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- ItemGiant thermal expansion and α-precipitation pathways in Ti-Alloys(London : Nature Publishing Group, 2017) Bönisch, M.; Panigrahi, A.; Stoica, M.; Calin, M.; Ahrens, E.; Zehetbauer, M.; Skrotzki, W.; Eckert, J.Ti-Alloys represent the principal structural materials in both aerospace development and metallic biomaterials. Key to optimizing their mechanical and functional behaviour is in-depth know-how of their phases and the complex interplay of diffusive vs. displacive phase transformations to permit the tailoring of intricate microstructures across a wide spectrum of configurations. Here, we report on structural changes and phase transformations of Ti-Nb alloys during heating by in situ synchrotron diffraction. These materials exhibit anisotropic thermal expansion yielding some of the largest linear expansion coefficients (+ 163.9×10-6 to-95.1×10-6 °C-1) ever reported. Moreover, we describe two pathways leading to the precipitation of the α-phase mediated by diffusion-based orthorhombic structures, α″lean and α″iso. Via coupling the lattice parameters to composition both phases evolve into α through rejection of Nb. These findings have the potential to promote new microstructural design approaches for Ti-Nb alloys and β-stabilized Ti-Alloys in general.
- ItemMemory effect assisted imaging through multimode optical fibres([London] : Nature Publishing Group UK, 2021) Li, Shuhui; Horsley, Simon A.R.; Tyc, Tomáš; Čižmár, Tomáš; Phillips, David B.When light propagates through opaque material, the spatial information it holds becomes scrambled, but not necessarily lost. Two classes of techniques have emerged to recover this information: methods relying on optical memory effects, and transmission matrix (TM) approaches. Here we develop a general framework describing the nature of memory effects in structures of arbitrary geometry. We show how this framework, when combined with wavefront shaping driven by feedback from a guide-star, enables estimation of the TM of any such system. This highlights that guide-star assisted imaging is possible regardless of the type of memory effect a scatterer exhibits. We apply this concept to multimode fibres (MMFs) and identify a ‘quasi-radial’ memory effect. This allows the TM of an MMF to be approximated from only one end - an important step for micro-endoscopy. Our work broadens the applications of memory effects to a range of novel imaging and optical communication scenarios.
- ItemStructural evolution in Ti-Cu-Ni metallic glasses during heating(New York : American Institute of Physics, 2015) Gargarella, P.; Pauly, S.; Stoica, M.; Vaughan, G.; Afonso, C.R.M.; Kühn, U.; Eckert, J.The structural evolution of Ti50Cu43Ni7 and Ti55Cu35Ni10 metallic glasses during heating was investigated by in-situ synchrotron X-ray diffraction. The width of the most intense diffraction maximum of the glassy phase decreases slightly during relaxation below the glass transition temperature. Significant structural changes only occur above the glass transition manifesting in a change in the respective peak positions. At even higher temperatures, nanocrystals of the shape memory B2-Ti(Cu,Ni) phase precipitate, and their small size hampers the occurrence of a martensitic transformation.
- ItemNematic fluctuations in iron-oxychalcogenide Mott insulators(London : Nature Publishing Group, 2021) Freelon, B.; Sarkar, R.; Kamusella, S.; Brückner, F.; Grinenko, V.; Acharya, Swagata; Laad, Mukul; Craco, Luis; Yamani, Zahra; Flacau, Roxana; Swainson, Ian; Frandsen, Benjamin; Birgeneau, Robert; Liu, Yuhao; Karki, Bhupendra; Alfailakawi, Alaa; Neuefeind, Joerg C.; Everett, Michelle; Wang, Hangdong; Xu, Binjie; Fang, Minghu; Klauss, H.-H.Nematic fluctuations occur in a wide range physical systems from biological molecules to cuprates and iron pnictide high-Tc superconductors. It is unclear whether nematicity in pnictides arises from electronic spin or orbital degrees of freedom. We studied the iron-based Mott insulators La2O2Fe2OM2M = (S, Se), which are structurally similar to pnictides. Nuclear magnetic resonance revealed a critical slowing down of nematic fluctuations and complementary Mössbauerr spectroscopy data showed a change of electrical field gradient. The neutron pair distribution function technique detected local C2 fluctuations while neutron diffraction indicates that global C4 symmetry is preserved. A geometrically frustrated Heisenberg model with biquadratic and single-ion anisotropic terms provides the interpretation of the low temperature magnetic fluctuations. The nematicity is not due to spontaneous orbital order, instead it is linked to geometrically frustrated magnetism based on orbital selectivity. This study highlights the interplay between orbital order and spin fluctuations in nematicity.
- ItemInterpretation of Radio Wave Scintillation Observed through LOFAR Radio Telescopes(London : Institute of Physics Publ., 2022) Forte, Biagio; Fallows, Richard A.; Bisi, Mario M.; Zhang, Jinge; Krankowski, Andrzej; Dabrowski, Bartosz; Rothkaehl, Hanna; Vocks, ChristianRadio waves propagating through a medium containing irregularities in the spatial distribution of the electron density develop fluctuations in their intensities and phases. In the case of radio waves emitted from astronomical objects, they propagate through electron density irregularities in the interstellar medium, the interplanetary medium, and Earth’s ionosphere. The LOFAR radio telescope, with stations across Europe, can measure intensity across the VHF radio band and thus intensity scintillation on the signals received from compact astronomical objects. Modeling intensity scintillation allows the estimate of various parameters of the propagation medium, for example, its drift velocity and its turbulent power spectrum. However, these estimates are based on the assumptions of ergodicity of the observed intensity fluctuations and, typically, of weak scattering. A case study of single-station LOFAR observations of the strong astronomical source Cassiopeia A in the VHF range is utilized to illustrate deviations from ergodicity, as well as the presence of both weak and strong scattering. Here it is demonstrated how these aspects can lead to misleading estimates of the propagation medium properties, for example, in the solar wind. This analysis provides a method to model errors in these estimates, which can be used in the characterization of both the interplanetary medium and Earth’s ionosphere. Although the discussion is limited to the case of the interplanetary medium and Earth’s ionosphere, its ideas are also applicable to the case of the interstellar medium.
- ItemTwo-dimensional imaging in hyperbolic media-the role of field components and ordinary waves([London] : Macmillan Publishers Limited, part of Springer Nature, 2015) Tuniz, Alessandro; Kuhlmey, Boris T.We study full vector imaging of two dimensional source fields through finite slabs of media with extreme anisotropy, such as hyperbolic media. For this, we adapt the exact transfer matrix method for uniaxial media to calculate the two dimensional transfer functions and point spread functions for arbitrary vector fields described in Cartesian coordinates. This is more convenient for imaging simulations than the use of the natural, propagation direction-dependent TE/TM basis and clarifies which field components contribute to sub-diffraction imaging. We study the effect of ordinary waves on image quality, which previous one-dimensional approaches could not consider. Perfect sub-diffraction imaging can be achieved if longitudinal fields are measured, but in the more common case where field intensities or transverse fields are measured, ordinary waves cause artefacts. These become more prevalent when attempting to image large objects with high resolution. We discuss implications for curved hyperbolic imaging geometries such as hyperlenses.
- ItemPotentials of Gaussians and approximate wavelets(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2006) Maz'ya, Vladimir; Schmidt, GuntherWe derive new formulas for harmonic, diffraction, elastic, and hydrodynamic potentials acting on anisotropic Gaussians and approximate wavelets. These formulas can be used to construct accurate cubature formulas for these potentials.