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Self-Consistent Cathode–Plasma Coupling and Role of the Fluid Flow Approach in Torch Modeling
A two-dimensional and stationary magnetohydrodynamic model of a plasma spray torch operated with argon is developed to predict the plasma properties in a steady operating mode. The model couples a submodel of a refractory cathode and its non-equilibrium boundary layer to a submodel of the plasma in local thermodynamic equilibrium in a self-consistent manner. The Navier–Stokes equations for a laminar and compressible flow are solved in terms of low and high Mach number numerical approaches. The results show that the Mach number can reach values close to one. Simulations are performed for electric currents of 600 A and 800 A, and gas flow rates of 40, 60, and 80 NLPM. The plasma parameters obtained by the two approaches differ, and the differences become more pronounced for higher currents and gas flow rates. The arc voltage, the electric power, and the thermal efficiency from both the low and high Mach number models of the plasma agree well with experimental findings for a current of 600 A and a flow rate of 40 NLPM. For higher currents and gas flow rates, the results of the low and high Mach number models gradually differ and underline the greater appropriateness of the high Mach number model.
Modelling and experimental evidence of the cathode erosion in a plasma spray torch
The lifetime of tungsten cathodes used in plasma spray torches is limited by processes leading to a loss of cathode material. It was reported in the literature that the mechanism of their erosion is the evaporation. A model of the ionization layer of a cathode is developed to study the diffusive transport of evaporated tungsten atoms and tungsten ions produced due to ionization by electron impact in a background argon plasma. It is shown that the Stefan-Maxwell equations do not reduce to Fick law as one could expect for the transport of diluted species, which is due to significant diffusion velocities of argon ions. The ionization of tungsten atoms occurs in a distance of a few micrometers from the cathode surface and leads to a strong sink, which increases the net flux of tungsten atoms far beyond that obtained in absence of tungsten ions. This shows that the tungsten ions are driven by the electric field towards the cathode resulting in no net diffusive flux and no removal of tungsten species from the ionization layer even if convection is accounted for. A possible mechanism of removal is found by extending the model to comprise an anode. The extended model resolves the inter-electrode region and provides the plasma parameters for a current density corresponding to the value at the center of the cathode under typical arc currents of 600 A and 800 A. The presence of the anode causes a reversal of the electric field on the anode side, which pulls the ions away from the ionization layer of the cathode. The net flux of tungsten ions can be further fortified by convection. This model allows one to evaluate the loss of cathode material under realistic operating conditions in a quantitative agreement with measured values.