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Now showing 1 - 5 of 5
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    Incorporation of nitrogen into TiO2 thin films during PVD processes
    (Bristol : Institute of Physics Publishing, 2014) Asenova, I.; Manova, D.; Mändl, S.
    In this paper we investigate the possibility of incorporating nitrogen into amorphous, photocatalytic TiO2 thin films, prepared at room temperature, during the growth process. The aim is to reduce the bandgap of the UV active thin films. Physical vapor deposition experiments employing a titanium vacuum arc with gas backfill ranging from pure oxygen to pure nitrogen, are carried out. The resulting films are characterized for chemical composition, phase composition, optical properties and hydrophilicity in order to determine a correlation between gas composition and thin film properties. The experimental results point that a visible change in the band structure of the deposited layers is achieved.
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    Combinatorial synthesis of (YxGd1-x)Ba2Cu3Ox superconducting thin films
    (Amsterdam [u.a.] : Elsevier, 2012) Kirchner, A.; Erbe, M.; Freudenberg, T.; Hühne, R.; Feys, J.; Van Driessche, I.; Schultz, L.; Holzapfel, B.
    Environmentally friendly water-based YBa2Cu3Ox (YBCO) and GdBa2Cu3Ox (GdBCO) precursor solutions were synthesized to realize thin films by chemical solution deposition. Pure YBCO and GdBCO precursor solutions were used for ink plotting on SrTiO3 substrates and subsequent thermal treatment at the corresponding crystallization temperature. Phase formation of Gd123 requires a higher crystallization temperature of 840 °C compared to the Y123 phase. The critical temperature of YBCO films is about 92 K with a sharp transition into the superconducting state. Micro liter sized ink volumes of YBCO and GdBCO were successfully mixed for two-dimensional ink plotting of a (YxGd1-x)Ba2Cu3Ox film library. A homogeneous surface and no indication of a-axis growth were found in all mixed films.
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    Supramolecular assemblies of block copolymers as templates for fabrication of nanomaterials
    (New York, NY [u.a.] : Elsevier, 2011) Nandan, B.; Kuila, B.K.; Stamm, M.
    Self-assembled polymeric systems have played an important role as templates for nanofabrication; they offer nanotemplates with different morphologies and tunable sizes, are easily removed after reactions, and could be further modified with different functional groups to enhance the interactions. Among the various self-assembled polymeric systems, block copolymer supramolecular assemblies have received considerable attention because of the inherent processing advantages. These supramolecular assemblies are formed by the non-covalent interactions of one of the blocks of the block copolymer with a low molar-mass additive. Selective extraction of the additive leads to porous membranes or nano-objects which could then be used as templates for nanofabrication leading to a variety of ordered organic/inorganic nanostructures. In this feature article, we present an over-view of the recent developments in this area with a special focus on some examples from our group.
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    Investigation of the strain-sensitive superconducting transition of BaFe1.8Co0.2As2 thin films utilizing piezoelectric substrates
    (Milton Park : Taylor & Francis, 2014) Trommler, S.; Hänisch, J.; Iida, K.; Kurth, F.; Schultz, L.; Holzapfel, B.; Hühne, R.
    The preparation of biaxially textured BaFe1.8Co0.2As2 thin films has been optimized on MgO single crystals and transfered to piezoelectric (001) Pb(Mg1/3Nb2/3)0.72Ti0.28O3 substrates. By utilizing the inverse piezoelectric effect the lattice parameter of these substrates can be controlled applying an electric field, leading to a induction of biaxial strain into the superconducting layer. High electric fields were used to achieve a total strain of up to 0.05% at low temperatures. A sharpening of the resistive transition and a shift of about 0.6 K to higher temperatures was found at a compressive strain of 0.035%.
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    Femtosecond spectroscopy in a nearly optimally doped Fe-based superconductors FeSe0.5Te0.5 and Ba(Fe 1-xCox)2As2/Fe thin film
    (Bristol : Institute of Physics Publishing, 2014) Bonavolontà, C.; Parlato, L.; De, Lisio, C.; Valentino, M.; Pepe, G.P.; Kazumasa, I.; Kurth, F.; Bellingeri, E.; Pallecchi, I.; Putti, M.; Ferdeghini, C.; Ummarino, G.A.; Laviano, F.
    Femtosecond spectroscopy has been used to investigate the quasi-particle relaxation times in nearly optimally doped Fe-based superconductors FeSe 0.5Te0.5 and optimally doped Ba-122 thin films growth on a Fe buffer layer. Experimental results concerning the temperature dependence of the relaxation time of such pnictides both in the superconducting state are now presented and discussed. Modelling the T-dependence of relaxation times an estimation of both electron-phonon constant and superconducting energy gap in the excitation spectrum of both Fe(Se,Te) and Ba-122 compounds is obtained.