Search Results
Explicit modeling of volatile organic compounds partitioning in the atmospheric aqueous phase
The gas phase oxidation of organic species is a multigenerational process involving a large number of secondary compounds. Most secondary organic species are water-soluble multifunctional oxygenated molecules. The fully explicit chemical mechanism GECKO-A (Generator of Explicit Chemistry and Kinetics of Organics in the Atmosphere) is used to describe the oxidation of organics in the gas phase and their mass transfer to the aqueous phase. The oxidation of three hydrocarbons of atmospheric interest (isoprene, octane and α-pinene) is investigated for various NOx conditions. The simulated oxidative trajectories are examined in a new two dimensional space defined by the mean oxidation state and the solubility. The amount of dissolved organic matter was found to be very low (yield less than 2% on carbon atom basis) under a water content typical of deliquescent aerosols. For cloud water content, 50% (isoprene oxidation) to 70% (octane oxidation) of the carbon atoms are found in the aqueous phase after the removal of the parent hydrocarbons for low NOx conditions. For high NOx conditions, this ratio is only 5% in the isoprene oxidation case, but remains large for α-pinene and octane oxidation cases (40% and 60%, respectively). Although the model does not yet include chemical reactions in the aqueous phase, much of this dissolved organic matter should be processed in cloud drops and modify both oxidation rates and the speciation of organic species.
Time-lapse gravity and levelling surveys reveal mass loss and ongoing subsidence in the urban subrosion-prone area of Bad Frankenhausen, Germany
We present results of sophisticated, high-precision time-lapse gravity monitoring that was conducted over 4 years in Bad Frankenhausen (Germany). To our knowledge, this is the first successful attempt to monitor subrosion-induced mass changes in urban areas with repeated gravimetry. The method provides an approach to estimate the mass of dissolved rocks in the subsurface. Subrosion, i.e. leaching and transfer of soluble rocks, occurs worldwide. Mainly in urban areas, any resulting ground subsidence can cause severe damage, especially if catastrophic events, i.e. collapse sinkholes, occur. Monitoring strategies typically make use of established geodetic methods, such as levelling, and therefore focus on the associated deformation processes. In this study, we combine levelling and highly precise time-lapse gravity observations. Our investigation area is the urban area of Bad Frankenhausen in central Germany, which is prone to subrosion, as many subsidence and sinkhole features on the surface reveal. The city and the surrounding areas are underlain by soluble Permian deposits, which are continuously dissolved by meteoric water and groundwater in a strongly fractured environment. Between 2014 and 2018, a total of 17 high-precision time-lapse gravimetry and 18 levelling campaigns were carried out in quarterly intervals within a local monitoring network. This network covers historical sinkhole areas but also areas that are considered to be stable. Our results reveal ongoing subsidence of up to 30.4 mm a−1 locally, with distinct spatiotemporal variations. Furthermore, we observe a significant time-variable gravity decrease on the order of 8 µGal over 4 years at several measurement points. In the processing workflow, after the application of all required corrections and least squares adjustment to our gravity observations, a significant effect of varying soil water content on the adjusted gravity differences was figured out. Therefore, we place special focus on the correlation of these observations and the correction of the adjusted gravity differences for soil water variations using the Global Land Data Assimilation System (GLDAS) Noah model to separate these effects from subrosion-induced gravity changes. Our investigations demonstrate the feasibility of high-precision time-lapse gravity monitoring in urban areas for sinkhole investigations. Although the observed rates of gravity decrease of 1–2 µGal a−1 are small, we suggest that it is significantly associated with subterranean mass loss due to subrosion processes. We discuss limitations and implications of our approach, as well as give a first quantitative estimation of mass transfer at different depths and for different densities of dissolved rocks.
Kinematic first-order calving law implies potential for abrupt ice-shelf retreat
Recently observed large-scale disintegration of Antarctic ice shelves has moved their fronts closer towards grounded ice. In response, ice-sheet discharge into the ocean has accelerated, contributing to global sea-level rise and emphasizing the importance of calving-front dynamics. The position of the ice front strongly influences the stress field within the entire sheet-shelf-system and thereby the mass flow across the grounding line. While theories for an advance of the ice-front are readily available, no general rule exists for its retreat, making it difficult to incorporate the retreat in predictive models. Here we extract the first-order large-scale kinematic contribution to calving which is consistent with large-scale observation. We emphasize that the proposed equation does not constitute a comprehensive calving law but represents the first-order kinematic contribution which can and should be complemented by higher order contributions as well as the influence of potentially heterogeneous material properties of the ice. When applied as a calving law, the equation naturally incorporates the stabilizing effect of pinning points and inhibits ice shelf growth outside of embayments. It depends only on local ice properties which are, however, determined by the full topography of the ice shelf. In numerical simulations the parameterization reproduces multiple stable fronts as observed for the Larsen A and B Ice Shelves including abrupt transitions between them which may be caused by localized ice weaknesses. We also find multiple stable states of the Ross Ice Shelf at the gateway of the West Antarctic Ice Sheet with back stresses onto the sheet reduced by up to 90 % compared to the present state.