : AIP Publ., 2020) Wilhelm, Marek; Giesen, Margret; Duchoň, Tomáš; Moors, Marco; Mueller, David N.; Hackl, Johanna; Baeumer, Christoph; Hamed, Mai Hussein; Cao, Lei; Zhang, Hengbo; Petracic, Oleg; Glöß, Maria; Cramm, Stefan; Nemšák, Slavomír; Wiemann, Carsten; Dittmann, Regina; Schneider, Claus M.; Müller, MartinaMagneto-ionic control of magnetism is a promising route toward the realization of non-volatile memory and memristive devices. Magneto-ionic oxides are particularly interesting for this purpose, exhibiting magnetic switching coupled to resistive switching, with the latter emerging as a perturbation of the oxygen vacancy concentration. Here, we report on electric-field-induced magnetic switching in a La0.7Sr0.3MnO3 (LSMO) thin film. Correlating magnetic and chemical information via photoemission electron microscopy, we show that applying a positive voltage perpendicular to the film surface of LSMO results in the change in the valence of the Mn ions accompanied by a metal-to-insulator transition and a loss of magnetic ordering. Importantly, we demonstrate that the voltage amplitude provides granular control of the phenomena, enabling fine-tuning of the surface electronic structure. Our study provides valuable insight into the switching capabilities of LSMO that can be utilized in magneto-ionic devices. © 2020 Author(s).
- ItemShapeable magnetoelectronics(Melville, NY : American Inst. of Physics, 2016) Makarov, Denys; Melzer, Michael; Karnaushenko, Daniil; Schmidt, Oliver G.Inorganic nanomembranes are shapeable (flexible, printable, and even stretchable) and transferrable to virtually any substrate. These properties build the core concept for new technologies, which transform otherwise rigid high-speed devices into their shapeable counterparts. This research is motivated by the eagerness of consumer electronics towards being thin, lightweight, flexible, and even wearable. The realization of this concept requires all building blocks as we know them from rigid electronics (e.g., active elements, optoelectronics, magnetoelectronics, and energy storage) to be replicated in the form of (multi)functional nanomembranes, which can be reshaped on demand after fabrication. There are already a variety of shapeable devices commercially available, i.e., electronic displays, energy storage elements, and integrated circuitry, to name a few. From the beginning, the main focus was on the fabrication of shapeable high-speed electronics and optoelectronics. Only very recently, a new member featuring magnetic functionalities was added to the family of shapeable electronics. With their unique mechanical properties, the shapeable magnetic field sensor elements readily conform to ubiquitous objects of arbitrary shapes including the human skin. This feature leads electronic skin systems beyond imitating the characteristics of its natural archetype and extends their cognition to static and dynamic magnetic fields that by no means can be perceived by human beings naturally. Various application fields of shapeable magnetoelectronics are proposed. The developed sensor platform can equip soft electronic systems with navigation, orientation, motion tracking, and touchless control capabilities. A variety of novel technologies, such as smart textiles, soft robotics and actuators, active medical implants, and soft consumer electronics, will benefit from these new magnetic functionalities. This review reflects the establishment of shapeable magnetic sensorics, describing the entire development from the first attempts to verify the functional concept to the realization of ready-to-use highly compliant and strain invariant sensor devices with remarkable robustness.
- ItemThe interplay between spin densities and magnetic superexchange interactions: Case studies of monoand trinuclear bis(oxamato)-type complexes(Frankfurt am Main : Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2017) Aliabadi, A.; Büchner, B.; Kataev, V.; Rüffer, T.For future molecular spintronic applications the possibility to modify and tailor the magnetic properties of transition-metal complexes is very promising. One of such possibilities is given by the countless derivatization offered by carbon chemistry. They allow for altering chemical structures and, in doing so, to tune magnetic properties of molecular spin-carrying compounds. With emphasis on the interplay of the spin density distribution of mononuclear and magnetic superexchange couplings of trinuclear bis(oxamato)- type complexes we review on efforts on such magneto-structural correlations.