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Elastic properties of single crystal Bi12SiO20 as a function of pressure and temperature and acoustic attenuation effects in Bi12 MO20 (M = Si, Ge and Ti)
2020, Haussühl, Eiken, Reichmann, Hans Josef, Schreuer, Jürgen, Friedrich, Alexandra, Hirschle, Christian, Bayarjargal, Lkhamsuren, Winkler, Björn, Alencar, Igor, Wiehl, Leonore, Ganschow, Steffen
A comprehensive study of sillenite Bi12SiO20 single-crystal properties, including elastic stiffness and piezoelectric coefficients, dielectric permittivity, thermal expansion and molar heat capacity, is presented. Brillouin-interferometry measurements (up to 27 GPa), which were performed at high pressures for the first time, and ab initio calculations based on density functional theory (up to 50 GPa) show the stability of the sillenite structure in the investigated pressure range, in agreement with previous studies. Elastic stiffness coefficients c 11 and c 12 are found to increase continuously with pressure while c 44 increases slightly for lower pressures and remains nearly constant above 15 GPa. Heat-capacity measurements were performed with a quasi-adiabatic calorimeter employing the relaxation method between 2 K and 395 K. No phase transition could be observed in this temperature interval. Standard molar entropy, enthalpy change and Debye temperature are extracted from the data. The results are found to be roughly half of the previous values reported in the literature. The discrepancy is attributed to the overestimation of the Debye temperature which was extracted from high-temperature data. Additionally, Debye temperatures obtained from mean sound velocities derived by Voigt-Reuss averaging are in agreement with our heat-capacity results. Finally, a complete set of electromechanical coefficients was deduced from the application of resonant ultrasound spectroscopy between 103 K and 733 K. No discontinuities in the temperature dependence of the coefficients are observed. High-temperature (up to 1100 K) resonant ultrasound spectra recorded for Bi12 MO20 crystals revealed strong and reversible acoustic dissipation effects at 870 K, 960 K and 550 K for M = Si, Ge and Ti, respectively. Resonances with small contributions from the elastic shear stiffness c 44 and the piezoelectric stress coefficient e 123 are almost unaffected by this dissipation. © 2020 The Author(s). Published by IOP Publishing Ltd.
Bio-responsive polymer hydrogels homeostatically regulate blood coagulation
2013, Maitz, Manfred F., Freudenberg, U., Tsurkan, M.V., Fischer, M., Beyrich, T., Werner, C.
Bio-responsive polymer architectures can empower medical therapies by engaging molecular feedback-response mechanisms resembling the homeostatic adaptation of living tissues to varying environmental constraints. Here we show that a blood coagulation-responsive hydrogel system can deliver heparin in amounts triggered by the environmental levels of thrombin, the key enzyme of the coagulation cascade, which - in turn - becomes inactivated due to released heparin. The bio-responsive hydrogel quantitatively quenches blood coagulation over several hours in the presence of pro-coagulant stimuli and during repeated incubation with fresh, non-anticoagulated blood. These features enable the introduced material to provide sustainable, autoregulated anticoagulation, addressing a key challenge of many medical therapies. Beyond that, the explored concept may facilitate the development of materials that allow the effective and controlled application of drugs and biomolecules.
Regularity of elastic fields in composites
2006, Knees, Dorothee, Sändig, Anna-Margarete
It is well known that high stress concentrations can occur in elastic composites in particular due to the interaction of geometrical singularities like corners, edges and cracks and structural singularities like jumping material parameters. In the project C5 "Stress concentrations in heterogeneous materials" of the SFB 404 "Multifield Problems in Solid and Fluid Mechanics" it was mathematically analyzed where and which kind of stress singularities in coupled linear and nonlinear elastic structures occur. In the linear case asymptotic expansions near the geometrical and structural peculiarities are derived, formulae for generalized stress intensity factors included. In the nonlinear case such expansions are unknown in general and regularity results are proved for elastic materials with power-law constitutive equations with the help of the difference quotient technique combined with a quasi-monotone covering condition for the subdomains and the energy densities. Furthermore, some applications of the regularity results to shape and structure optimization and the Griffith fracture criterion in linear and nonlinear elastic structures are discussed. Numerical examples illustrate the results.
Phase transition and hysteresis in a rechargeable lithium battery revisited
2009, Dreyer, Wolfgang, Gaberscek, Miran, Guhlke, Clemens, Huth, Robert, Jamnik, Janko
We revisit a model which describes the evolution of a phase transition that occurs in the cathode of a rechargeable lithium battery during the process of charging/discharging. The model is capable to simulate hysteretic behavior of the voltage
Fiscal Consolidation Programs and Income Inequality
2020, Brinca, Pedro, Ferreira, Miguel H., Franco, Francesco, Holter, Hans A., Malafry, Laurence
We document a strong empirical relationship between higher income inequality and stronger recessive impacts of fiscal consolidation episodes across time and space. To explain this finding, we develop a life-cycle economy with uninsurable income risk. We calibrate our model to match key characteristics of several European economies, including inequality and fiscal structures, and study the effects of fiscal consolidation programs. In our model, higher income risk induces precautionary savings behavior, which decreases the proportion of credit-constrained agents in the economy. These agents have less elastic labor supply responses to fiscal consolidations, which explain the correlation with inequality in the data.
Two types of magnetic shape-memory effects from twinned microstructure and magneto-structural coupling in Fe1 +yTe
2019, Rößler, S., Koz, C., Wang, Z., Skourski, Y., Doerr, M., Kasinathan, D., Rosner, H., Schmidt, M., Schwarz, U., Rößler, U.K., Wirth, S.
A detailed experimental investigation of Fe1+yTe (y = 0.11, 0.12) using pulsed magnetic fields up to 60 T confirms remarkable magnetic shape-memory (MSM) effects. These effects result from magnetoelastic transformation processes in the low-temperature antiferromagnetic state of these materials. The observation of modulated and finely twinned microstructure at the nanoscale through scanning tunneling microscopy establishes a behavior similar to that of thermoelastic martensite. We identified the observed, elegant hierarchical twinning pattern of monoclinic crystallographic domains as an ideal realization of crossing twin bands. The antiferromagnetism of the monoclinic ground state allows for a magnetic-field–induced reorientation of these twin variants by the motion of one type of twin boundaries. At sufficiently high magnetic fields, we observed a second isothermal transformation process with large hysteresis for different directions of applied field. This gives rise to a second MSM effect caused by a phase transition back to the field-polarized tetragonal lattice state.
Fractal homogenization of a multiscale interface problem
2017, Heida, Martin, Kornhuber, Ralf, Podlesny, Joscha
Inspired from geological problems, we introduce a new geometrical setting for homogenization of a well known and well studied problem of an elliptic second order differential operator with jump condition on a multiscale network of interfaces. The geometrical setting is fractal and hence neither periodic nor stochastic methods can be applied to the study of such kind of multiscale interface problem. Instead, we use the fractal nature of the geometric structure to introduce smoothed problems and apply methods from a posteriori theory to derive an estimate for the order of convergence. Computational experiments utilizing an iterative homogenization approach illustrate that the theoretically derived order of convergenceof the approximate problems is close to optimal.
Promoting abnormal grain growth in Fe-based shape memory alloys through compositional adjustments
2019, Vollmer, M., Arold, T., Kriegel, M.J., Klemm, V., Degener, S., Freudenberger, J., Niendorf, T.
Iron-based shape memory alloys are promising candidates for large-scale structural applications due to their cost efficiency and the possibility of using conventional processing routes from the steel industry. However, recently developed alloy systems like Fe–Mn–Al–Ni suffer from low recoverability if the grains do not completely cover the sample cross-section. To overcome this issue, here we show that small amounts of titanium added to Fe–Mn–Al–Ni significantly enhance abnormal grain growth due to a considerable refinement of the subgrain sizes, whereas small amounts of chromium lead to a strong inhibition of abnormal grain growth. By tailoring and promoting abnormal grain growth it is possible to obtain very large single crystalline bars. We expect that the findings of the present study regarding the elementary mechanisms of abnormal grain growth and the role of chemical composition can be applied to tailor other alloy systems with similar microstructural features.
An anisotropic, inhomogeneous, elastically modified Gibbs-Thomson law as singular limit of a diffuse interface model
2009, Garcke, Harald, Kraus, Christiane
We consider the sharp interface limit of a diffuse phase field model with prescribed total mass taking into account a spatially inhomogeneous anisotropic interfacial energy and an elastic energy. The main aim is the derivation of a weak formulation of an anisotropic, inhomogeneous, elastically modified Gibbs-Thomson law in the sharp interface limit. To this end we show that one can pass to the limit in the weak formulation of the Euler-Lagrange equation of the diffuse phase field energy
The behavior of a many particle cathode in a lithium-ion battery
2009, Dreyer, Wolfgang, Guhlke, Clemens, Huth, Robert
We study the almost reversible storage process of charging and discharging of lithium-ion batteries. That process is accompanied by a phase transition and charging and discharging run along different paths, so that hysteretic behavior is observed. We are interested in the storage problem of the cathode of a lithium-ion battery consisting of a system of many iron phosphate (FePO4) particles. There are mathematical models, see [DGJ08], [DGGHJ09] and [DG09], that describe phase transitions and hysteresis exclusively in a single storage particle and they can describe the observed hysteretic voltage-charge plots with almost horizontal plateaus. Interestingly the models predict that the coexistence of a 2-phase system in an individual particle disappears, if its size is below a critical value. The disappearance of the phase transition in the single particle model implies the disappearance of the hysteresis. However, in the experiment hysteretic behavior survives. In other words: The behavior of a storage system consisting of many particles is qualitatively independent of the fact whether the individual particles itself develop a 2-phase system or if they remain in a single phase state. This apparent paradoxical observation will be resolved in this article by a many particle model. It will be shown that if each of the individual particles is in a homogeneous state, nevertheless the many particle ensemble exhibits phase transition and hysteresis ...