2018, Slemr, Franz, Weigelt, Andreas, Ebinghaus, Ralf, Bieser, Johannes, Brenninkmeijer, Carl A. M., Rauthe-Schöch, Armin, Hermann, Markus, Martinsson, Bengt G., van Velthoven, Peter, Bönisch, Harald, Neumaier, Marco, Zahn, Andreas, Ziereis, Helmut

Mercury was measured onboard the IAGOS-CARIBIC passenger aircraft from May 2005 until February 2016 during near monthly sequences of mostly four intercontinental flights from Germany to destinations in North and South America, Africa and South and East Asia. Most of these mercury data were obtained using an internal default signal integration procedure of the Tekran instrument but since April 2014 more precise and accurate data were obtained using post-flight manual integration of the instrument raw signal. In this paper we use the latter data. Increased upper tropospheric total mercury (TM) concentrations due to large scale biomass burning were observed in the upper troposphere (UT) at the equator and southern latitudes during the flights to Latin America and South Africa in boreal autumn (SON) and boreal winter (DJF). TM concentrations in the lowermost stratosphere (LMS) decrease with altitude above the thermal tropopause but the gradient is less steep than reported before. Seasonal variation of the vertical TM distribution in the UT and LMS is similar to that of other trace gases with surface sources and stratospheric sinks. Speciation experiments suggest comparable TM and gaseous elementary mercury (GEM) concentrations at and below the tropopause leaving little space for Hg2+ (TM-thinsp;GEM) being the dominating component of TM here. In the stratosphere significant GEM concentrations were found to exist up to 4 km altitude above the thermal tropopause. Correlations with N2O as a reference tracer suggest stratospheric lifetimes of 72±37 and 74±27 years for TM and GEM, respectively, comparable to the stratospheric lifetime of COS. This coincidence, combined with pieces of evidence from us and other researchers, corroborates the hypothesis that Hg2+ formed by oxidation in the stratosphere attaches to sulfate particles formed mainly by oxidation of COS and is removed with them from the stratosphere by air mass exchange, gravitational sedimentation and cloud scavenging processes.

2020, Collaud Coen, Martine, Andrews, Elisabeth, Alastuey, Andrés, Petkov Arsov, Todor, Backman, John, Brem, Benjamin T., Bukowiecki, Nicolas, Couret, Cédric, Eleftheriadis, Konstantinos, Flentje, Harald, Fiebig, Markus, Gysel-Beer, Martin, Hand, Jenny L., Hoffer, András, Hooda, Rakesh, Hueglin, Christoph, Joubert, Warren, Keywood, Melita, Eun Kim, Jeong, Kim, Sang-Woo, Labuschagne, Casper, Lin, Neng-Huei, Lin, Yong, Lund Myhre, Cathrine, Luoma, Krista, Lyamani, Hassan, Marinoni, Angela, Mayol-Bracero, Olga L., Mihalopoulos, Nikos, Pandolfi, Marco, Prats, Natalia, Prenni, Anthony J., Putaud, Jean-Philippe, Ries, Ludwig, Reisen, Fabienne, Sellegri, Karine, Sharma, Sangeeta, Sheridan, Patrick, Sherman, James Patrick, Sun, Junying, Titos, Gloria, Torres, Elvis, Tuch, Thomas, Weller, Rolf, Wiedensohler, Alfred, Zieger, Paul, Laj, Paolo

In order to assess the evolution of aerosol parameters affecting climate change, a long-term trend analysis of aerosol optical properties was performed on time series from 52 stations situated across five continents. The time series of measured scattering, backscattering and absorption coefficients as well as the derived single scattering albedo, backscattering fraction, scattering and absorption Ångström exponents covered at least 10 years and up to 40 years for some stations. The non-parametric seasonal Mann-Kendall (MK) statistical test associated with several pre-whitening methods and with Sen's slope was used as the main trend analysis method. Comparisons with general least mean square associated with autoregressive bootstrap (GLS/ARB) and with standard least mean square analysis (LMS) enabled confirmation of the detected MK statistically significant trends and the assessment of advantages and limitations of each method. Currently, scattering and backscattering coefficient trends are mostly decreasing in Europe and North America and are not statistically significant in Asia, while polar stations exhibit a mix of increasing and decreasing trends. A few increasing trends are also found at some stations in North America and Australia. Absorption coefficient time series also exhibit primarily decreasing trends. For single scattering albedo, 52 % of the sites exhibit statistically significant positive trends, mostly in Asia, eastern/northern Europe and the Arctic, 22 % of sites exhibit statistically significant negative trends, mostly in central Europe and central North America, while the remaining 26 % of sites have trends which are not statistically significant. In addition to evaluating trends for the overall time series, the evolution of the trends in sequential 10-year segments was also analyzed. For scattering and backscattering, statistically significant increasing 10-year trends are primarily found for earlier periods (10-year trends ending in 2010-2015) for polar stations and Mauna Loa. For most of the stations, the present-day statistically significant decreasing 10-year trends of the single scattering albedo were preceded by not statistically significant and statistically significant increasing 10-year trends. The effect of air pollution abatement policies in continental North America is very obvious in the 10-year trends of the scattering coefficient - there is a shift to statistically significant negative trends in 2009-2012 for all stations in the eastern and central USA. This long-term trend analysis of aerosol radiative properties with a broad spatial coverage provides insight into potential aerosol effects on climate changes. © 2020 Royal Society of Chemistry. All rights reserved.

2015, Jägermeyr, J., Gerten, D., Heinke, J., Schaphoff, S., Kummu, M., Lucht, W.

2017, Ortiz-Amezcua, Pablo, Guerrero-Rascado, Juan Luis, Granados-Muñoz, María José, Benavent-Oltra, José Antonio, Böckmann, Christine, Samaras, Stefanos, Stachlewska, Iwona S., Janicka, Łucja, Baars, Holger, Bohlmann, Stephanie, Alados-Arboledas, Lucas

Strong events of long-range transported biomass burning aerosol were detected during July 2013 at three EARLINET (European Aerosol Research Lidar Network) stations, namely Granada (Spain), Leipzig (Germany) and Warsaw (Poland). Satellite observations from MODIS (Moderate Resolution Imaging Spectroradiometer) and CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) instruments, as well as modeling tools such as HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) and NAAPS (Navy Aerosol Analysis and Prediction System), have been used to estimate the sources and transport paths of those North American forest fire smoke particles. A multiwavelength Raman lidar technique was applied to obtain vertically resolved particle optical properties, and further inversion of those properties with a regularization algorithm allowed for retrieving microphysical information on the studied particles. The results highlight the presence of smoke layers of 1-2 km thickness, located at about 5 km a.s.l. altitude over Granada and Leipzig and around 2.5 km a.s.l. at Warsaw. These layers were intense, as they accounted for more than 30 % of the total AOD (aerosol optical depth) in all cases, and presented optical and microphysical features typical for different aging degrees: Color ratio of lidar ratios (LR532/LR355) around 2, α-related ängström exponents of less than 1, effective radii of 0.3 μm and large values of single scattering albedos (SSA), nearly spectrally independent. The intensive microphysical properties were compared with columnar retrievals form co-located AERONET (Aerosol Robotic Network) stations. The intensity of the layers was also characterized in terms of particle volume concentration, and then an experimental relationship between this magnitude and the particle extinction coefficient was established.

2014, Kundzewicz, Z.W., Kanae, S., Seneviratne, S.I., Handmer, J., Nicholls, N., Peduzzi, P., Mechler, R., Bouwer, L.M., Arnell, N., Mach, K., Muir-Wood, R., Brakenridge, G.R., Kron, W., Benito, G., Honda, Y., Takahashi, K., Sherstyukov, B.

A holistic perspective on changing rainfall-driven flood risk is provided for the late 20th and early 21st centuries. Economic losses from floods have greatly increased, principally driven by the expanding exposure of assets at risk. It has not been possible to attribute rain-generated peak streamflow trends to anthropogenic climate change over the past several decades. Projected increases in the frequency and intensity of heavy rainfall, based on climate models, should contribute to increases in precipitation-generated local flooding (e.g. flash flooding and urban flooding). This article assesses the literature included in the IPCC SREX report and new literature published since, and includes an assessment of changes in flood risk in seven of the regions considered in the recent IPCC SREX report-Africa, Asia, Central and South America, Europe, North America, Oceania and Polar regions. Also considering newer publications, this article is consistent with the recent IPCC SREX assessment finding that the impacts of climate change on flood characteristics are highly sensitive to the detailed nature of those changes and that presently we have only low confidence1 in numerical projections of changes in flood magnitude or frequency resulting from climate change.

2014, Peron, T.K.D., Comin, C.H., Amancio, D.R., Da F. Costa, L., Rodrigues, F.A., Kurths, J.

In the last few years, the scientific community has witnessed an ongoing trend of using ideas developed in the study of complex networks to analyze climate dynamics. This powerful combination, usually called climate networks, can be used to uncover non-trivial patterns of weather changes throughout the years. Here we investigate the temperature network of the North American region and show that two network characteristics, namely degree and clustering, have marked differences between the eastern and western regions. We show that such differences are a reflection of the presence of a large network community on the western side of the continent. Moreover, we provide evidence that this large community is a consequence of the peculiar characteristics of the western relief of North America.