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Laser powder bed fusion of a superelastic Cu-Al-Mn shape memory alloy
2021, Babacan, N., Pauly, S., Gustmann, T.
Dense and crack-free specimens of the shape memory alloy Cu71.6Al17Mn11.4 (at.%) were produced via laser powder bed fusion across a wide range of process parameters. The microstructure, viz. grain size, can be directly tailored within the process and with it the transformation temperatures (TTs) shifted to higher values by raising the energy input. The microstructure, and the superelastic behavior of additively manufactured samples were assessed by a detailed comparison with induction melted material. The precipitation of the α phase, which inhibit the martensitic transformation, were not observed in the additively manufactured samples owing to the high intrinsic cooling rates during the fabrication process. Fine columnar grains with a strong [001]-texture along the building direction lead to an enhanced yield strength compared to the coarse-grained cast samples. A maximum recoverable strain of 2.86% was observed after 5% compressive loading. The first results of our approach imply that laser powder bed fusion is a promising technique to directly produce individually designed Cu-Al-Mn shape memory parts with a pronounced superelasticity at room temperature.
Influence of isothermal omega precipitation aging on deformation mechanisms and mechanical properties of a β-type Ti-Nb alloy
2022, Pilz, S., Hariharan, A., Günther, F., Zimmermann, M., Gebert, A.
In this study, the influence of ωiso precipitates on the active deformation mechanisms and the mechanical properties of the biomedical β-type Ti-40Nb alloy are revealed. Low temperature heat treatments (aging) at 573 K for durations up to 108.0 ks were carried out for a cold-rolled and recrystallized sample state. After an aging time of 3.6 ks the ωiso phase was determined by means of synchrotron XRD and the fraction and the crystallite size of ωiso increased progressively with increasing aging time. Due to the high intrinsic Young's modulus of the ωiso phase, the Young's modulus increased gradually with the aging time from 63 GPa, for the recrystallized reference condition, to values of 70 GPa (3.6 ks), 73 GPa (14.4 ks), 81 GPa (28.8 ks) and 96 GPa (108.0 ks). Depending on the aging time, also a change of the active deformation mechanisms occurred, resulting in significantly altered mechanical properties. For the single β-phase reference microstructure, stress-induced martensite (SIM) formation, {332} <113> twinning and dislocation slip were observed under tensile loading, resulting in a low 0.2% proof stress of around 315 MPa but a high elongation at fracture of 26.2%. With increasing aging time, SIM formation and mechanical twinning are progressively hindered under tensile loading. SIM formation could not be detected for samples aged longer than 3.6 ks. The amount and thickness of deformation twins is clearly reduced with increasing aging time and for samples aged longer than 14.4 ks deformation twinning is completely suppressed. As a result of the changed deformation mechanisms and the increase of the critical stress for slip caused by ωiso, the 0.2% proof stress of the aged samples increased gradually from 410 MPa (3.6 ks) to around 910 MPa (108.0 ks). With regard to application as new bone implant material, a balanced ratio of a low Young's modulus of E = 73 GPa and higher 0.2% proof stress of 640 MPa was achieved after an aging time of 14.4 ks.
Dissipation losses limiting first-order phase transition materials in cryogenic caloric cooling: A case study on all-d-metal Ni(-Co)-Mn-Ti Heusler alloys
2023, Beckmann, Benedikt, Koch, David, Pfeuffer, Lukas, Gottschall, Tino, Taubel, Andreas, Adabifiroozjaei, Esmaeil, Miroshkina, Olga N., Riegg, Stefan, Niehoff, Timo, Kani, Nagaarjhuna A., Gruner, Markus E., Molina-Luna, Leopoldo, Skokov, Konstantin P., Gutfleisch, Oliver
Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic transformation. However, no comprehensive study on the crucially important transition entropy change Δst exists so far for Ni(-Co)-Mn-Ti. Here, we present a systematic study analyzing the composition and temperature dependence of Δst. Our results reveal a substantial structural entropy change contribution of approximately 65 J(kgK)-1, which is compensated at lower temperatures by an increasingly negative entropy change associated with the magnetic subsystem. This leads to compensation temperatures Tcomp of 75 K and 300 K in Ni35Co15Mn50-yTiy and Ni33Co17Mn50-yTiy, respectively, below which the martensitic transformations are arrested. In addition, we simultaneously measured the responses of the magnetic, structural and electronic subsystems to the temperature- and field-induced martensitic transformation near Tcomp, showing an abnormal increase of hysteresis and consequently dissipation energy at cryogenic temperatures. Simultaneous measurements of magnetization and adiabatic temperature change ΔTad in pulsed magnetic fields reveal a change in sign of ΔTad and a substantial positive and irreversible ΔTad up to 15 K at 15 K as a consequence of increased dissipation losses and decreased heat capacity. Most importantly, this phenomenon is universal, it applies to any first-order material with non-negligible hysteresis and any stimulus, effectively limiting the utilization of their caloric effects for gas liquefaction at cryogenic temperatures.