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Tropospheric aqueous-phase chemistry: kinetics, mechanisms, and its coupling to a changing gas phase

2015, Herrmann, Hartmut, Schaefer, Thomas, Tilgner, Andreas, Styler, Sarah A., Weller, Christian, Teich, Monique, Otto, Tobias

[no abstract available]

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Monitoring excited-state relaxation in a molecular marker in live cells–a case study on astaxanthin

2021, Yang, Tingxiang, Chettri, Avinash, Radwan, Basseem, Matuszyk, Ewelina, Baranska, Malgorzata, Dietzek, Benjamin

Small molecules are frequently used as dyes, labels and markers to visualize and probe biophysical processes within cells. However, very little is generally known about the light-driven excited-state reactivity of such systems when placed in cells. Here an experimental approach to study ps time-resolved excited state dynamics of a benchmark molecular marker, astaxanthin, in live human cells is introduced. © The Royal Society of Chemistry 2021.

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Tuning functional properties by plastic deformation

2009, Kwon, A.R., Neu, V., Matias, V., Hänisch, J., Hühne, R., Freudenberger, J., Holzapfel, B., Schultz, L., Fähler, S.

It is well known that a variation of lattice constants can strongly influence the functional properties of materials. Lattice constants can be influenced by external forces; however, most experiments are limited to hydrostatic pressure or biaxial stress. Here, we present an experimental approach that imposes a large uniaxial strain on epitaxially grown films in order to tune their functional properties. A substrate made of a ductile metal alloy covered with a biaxially oriented MgO layer is used as a template for growth of epitaxial films. By applying an external plastic strain, we break the symmetry within the substrate plane compared to the as-deposited state. The consequences of 2% plastic strain are examined for an epitaxial hard magnetic Nd2Fe14B film and are found to result in an elliptical distortion of the in-plane anisotropy below the spin-reorientation temperature. Our approach is a versatile method to study the influence of large plastic strain on various materials, as the MgO(001) layer used is a common substrate for epitaxial growth.