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Phase formation of a biocompatible Ti-based alloy under kinetic constraints studied via in-situ high-energy X-ray diffraction

2020, Kosiba, K., Rothkirch, A., Han, J., Deng, L., Escher, B., Wang, G., Kühn, U., Bednarcik, J.

The biocompatible Ti40Cu34Pd14Zr10Sn2 bulk metallic glass was rapidly heated, also known as flash-annealed, at varying heating rates up to 1579 K/s. Thereby, the phase formation was characterized via advanced in-situ high-energy X-ray diffraction. It has been found that the evolving kinetic constraints can be used as a tool to deliberately alter the crystalline phase formation. This novel processing route permits to select phases to crystallize to a predefined fraction and, thus, to potentially design the microstructure of materials according to a specified property-profile. Consequently, flash-annealing poses a unique synthesis route to design materials with, for instance, good biomechanical compatibility.