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- ItemCatalyzing mitigation ambition under the Paris Agreement: elements for an effective Global Stocktake(London [u.a.] : Taylor & Francis, 2019) Hermwille, Lukas; Siemons, Anne; Förster, Hannah; Jeffery, LouiseThe Global Stocktake (GST) takes a central role within the architecture of the Paris Agreement, with many hoping that it will become a catalyst for increased mitigation ambition. This paper outlines four governance functions for an ideal GST: pacemaker, ensurer of accountability, driver of ambition and provider of guidance and signal. The GST can set the pace of progress by stimulating and synchronizing policy processes across governance levels. It can ensure accountability of Parties through transparency and public information sharing. Ambition can be enhanced through benchmarks for action and transformative learning. By reiterating and refining the long term visions, it can echo and amplify the guidance and signal provided by the Paris Agreement. The paper further outlines preconditions for the effective performance of these functions. Process-related conditions include: a public appraisal of inputs; a facilitative format that can develop specific recommendations; high-level endorsement to amplify the message and effectively inform national climate policy agendas; and an appropriate schedule, especially with respect to the transparency framework. Underlying information provided by Parties complemented with other (scientific) sources needs to enable benchmark setting for collective climate action, to allow for transparent assessments of the state of emissions and progress of a low-carbon transformation. The information also needs to be politically relevant and concrete enough to trigger enhancement of ambition. We conclude that meeting these conditions would enable an ideal GST and maximize its catalytic effect. Key policy insights The functional argument developed in this article may inspire a purposeful design of the GST as its modalities and procedures are currently being negotiated. The analytical framework provided serves as a benchmark against which to assess the GST's modalities and procedures. Gaps and blind spots in the official GST can and should be addressed by processes external to the climate regime in academia and civil society. © 2019, © 2019 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.
- ItemOperando diagnostic detection of interfacial oxygen ‘breathing’ of resistive random access memory by bulk-sensitive hard X-ray photoelectron spectroscopy(London [u.a.] : Taylor & Francis, 2019) Niu, Gang; Calka, Pauline; Huang, Peng; Sharath, Sankaramangalam Ulhas; Petzold, Stefan; Gloskovskii, Andrei; Fröhlich, Karol; Zhao, Yudi; Kan, Jinfeng; Schubert, Markus Andreas; Bärwolf, Florian; Ren, Wei; Ye, Zuo-Guang; Perez, Eduardo; Wenger, Christian; Alff, Lambert; Schroeder, ThomasThe HfO2-based resistive random access memory (RRAM) is one of the most promising candidates for non-volatile memory applications. The detection and examination of the dynamic behavior of oxygen ions/vacancies are crucial to deeply understand the microscopic physical nature of the resistive switching (RS) behavior. By using synchrotron radiation based, non-destructive and bulk-sensitive hard X-ray photoelectron spectroscopy (HAXPES), we demonstrate an operando diagnostic detection of the oxygen ‘breathing’ behavior at the oxide/metal interface, namely, oxygen migration between HfO2 and TiN during different RS periods. The results highlight the significance of oxide/metal interfaces in RRAM, even in filament-type devices. IMPACT STATEMENT: The oxygen ‘breathing’ behavior at the oxide/metal interface of filament-type resistive random access memory devices is operandoly detected using hard X-ray photoelectron spectroscopy as a diagnostic tool. © 2019, © 2019 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.
- ItemCryogenic-temperature-induced structural transformation of a metallic glass(London [u.a.] : Taylor & Francis, 2016-11-30) Bian, Xilei; Wang, Gang; Wang, Qing; Sun, Baoan; Hussain, Ishtiaq; Zhai, Qijie; Mattern, Norbert; Bednarčík, Jozef; Eckert, JürgenThe plasticity of metallic glasses depends largely on the atomic-scale structure. However, the details of the atomic-scale structure, which are responsible for their properties, remain to be clarified. In this study, in-situ high-energy synchrotron X-ray diffraction and strain-rate jump compression tests at different cryogenic temperatures were carried out. We show that the activation volume of flow units linearly depends on temperature in the non-serrated flow regime. A plausible atomic deformation mechanism is proposed, considering that the activated flow units mediating the plastic flow originate from the medium-range order and transit to the short-range order with decreasing temperature.
- ItemStochastic approximation versus sample average approximation for Wasserstein barycenters(London [u.a.] : Taylor & Francis, 2022) Dvinskikh, DarinaIn the machine learning and optimization community, there are two main approaches for the convex risk minimization problem, namely the Stochastic Approximation (SA) and the Sample Average Approximation (SAA). In terms of the oracle complexity (required number of stochastic gradient evaluations), both approaches are considered equivalent on average (up to a logarithmic factor). The total complexity depends on a specific problem, however, starting from the work [A. Nemirovski, A. Juditsky, G. Lan, and A. Shapiro, Robust stochastic approximation approach to stochastic programming, SIAM. J. Opt. 19 (2009), pp. 1574–1609] it was generally accepted that the SA is better than the SAA. We show that for the Wasserstein barycenter problem, this superiority can be inverted. We provide a detailed comparison by stating the complexity bounds for the SA and SAA implementations calculating barycenters defined with respect to optimal transport distances and entropy-regularized optimal transport distances. As a byproduct, we also construct confidence intervals for the barycenter defined with respect to entropy-regularized optimal transport distances in the ℓ2-norm. The preliminary results are derived for a general convex optimization problem given by the expectation to have other applications besides the Wasserstein barycenter problem.
- ItemQuenching of material dependence in few-cycle driven electron acceleration from nanoparticles under many-particle charge interaction(London [u.a.] : Taylor & Francis, 2016-12-25) Rupp, Philipp; Seiffert, Lennart; Liu, Qingcao; Süßmann, Frederik; Ahn, Byungnam; Förg, Benjamin; Schäfer, Christian G.; Gallei, Markus; Mondes, Valerie; Kessel, Alexander; Trushin, Sergei; Graf, Christina; Rühl, Eckart; Lee, Jinwoo; Kim, Min Su; Kim, Dong Eon; Fennel, Thomas; Kling, Matthias F.; Zherebtsov, SergeyThe excitation of nanoscale near-fields with ultrashort and intense laser pulses of well-defined waveform enables strongly spatially and temporally localized electron emission, opening up the possibility for the generation of attosecond electron pulses. Here, we investigate the electron photoemission from isolated nanoparticles of different materials in few-cycle laser fields at intensities where the Coulomb field of the ionized electrons and residual ions significantly contribute to the electron acceleration process. The dependences of the electron cut-off energy on the material’s dielectric properties and electron binding energy are investigated systematically in both experiments and semi-classical simulations. We find that for sufficiently high near-field intensities the material dependence of the acceleration in the enhanced near-fields is quenched by many-particle charge-interaction.
- ItemUrban nitrogen budgets: flows and stock changes of potentially polluting nitrogen compounds in cities and their surroundings–a review(London [u.a.] : Taylor & Francis, 2020) Winiwarter, Wilfried; Amon, Barbara; Bai, Zhaohai; Greinert, Andrzej; Kaltenegger, Katrin; Ma, Lin; Myszograj, Sylwia; Schneidergruber, Markus; Suchowski-Kisielewicz, Monika; Wolf, Lisa; Zhang, Lin; Zhou, FengConcepts of material flow and mass consistency of nitrogen compounds have been used to elucidate nitrogen’s fate in an urban environment. While reactive nitrogen commonly is associated to agriculture and hence to large areas, here we have compiled scientific literature on nitrogen budget approaches in cities, following the central role cities have in anthropogenic activities generally. This included studies that specifically dealt with individual sectors as well as budgets covering all inputs and outputs to and from a city across all sectors and media. In the available data set, a clear focus on Asian cities was noted, making full use of limited information and thus enable to quantitatively describe a local pollution situation. Time series comparisons helped to identify trends, but comparison between cities was hampered by a lack of harmonized methodologies. Some standardization, or at least improved reference to relevant standardized data collection along international norms was considered helpful. Analysis of results available pointed to the following aspects that would reveal additional benchmarks for urban nitrogen budgets: analysing the share of nitrogen that is recycled or reused, separating largely independent sets of nitrogen flows specifically between food nitrogen streams and fossil fuel combustion-related flows, and estimating the stock changes for the whole domain or within individual pools.
- ItemNanocellulose and PEDOT:PSS composites and their applications(London [u.a.] : Taylor & Francis, 2022) Brooke, Robert; Lay, Makara; Jain, Karishma; Francon, Hugo; Say, Mehmet Girayhan; Belaineh, Dagmawi; Wang, Xin; Håkansson, Karl M. O.; Wågberg, Lars; Engquist, Isak; Edberg, Jesper; Berggren, MagnusThe need for achieving sustainable technologies has encouraged research on renewable and biodegradable materials for novel products that are clean, green, and environmentally friendly. Nanocellulose (NC) has many attractive properties such as high mechanical strength and flexibility, large specific surface area, in addition to possessing good wet stability and resistance to tough chemical environments. NC has also been shown to easily integrate with other materials to form composites. By combining it with conductive and electroactive materials, many of the advantageous properties of NC can be transferred to the resulting composites. Conductive polymers, in particular poly(3,4-ethylenedioxythiophene:poly(styrene sulfonate) (PEDOT:PSS), have been successfully combined with cellulose derivatives where suspensions of NC particles and colloids of PEDOT:PSS are made to interact at a molecular level. Alternatively, different polymerization techniques have been used to coat the cellulose fibrils. When processed in liquid form, the resulting mixture can be used as a conductive ink. This review outlines the preparation of NC/PEDOT:PSS composites and their fabrication in the form of electronic nanopapers, filaments, and conductive aerogels. We also discuss the molecular interaction between NC and PEDOT:PSS and the factors that affect the bonding properties. Finally, we address their potential applications in energy storage and harvesting, sensors, actuators, and bioelectronics.
- ItemOptimizing Variable-Axial Fiber-Reinforced Composite Laminates: The Direct Fiber Path Optimization Concept(London [u.a.] : Taylor & Francis, 2019) Bittrich, Lars; Spickenheuer, Axel; Almeida Jr., José Humberto S.; Müller, Sascha; Kroll, Lothar; Heinrich, GertThe concept of aligning reinforcing fibers in arbitrary directions offers a new perception of exploiting the anisotropic characteristic of the carbon fiber-reinforced polymer (CFRP) composites. Complementary to the design concept of multiaxial composites, a laminate reinforced with curvilinear fibers is called variable-axial (also known as variable stiffness and variable angle tow). The Tailored Fiber Placement (TFP) technology is well capable of manufacturing textile preforming with a variable-axial fiber design by using adapted embroidery machines. This work introduces a novel concept for simulation and optimization of curvilinear fiber-reinforced composites, where the novelty relies on the local optimization of both fiber angle and intrinsic thickness build-up concomitantly. This framework is called Direct Fiber Path Optimization (DFPO). Besides the description of DFPO, its capabilities are exemplified by optimizing a CFRP open-hole tensile specimen. Key results show a clear improvement compared to the current often used approach of applying principal stress trajectories for a variable-axial reinforcement pattern. © 2019 Lars Bittrich et al.
- ItemSynthesis of surfactant-free Cu–Pt dendritic heterostructures with highly electrocatalytic performance for methanol oxidation reaction(London [u.a.] : Taylor & Francis, 2016) Kang, Shendong; Gao, Guanhui; Xie, Xiaobin; Shibayama, Tamaki; Lei, Yanhua; Wang, Yan; Cai, LintaoA facile and free surfactant strategy is explored to synthesize Cu–Pt bimetallic nano-heterostructures with dendritic exterior. For comparison, the Cu–Pt coral-like nanoparticles are fabricated by using CTAC as a surfactant. The well-designed Cu–Pt dendritic spherical heterostructures exhibit superior enhanced electrocatalytic activity and stability toward methanol oxidation reaction in alkaline media, compared to the Cu–Pt coral-like nanoparticles and the commercial Pt/C, respectively. The advanced technique for fabricating Cu–Pt dendritic spherical heterostructures could pave a way to pursue low-cost Pt-based catalysts, maintaining highly promoted electrocatalytic performance and durability.
- ItemIs the energy density a reliable parameter for materials synthesis by selective laser melting?(London [u.a.] : Taylor & Francis, 2017-3-9) Prashanth, K.G.; Scudino, S.; Maity, T.; Das, J.; Eckert, J.The effective fabrication of materials using selective laser melting depends on the process parameters. Here, we analyse the suitability of the energy density to represent the energy transferred to the powder bed, which is effectively used to melt the particles and to produce the bulk specimens. By properly varying laser power and speed in order to process the powder at constant energy density, we show that the equation currently used to calculate the energy density gives only an approximate estimation and that hatch parameters and material properties should be considered to correctly evaluate the energy density.