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Overcoming the shortcomings of the Nernst-Planck model
2012, Dreyer, Wolfgang, Guhlke, Clemens, Müller, Rüdiger
This is a study on electrolytes that takes a thermodynamically consistent coupling between mechanics and diffusion into account. It removes some inherent deficiencies of the popular Nernst-Planck model. A boundary problem for equilibrium processes is used to illustrate the new features of our model.