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- ItemAdhesion behavior of polymer networks with tailored mechanical properties using spherical and flat contacts(Cambridge : Cambridge University Press, 2013) Lakhera, Nishant; Graucob, Annalena; Schneider, Andreas S.; Kroner, Elmar; Micciché, Maurizio; Arzt, Eduard; Frick, Carl P.Four acrylate-based networks were developed such that they possessed similar glass transition temperature (~-37 °C) but varied in material stiffness at room temperature by an order of magnitude (2-12 MPa). Thermo-mechanical and adhesion testing were performed to investigate the effect of elastic modulus on adhesion profiles of the developed samples. Adhesion experiments with a spherical probe revealed no dependency of the pull-off force on material modulus as predicted by the Johnson, Kendall, and Roberts theory. Results obtained using a flat probe showed that the pull-off force increases linearly with an increase in the material modulus, which matches very well with Kendall's theory.
- ItemIndentation-induced two-way shape-memory effect in aged Ti-50.9 at.% Ni(Cambridge : Cambridge University Press, 2015) Frensemeier, Mareike; Arzt, Eduard; Qin, Enwei; Frick, Carl P.; Schneider, Andreas S.In this study, Vickers indentation was used to investigate the two-way shape-memory effect (TWSME) in an austenitic Ti-50.9 at.% Ni alloy, exposed to different heat treatments. Three aging treatments were used to manipulate the size of Ti3Ni4 precipitates. All samples were Vickers indented, and the indent depth was investigated as function of thermal cycling. The TWSME was found only in the material aged at 400 °C, which contained coherent precipitates. Thermal cycling shows stable TWSME, however, heating well above the austenite finish temperature lead to permanent austenitic protrusions. The results indicate that stabilized martensite plays a critical role in creating TWSME surfaces.
- ItemIn situ observation of contact mechanisms in bioinspired adhesives at high magnification(Cambridge : Cambridge University Press, 2011) Paretkar, Dadhichi; Schneider, Andreas S.; Kroner, Elmar; Arzt, EduardWe analyzed the contact mechanisms of bioinspired microfibrillar adhesives using in situ scanning electron microscopy. During adhesion tests we observed that (i) the superior adhesion of mushroom-shaped fibrils is assisted by the stochastic nature of detachment, (ii) the aspect ratio of microfibrils influences the bending/buckling behavior and the contact reformation, and (iii) the backing layer deformation causes the microfibrils to elastically interact with each other. These studies give new insights into the mechanisms responsible for adhesion of bioinspired fibrillar adhesives.
- ItemSHMIP The subglacial hydrology model intercomparison Project(Cambridge : Cambridge University Press, 2018) De Fleurian, Basile; Werder, Mauro A.; Beyer, Sebastian; Brinkenhoff, Douglas J.; Delaney, Ian; Dow, Christine F.; Downs, Jacob; Gagliardini, Olivier; Hoffman, Matthew J.; HookeE, Roger LeB; Seguinot, Julien; Sommers, Aleah N.Subglacial hydrology plays a key role in many glaciological processes, including ice dynamics via the modulation of basal sliding. Owing to the lack of an overarching theory, however, a variety of model approximations exist to represent the subglacial drainage system. The Subglacial Hydrology Model Intercomparison Project (SHMIP) provides a set of synthetic experiments to compare existing and future models. We present the results from 13 participating models with a focus on effective pressure and discharge. For many applications (e.g. steady states and annual variations, low input scenarios) a simple model, such as an inefficient-system-only model, a flowline or lumped model, or a porous-layer model provides results comparable to those of more complex models. However, when studying short term (e.g. diurnal) variations of the water pressure, the use of a two-dimensional model incorporating physical representations of both efficient and inefficient drainage systems yields results that are significantly different from those of simpler models and should be preferentially applied. The results also emphasise the role of water storage in the response of water pressure to transient recharge. Finally, we find that the localisation of moulins has a limited impact except in regions of sparse moulin density.
- ItemAntarctic ice sheet response to sudden and sustained ice-shelf collapse (ABUMIP)(Cambridge : Cambridge University Press, 2020) Sun, Sainan; Pattyn, Frank; Simon, Erika G.; Albrecht, Torsten; Cornford, Stephen; Calov, Reinhard; Dumas, Christophe; Gillet-Chaulet, Fabien; Goelzer, Goelzer; Golledge, Nicholas R.; Greve, Ralf; Hoffman, Matthew J.; Humbert, Angelika; Kazmierczak, Elise; Kleiner, Thomas; Leguy, Gunter R.; Lipscomb, William H.; Martin, Daniel; Morlighem, Mathieu; Nowicki, Sophie; Pollard, David; Price, Stephen; Quiquet, Aurélien; Seroussi, Hélène; Schlemm, Tanja; Sutter, Johannes; van de Wal, Roderik S.W.; Winkelmann, Ricarda; Zhang, TongAntarctica's ice shelves modulate the grounded ice flow, and weakening of ice shelves due to climate forcing will decrease their 'buttressing' effect, causing a response in the grounded ice. While the processes governing ice-shelf weakening are complex, uncertainties in the response of the grounded ice sheet are also difficult to assess. The Antarctic BUttressing Model Intercomparison Project (ABUMIP) compares ice-sheet model responses to decrease in buttressing by investigating the 'end-member' scenario of total and sustained loss of ice shelves. Although unrealistic, this scenario enables gauging the sensitivity of an ensemble of 15 ice-sheet models to a total loss of buttressing, hence exhibiting the full potential of marine ice-sheet instability. All models predict that this scenario leads to multi-metre (1-12 m) sea-level rise over 500 years from present day. West Antarctic ice sheet collapse alone leads to a 1.91-5.08 m sea-level rise due to the marine ice-sheet instability. Mass loss rates are a strong function of the sliding/friction law, with plastic laws cause a further destabilization of the Aurora and Wilkes Subglacial Basins, East Antarctica. Improvements to marine ice-sheet models have greatly reduced variability between modelled ice-sheet responses to extreme ice-shelf loss, e.g. compared to the SeaRISE assessments. Copyright © The Author(s) 2020.
- ItemHigh strength nanocrystalline Cu–Co alloys with high tensile ductility(Cambridge : Cambridge University Press, 2018) Bachmaier, Andrea; Rathmayr, Georg Benedikt; Schmauch, Jörg; Schell, Norbert; Stark, Andreas; de Jonge, Niels; Pippan, ReinhardA supersaturated single-phase Cu–26 at.% Co alloy was produced by high-pressure torsion deformation, leading to a nanocrystalline microstructure with a grain size smaller than 100 nm. The nonequilibrium solid solution decomposed during subsequent isothermal annealing. In situ high-energy X-ray diffraction was used to map changes linked to the separating phases, and the development of a nanoscale Cu–Co composite structure was observed. To gain further information about the relationship of the microstructure and the mechanical properties after phase separation, uniaxial tensile tests were conducted on as-deformed and isothermally annealed samples. Based on the in situ diffraction data, different isothermal annealing temperatures were chosen. Miniaturized tensile specimens with a round cross section were tested, and an image-based data evaluation method enabled the evaluation of true stress–strain curves and strain hardening behavior. The main results are as follows: all microstructural states showed high strength and ductility, which was achieved by a combination of strain-hardening and strain-rate hardening.
- ItemProcessing of Al–12Si–TNM composites by selective laser melting and evaluation of compressive and wear properties(Cambridge : Cambridge University Press, 2015) Prashantha, Konda G.; Scudino, Sergio; Chaubey, Anil K.; Löber, Lukas; Wang, Pei; Attar, Hooyar; Schimansky, Frank P.; Pyczak, Florian; Eckert, JürgenAl-12Si (80 vol%)-Ti52.4Al42.2Nb4.4Mo0.9B0.06 (at.%) (TNM) composites were successfully produced by the selective laser melting (SLM). Detailed structural and microstructural analysis shows the formation of the Al6MoTi intermetallic phase due to the reaction of the TNM reinforcement with the Al-12Si matrix during SLM. Compression tests reveal that the composites exhibit significantly improved properties (∼140 and ∼160 MPa higher yield and ultimate compressive strengths, respectively) compared with the Al-12Si matrix. However, the samples break at ∼6% total strain under compression, thus showing a reduced plasticity of the composites. Sliding wear tests were carried out for both the Al-12Si matrix and the Al-12Si-TNM composites. The composites perform better under sliding wear conditions and the wear rate increases with increasing loads. At high loads, the wear takes place at three different rates and the wear rate decreases with increasing experiment duration.
- ItemRemote sensing of life: Polarimetric signatures of photosynthetic pigments as sensitive biomarkers(Cambridge : Cambridge University Press, 2015) Berdyugina, Svetlana V.; Kuhn, Jeff R.; Harrington, David M.; Šantl-Temkiv, Tina; Messersmith, E. JohnWe develop a polarimetry-based remote-sensing method for detecting and identifying life forms in distant worlds and distinguishing them from non-biological species. To achieve this we have designed and built a bio-polarimetric laboratory experiment BioPol for measuring optical polarized spectra of various biological and non-biological samples. Here we focus on biological pigments, which are common in plants and bacteria that employ them either for photosynthesis or for protection against reactive oxygen species. Photosynthesis, which provides organisms with the ability to use light as a source of energy, emerged early in the evolution of life on Earth. The ability to harvest such a significant energy resource could likely also develop on habited exoplanets. Thus, we investigate the detectability of biomolecules that can capture photons of particular wavelengths and contribute to storing their energy in chemical bonds. We have carried out laboratory spectropolarimetric measurements of a representative sample of plants containing various amounts of pigments such as chlorophyll, carotenoids and others. We have also measured a variety of non-biological samples (sands, rocks). Using our lab measurements, we have modelled intensity and polarized spectra of Earth-like planets having different surface coverage by photosynthetic organisms, deserted land and ocean, as well as clouds. Our results demonstrate that linearly polarized spectra provide very sensitive and rather unambiguous detection of photosynthetic pigments of various kinds. Our work paves the path towards analogous measurements of microorganisms and remote sensing of microbial ecology on the Earth and of extraterrestrial life on other planets and moons.
- ItemGlobal warming as a detectable thermodynamic marker of Earth-like extrasolar civilizations: The case for a telescope like Colossus(Cambridge : Cambridge University Press, 2015) Kuhn, Jeff R.; Berdyugina, Svetlana V.Earth-like civilizations generate heat from the energy that they utilize. The thermal radiation from this heat can be a thermodynamic marker for civilizations. Here we model such planetary radiation on Earth-like planets and propose a strategy for detecting such an alien unintentional thermodynamic electromagnetic biomarker. We show that astronomical infrared (IR) civilization biomarkers may be detected within an interestingly large cosmic volume using a 70 m-class or larger telescope. In particular, the Colossus telescope with achievable coronagraphic and adaptive optics performance may reveal Earth-like civilizations from visible and IR photometry timeseries’ taken during an exoplanetary orbit period. The detection of an alien heat signature will have far-ranging implications, but even a null result, given 70 m aperture sensitivity, could also have broad social implications.
- ItemRanking facts for explaining answers to elementary science questions(Cambridge : Cambridge University Press, 2023) D’Souza, Jennifer; Mulang, Isaiah Onando; Auer, SörenIn multiple-choice exams, students select one answer from among typically four choices and can explain why they made that particular choice. Students are good at understanding natural language questions and based on their domain knowledge can easily infer the question's answer by “connecting the dots” across various pertinent facts. Considering automated reasoning for elementary science question answering, we address the novel task of generating explanations for answers from human-authored facts. For this, we examine the practically scalable framework of feature-rich support vector machines leveraging domain-targeted, hand-crafted features. Explanations are created from a human-annotated set of nearly 5000 candidate facts in the WorldTree corpus. Our aim is to obtain better matches for valid facts of an explanation for the correct answer of a question over the available fact candidates. To this end, our features offer a comprehensive linguistic and semantic unification paradigm. The machine learning problem is the preference ordering of facts, for which we test pointwise regression versus pairwise learning-to-rank. Our contributions, originating from comprehensive evaluations against nine existing systems, are (1) a case study in which two preference ordering approaches are systematically compared, and where the pointwise approach is shown to outperform the pairwise approach, thus adding to the existing survey of observations on this topic; (2) since our system outperforms a highly-effective TF-IDF-based IR technique by 3.5 and 4.9 points on the development and test sets, respectively, it demonstrates some of the further task improvement possibilities (e.g., in terms of an efficient learning algorithm, semantic features) on this task; (3) it is a practically competent approach that can outperform some variants of BERT-based reranking models; and (4) the human-engineered features make it an interpretable machine learning model for the task.