Search Results
Gradient flow perspective of thin-film bilayer flows
2013, Huth, Robert, Jachalski, Sebastian, Kitavtsev, Georgy, Peschka, Dirk
We study gradient flow formulations of thin-film bilayer flows with triple-junctions between liquid/liquid/air. First we highlight the gradient structure in the Stokes free-boundary flow and identify its solutions with the well-known PDE with boundary conditions. Next we propose a similar gradient formulation for the corresponding thin-film model and formally identify solutions with those of the corresponding free-boundary problem. A robust numerical algorithm for the thin-film gradient flow structure is then provided. Using this algorithm we compare the sharp triple-junction model with precursor models. For their stationary solutions a rigorous connection is established using [Gamma]-convergence. For time-dependentsolutions the comparison of numerical solutions shows a good agreement for small and moderate times. Finally we study spreading in the zero-contact angle case, where we compare numerical solutions with asymptotically exact source-type solutions.
Stationary solutions for two-layer lubrication equations
2011, Jachalski, Sebastian, Huth, Robert, Kitavtsev, Georgy, Peschka, Dirk, Wagner, Barbara
We investigate stationary solutions of flows of thin liquid bilayers in an energetic formulation which is motivated by the gradient flow structure of its lubrication approximation. The corresponding energy favors the liquid substrate to be only partially covered by the upper liquid. This is expressed by a negative spreading coefficient which arises from an intermolecular potential combining attractive and repulsive forces and leads to an ultra-thin layer of thickness e. For the corresponding lubrication models existence of stationary solutions is proven. In the limit e to 0 matched asymptotic analysis is applied to derive sharp-interface models and the corresponding contact angles, i.e. the Neumann triangle. In addition we use G-convergence and derive the equivalent sharp-interface models rigorously in this limit. For the resulting model existence and uniqueness of energetic minimizers are proven. The minimizers agree with solutions obtained by matched asymptotics.
On the spinodal dewetting of thin liquid bilayers
2021, Shiri, Roghayeh, Schmeller, Leonie, Seemann, Ralf, Peschka, Dirk, Wagner, Barbara
We investigate the spinodal dewetting of a thin liquid polystyrene (PS) film on a liquid polymethylmethacrylate (PMMA) subtrate. Following the evolution of the corrugations of the PS film via in situ measurements by atomic force microscopy (AFM) and those of the PS-PMMA interface via ex situ imaging, we provide a direct and detailed comparison of the experimentally determined spinodal wavelengths with the predictions from linear stability analysis of a thin-film continuum model for the bilayer system. The impact of rough interfaces and fluctuations is studied theoretically by investigating the impact of different choices of initial data on the unstable wavelength and on the rupture time. The key factor is the mode selection by initial data perturbed with correlated colored noise in the linearly unstable regime, which becomes relevant only for liquid bilayers to such an extent. By numerically solving the mathematical model, we further address the impact of nonlinear effects on rupture times and on the morphological evolution of the interfaces in comparison with experimental results.