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Subject: pulsed power ×

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    Hydrogen peroxide production of underwater nanosecond-pulsed streamer discharges with respect to pulse parameters and associated discharge characteristics
    (Bristol : IOP Publ., 2022) Rataj, Raphael; Werneburg, Matthias; Below, Harald; Kolb, Juergen F.
    Abstract Pulsed streamer discharges submerged in water have demonstrated potential in a number of applications. Especially the generation of discharges by short high-voltage pulses in the nanosecond range has been found to offer advantages with respect to efficacies and efficiencies. The exploited plasma chemistry generally relies on the initial production of short-lived species, e.g. hydroxyl radicals. Since the diagnostic of these transient species is not readily possible, a quantification of hydrogen peroxide provides an adequate assessment of underlying reactions. These conceivably depend on the characteristics of the high-voltage pulses, such as pulse duration, pulse amplitude, as well as pulse steepness. A novel electrochemical flow-injection system was used to relate these parameters to hydrogen peroxide concentrations. Accordingly, the accumulated hydrogen peroxide production for streamer discharges ignited in deionized water was investigated for pulse durations of 100 ns and 300 ns, pulse amplitudes between 54 kV and 64 kV, and pulse rise times from 16 ns to 31 ns. An independent control of the individual pulse parameters was enabled by providing the high-voltage pulses with a Blumlein line. Applied voltage, discharge current, optical light emission and time-integrated images were recorded for each individual discharge to determine dissipated energy, inception statistic, discharge expansion and the lifetime of a discharge. Pulse steepness did not affect the hydrogen peroxide production rate, but an increase in amplitude of 10 kV for 100 ns pulses nearly doubled the rate to (0.19 ± 0.01) mol l−1 s−1, which was overall the highest determined rate. The energy efficiency did not change with pulse amplitude, but was sensitive to pulse duration. Notably, production rate and efficiency doubled when the pulse duration decreased from 300 ns to 100 ns, resulting in the best peroxide production efficiency of (9.2 ± 0.9) g kWh−1. The detailed analysis revealed that the hydrogen peroxide production rate could be described by the energy dissipation in a representative single streamer. The production efficiency was affected by the corresponding discharge volume, which was comprised by the collective volume of all filaments. Hence, dissipating more energy in a filament resulted in an increased production rate, while increasing the relative volume of the discharge compared to its propagation time increased the energy efficiency.
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    Effective streamer discharge control by tailored nanosecond-pulsed high-voltage waveforms
    (Bristol : IOP Publ., 2021) Huiskamp, T.; Ton, C.; Azizi, M.; van Oorschot, J.J.; Höft, H.
    In this paper we present our solid-state nanosecond pulse source (the solid-state impedance-matched Marx generator) which can generate arbitrary waveforms and which can be used for pulsed discharge generation. The purpose of the development of such a generator is twofold: by being able to change the waveform at will, we aim to control the discharge generated by such pulses very precisely which can be very useful for plasma applications, but also for more fundamental studies. In the presented study, we applied the arbitrary-waveform pulse source for streamer discharge generation in a cylinder-wire-like arrangement and used the arbitrary-waveform capability to change the rise time (in our experiments we used 6.8-26.2 ns) of unipolar positive pulses with 6-10 kV amplitude and 80 ns duration. Additionally, we introduced variations of a step in the rising edge of the waveform. We performed measurements both in air and nitrogen to electrically characterize the discharge while analyzing the streamer propagation in the plasma reactor with intensified charge-coupled device imaging and measured ozone generation (in air). The results show that we can indeed control the propagation of the streamer discharge with the stepped waveform, but that the rise-time variation has little effect on the streamer propagation in our system. However, the streamer velocity and structure differs significantly comparing discharges in nitrogen and air for the same applied voltage waveform. Additionally, for some of the stepped waveforms we found a slight increase of the ozone yield for air at low overall energy densities.