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Publisher: Weinheim : Wiley-VCH-Verl. × Subject: arylboronates ×

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    Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
    (Weinheim : Wiley-VCH-Verl., 2017-3-16) Qi, Xinxin; Jiang, Li-Bing; Zhou, Chao; Peng, Jin-Bao; Wu, Xiao-Feng
    A convenient and general zinc-catalyzed borylation of aryl diazonium salts and aryltriazenes has been developed. With bis- (pinacolato)diboron as the borylation reagent, aryldiazonium tetrafluoroborate salts and aryltriazenes were transformed into the corresponding arylboronates in moderate to excellent yields under mild conditions. As a convenient and practical methodology, no additional ligands, base, or any other additives are required here.