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- ItemThe role of substrate temperature and magnetic filtering for DLC by cathodic arc evaporation(Basel : MDPI, 2019) Lux, Helge; Edling, Matthias; Lucci, Massimiliano; Kitzmann, Julia; Villringer, Claus; Siemroth, Peter; De Matteis, Fabio; Schrader, SigurdDiamond-like carbon (DLC) films were deposited using two different types of high current arc evaporation. The first process used a magnetic particle filter to remove droplets from the plasma. For the second process, the samples were put into a metallic cage which was placed directly above the plasma source. For both processes, we varied the substrate temperature from 21 to 350 °C in order to investigate the temperature effect. The samples were characterized using SEM, AFM, XPS, Raman Spectroscopy, Ellipsometry, Photometry, and Nano Indentation in order to compare both methods of deposition and provide a careful characterization of such DLC films. We found that the sp3 content and the hardness can be precisely adjusted by changing the substrate temperature. Furthermore, in the case of unfiltered deposition, the optical constants can be shifted in the direction of higher absorbance in order to produce black and hard carbon coatings. © 2019 by the authors.
- ItemCharacteristics of austenitic stainless steel nitrided in a hybrid glow discharge plasma(New York, NY : Springer, 2009) Oliveira, R.M.; Ueda, M.; Silva, L.L.G.; Reuther, H.; Lepienski, C.M.A nitriding process based on two distinct nitrogen glow discharge modes, with sample temperatures ranging from 380 °Cto480°C, was employed to treat the surface of austenitic stainless steel (SS 304). The temperature is controlled exclusively by switching the operation conditions of the discharges. First mode of operation is the conventional one, named cathodic, which runs at higher pressure values (1 mbar) in comparison to the second mode, named anodic, which runs at the pressure range of 10-3 -10-2 mbar. Cathodic mode is used to quickly heat the sample holder, by the high ion flux. On the other hand, in the anodic mode, due to the lower operation pressure, higher effective ion acceleration takes place, which allows deeper ion implantation into the sample surface. This hybrid process was thoroughly explored regarding the duty cycle and conditions of operation, to achieve optimal performance of the treatments, which led to the attainment of surface hardness for samples of AISI SS 304 as high as 20 GPa and improvements including higher elastic modulus and resistance against corrosion. Detailed comparison among samples treated by this process with others treated by conventional method was done using nanoindentation, Auger Electron Spectroscopy (AES) and corrosion resistance testing.
- ItemSynthesis and characterization of nanocrystallineMg-7.4%Al powders produced by mechanical alloying(Basel : MDPI AG, 2013) Chaubey, A.K.; Scudino, S.; Khoshkhoo, M.S.; Prashanth, K.G.; Mukhopadhyay, N.K.; Mishra, B.K.; Eckert, J.Nanocrystalline Mg-7.4%Al powder was prepared by mechanical alloying using a high-energy mill. The evolution of the various phases and their microstructure, including size and morphology of the powder particles in the course of milling and during subsequent annealing, were investigated in detail. Room temperature milling leads to a rather heterogeneous microstructure consisting of two distinct regions: Al-free Mg cores and Mg-Al intermixed areas. As a result, the material is mechanically heterogeneous with the Mg cores displaying low hardness (40–50 HV) and the Mg-Al intermixed regions showing high hardness of about 170 HV. The Mg cores disappear and the microstructure becomes (also mechanically) homogeneous after subsequent cryo-milling. Rietveld structure refinement reveals that the crystallite size of the milled powders decreases with increasing the milling time reaching a minimum value of about 30 nm. This is corroborated by transmission electron microscopy confirming an average grain size of ~25 nm.
- ItemReducing the nucleation barrier in magnetocaloric Heusler alloys by nanoindentation(New York : American Institute of Physics, 2016) Niemann, R.; Hahn, S.; Diestel, A.; Backen, A.; Schultz, L.; Nielsch, K.; Wagner, M.F.-X.; Fähler, S.Magnetocaloric materials are promising as solid state refrigerants for more efficient and environmentally friendly cooling devices. The highest effects have been observed in materials that exhibit a first-order phase transition. These transformations proceed by nucleation and growth which lead to a hysteresis. Such irreversible processes are undesired since they heat up the material and reduce the efficiency of any cooling application. In this article, we demonstrate an approach to decrease the hysteresis by locally changing the nucleation barrier. We created artificial nucleation sites and analyzed the nucleation and growth processes in their proximity. We use Ni-Mn-Ga, a shape memory alloy that exhibits a martensitic transformation. Epitaxial films serve as a model system, but their high surface-to-volume ratio also allows for a fast heat transfer which is beneficial for a magnetocaloric regenerator geometry. Nanoindentation is used to create a well-defined defect. We quantify the austenite phase fraction in its proximity as a function of temperature which allows us to determine the influence of the defect on the transformation.
- ItemElectrodeposition of nanocrystalline Fe-P coatings: Influence of bath temperature and glycine concentration on structure, mechanical and corrosion behavior(Basel : MDPI AG, 2019) Kovalska, N.; Tsyntsaru, N.; Cesiulis, H.; Gebert, A.; Fornell, J.; Pellicer, E.; Sort, J.; Hansal, W.; Kautek, W.A detailed electrochemical study and investigation of a Fe-P glycine bath as a function of the temperature and glycine concentrations and current density, and their resulting corrosion and mechanical behavior is presented. A low addition of glycine to the electrolyte led to a drastic increase of the P content. At low Fe-P deposition rates, heterogeneous rough deposits with morphological bumps and pores were observed. By increasing the Fe-P deposition rate, the number of pores were reduced drastically, resulting in smooth coatings. Increasing the P content led to the formation of nanocrystalline grains from an "amorphous-like" state. Coatings with higher P contents exhibited better corrosion resistance and hardening, most likely attributed to grain boundary strengthening.