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Subject: Phase transformation ×

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    Structure evolution of soft magnetic (Fe36Co36B19.2Si4.8Nb4)100-xCux (x = 0 and 0.5) bulk glassy alloys
    (Amsterdam [u.a.] : Elsevier Science, 2015) Stoica, Mihai; Ramasamy, Parthiban; Kaban, Ivan; Scudino, Sergio; Nicoara, Mircea; Vaughan, Gavin B.M.; Wright, Jonathan; Kumar, Ravi; Eckert, Jürgen
    Fully amorphous rods with diameters up to 2 mm diameter were obtained upon 0.5 at.% Cu addition to the Fe36Co36B19.2Si4.8Nb4 bulk metallic glass. The Cu-added glass shows a very good thermal stability but, in comparison with the Cu-free base alloy, the entire crystallization behavior is drastically changed. Upon heating, the glassy (Fe36Co36B19.2Si4.8Nb4)99.5Cu0.5 samples show two glass transitions-like events, separated by an interval of more than 100 K, in between which a bcc-(Fe,Co) solid solution is formed. The soft magnetic properties are preserved upon Cu-addition and the samples show a saturation magnetization of 1.1 T combined with less than 2 A/m coercivity. The relaxation behavior prior to crystallization, as well as the crystallization behavior, were studied by time-resolved X-ray diffraction using synchrotron radiation. It was found that both glassy alloys behave similar at temperatures below the glass transition. Irreversible structural transformations take place when approaching the glass transition and in the supercooled liquid region.
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    Microstructure, Texture, and Strength Development during High-Pressure Torsion of CrMnFeCoNi High-Entropy Alloy
    (Basel : MDPI, 2020) Skrotzki, Werner; Pukenas, Aurimas; Odor, Eva; Joni, Bertalan; Ungar, Tamas; Völker, Bernhard; Hohenwarter, Anton; Pippan, Reinhard; George, Easo P.
    The equiatomic face-centered cubic high-entropy alloy CrMnFeCoNi was severely deformed at room and liquid nitrogen temperature by high-pressure torsion up to shear strains of about 170. Itsmicrostructurewas analyzed by X-ray line profile analysis and transmission electronmicroscopy and its texture by X-ray microdiffraction. Microhardness measurements, after severe plastic deformation, were done at room temperature. It is shown that at a shear strain of about 20, a steady state grain size of 24 nm, and a dislocation density of the order of 1016 m-2 is reached. The dislocations are mainly screw-type with low dipole character. Mechanical twinning at room temperature is replaced by a martensitic phase transformation at 77 K. The texture developed at room temperature is typical for sheared face-centered cubic nanocrystalline metals, but it is extremely weak and becomes almost random after high-pressure torsion at 77 K. The strength of the nanocrystalline material produced by high-pressure torsion at 77 K is lower than that produced at room temperature. The results are discussed in terms of different mechanisms of deformation, including dislocation generation and propagation, twinning, grain boundary sliding, and phase transformation. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
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    Mechanical properties and twin boundary drag in Fe-Pd ferromagnetic shape memory foils-experiments and ab initio modeling
    (Bristol : IOP, 2011) Claussen, I.; Mayr, S.G.
    We report on vibrating reed measurements combined with density functional theory-based calculations to assess the elastic and damping properties of Fe-Pd ferromagnetic shape memory alloy splats. While the austenite-martensite phase transformation is generally accompanied by lattice softening, a severe modulus defect and elevated damping behavior are characteristic of the martensitic state. We interpret the latter in terms of twin boundary motion between pinning defects via partial 'twinning' dislocations. Energy dissipation is governed by twin boundary drag, primarily due to lattice imperfections, as concluded from the temperature dependence of damping and related activation enthalpies.
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    Microstructure and Mechanical Behavior of Al-Mg Composites Synthesized by Reactive Sintering
    (Basel : MDPI, 2018-9-25) Shahid, Rub Nawaz; Scudino, Sergio
    Lightweight metal matrix composites are synthesized from elemental powder mixtures of aluminum and magnesium using pressure-assisted reactive sintering. The effect of the reaction between aluminum and magnesium on the microstructure and mechanical properties of the composites due to the formation of β-Al3Mg2 and γ-Al12Mg17 intermetallics is investigated. The formation of the intermetallic compounds progressively consumes aluminum and magnesium and induces strengthening of the composites: the yield and compressive strengths increase with the increase of the content of intermetallic reinforcement at the expense of the plastic deformation. The yield strength of the composites follows the iso-stress model when the data are plotted as a function of the intermetallic content.