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Anisotropic surface energy formulations and their effect on stability of a growing thin film

2012, Korzec, Maciek D., Münch, Andreas, Wagner, Barbara

In this paper we revisit models for the description of the evolution of crystalline films with anisotropic surface energies. We prove equivalences of symmetry properties of anisotropic surface energy models commonly used in the literature. Then we systematically develop a framework for the derivation of surface diffusion models for the self-assembly of quantum dots during Stranski-Krastanov growth that include surface energies also with large anisotropy as well as the effect of wetting energy, elastic energy and a randomly perturbed atomic deposition flux. A linear stability analysis for the resulting sixth-order semilinear evolution equation for the thin film surface shows that that the new model allows for large anisotropy and gives rise to the formation of anisotropic quantum dots. The nonlinear three-dimensional evolution is investigated via numerical solutions. These suggest that increasing anisotropy stabilizes the faceted surfaces and may lead to a dramatic slow-down of the coarsening of the dots.

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From bell shapes to pyramids . continuum model for self-assembled quantum dot growth

2009, Korzec, Maciek D., Evans, Peter L.

A continuum model for the growth of self-assembled quantum dots that incorporates surface diffusion, an elastically deformable substrate, wetting interactions and anisotropic surface energy is presented. Using a small slope approximation a thin film equation for the surface profile that describes facetted growth is derived. A linear stability analysis shows that anisotropy acts to destabilize the surface. It lowers the critical height of flat films and there exists an anisotropy strength above which all thicknesses are unstable. A numerical algorithm based on spectral differentiation is presented and simulation are carried out. These clearly show faceting of the growing islands and a logarithmically slow coarsening behavior.