Search Results
Analysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part II: Approximation and a priori estimates
2017, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved NernstPlanckPoisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper, which continues the investigation of [DDGG17a], we derive for thermodynamically consistent approximation schemes the natural uniform estimates associated with the dissipations. Our results essentially improve our former study [DDGG16], in particular the a priori estimates concerning the relative chemical potentials.
Existence of weak solutions for improved Nernst-Planck-Poisson models of compressible reacting electrolytes
2016, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved Nernst-Planck-Poisson model for compressible electrolytes first proposed by Dreyer et al. in 2013. The model takes into account the elastic deformation of the medium. In particular, large pressure contributions near electrochemical interfaces induce an inherent coupling of mass and momentum transport. The model consists of convection-diffusion-reaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity and the Poisson equation for the electrical potential. Cross-diffusion phenomena occur due to the principle of mass conservation. Moreover, the diffusion matrix (mobility matrix) has a zero eigenvalue, meaning that the system is degenerate parabolic. In this paper we establish the existence of a global-in-time weak solution for the full model, allowing for cross-diffusion and an arbitrary number of chemical reactions in the bulk and on the active boundary.
Analysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part III: Compactness and convergence
2017, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved Nernst-Planck-Poisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper, which continues the investigations of [DDGG17a, DDGG17b], we prove the compactness of the solution vector, and existence and convergence for the approximation schemes. We point at simple structural PDE arguments as an adequate substitute to the AubinLions compactness Lemma and its generalisations: These familiar techniques attain their limit in the context of our model in which the relationship between time derivatives (transport) and diffusion gradients is highly non linear.
Analysis of improved Nernst-Planck-Poisson models of isothermal compressible electrolytes subject to chemical reactions: The case of a degenerate mobility matrix
2016, Druet, Pierre-Etienne
We continue our investigations of the improved NernstPlanckPoisson model introduced in [DGM13]. In the paper [DDGG16] the analysis relies on the hypothesis that the mobility matrix has maximal rank under the constraint of mass conservation (rank N-1 for a mixture of N species). In this paper we allow for the case that the positive eigenvalues of the mobility matrix tend to zero along with the partial mass densities of certain species. In this approach the mobility matrix has a variable rank between zero and N-1 according to the number of locally available species. We set up a concept of weak solution able to deal with this scenario, showing in particular how to extend the fundamental notion of differences of chemical potentials that supports the modelling and the analysis in [DDGG16]. We prove the global-in-time existence in this solution class.
A theory of generalised solutions for ideal gas mixtures with Maxwell--Stefan diffusion
2020, Druet, Pierre-Étienne
After the pioneering work by Giovangigli on mathematics of multicomponent flows, several attempts were made to introduce global weak solutions for the PDEs describing the dynamics of fluid mixtures. While the incompressible case with constant density was enlighted well enough due to results by Chen and Jüngel (isothermal case), or Marion and Temam, some open questions remain for the weak solution theory of gas mixtures with their corresponding equations of mixed parabolic-hyperbolic type. For instance, Mucha, Pokorny and Zatorska showed the possibility to stabilise the hyperbolic component by means of the Bresch-Desjardins technique and a regularisation of pressure preventing vacuum. The result by Dreyer, Druet, Gajewski and Guhlke avoids emphex machina stabilisations, but the mathematical assumption that the Onsager matrix is uniformly positive on certain subspaces leads, in the dilute limit, to infinite diffusion velocities which are not compatible with the Maxwell-Stefan form of diffusion fluxes. In this paper, we prove the existence of global weak solutions for isothermal and ideal compressible mixtures with natural diffusion. The main new tool is an asymptotic condition imposed at low pressure on the binary Maxwell-Stefan diffusivities, which compensates possibly extreme behaviour of weak solutions in the rarefied regime.
Analysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part I: Derivation of the model and survey of the results
2017, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved NernstPlanckPoisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper we establish the existence of a globalintime weak solution for the full model, allowing for a general structure of the mobility tensor and for chemical reactions with highly non linear rates in the bulk and on the active boundary. We characterise the singular states of the system, showing that the chemical species can vanish only globally in space, and that this phenomenon must be concentrated in a compact set of measure zero in time. With respect to our former study [DDGG16], we also essentially improve the a priori estimates, in particular concerning the relative chemical potentials.
Mass transport in multicomponent compressible fluids: Local and global well-posedness in classes of strong solutions for general class-one models
2019, Bothe, Dieter, Druet, Pierre-Étienne
We consider a system of partial differential equations describing mass transport in a multicomponent isothermal compressible fluid. The diffusion fluxes obey the Fick-Onsager or Maxwell- Stefan closure approach. Mechanical forces result into one single convective mixture velocity, the barycentric one, which obeys the Navier-Stokes equations. The thermodynamic pressure is defined by the Gibbs-Duhem equation. Chemical potentials and pressure are derived from a thermodynamic potential, the Helmholtz free energy, with a bulk density allowed to be a general convex function of the mass densities of the constituents. The resulting PDEs are of mixed parabolic-hyperbolic type. We prove two theoretical results concerning the well-posedness of the model in classes of strong solutions: 1. The solution always exists and is unique for short-times and 2. If the initial data are sufficiently near to an equilibrium solution, the well-posedness is valid on arbitrary large, but finite time intervals. Both results rely on a contraction principle valid for systems of mixed type that behave like the compressible Navier- Stokes equations. The linearised parabolic part of the operator possesses the self map property with respect to some closed ball in the state space, while being contractive in a lower order norm only. In this paper, we implement these ideas by means of precise a priori estimates in spaces of exact regularity.