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Subject: thermomagnetic materials ×

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    Efficient and affordable thermomagnetic materials for harvesting low grade waste heat
    (College Park, ML : American Institute of Physics, 2021) Dzekan, Daniel; Waske, Anja; Nielsch, Kornelius; Fähler, Sebastian
    Industrial processes release substantial quantities of waste heat, which can be harvested to generate electricity. At present, the conversion of low grade waste heat to electricity relies solely on thermoelectric materials, but such materials are expensive and have low thermodynamic efficiencies. Although thermomagnetic materials may offer a promising alternative, their performance remains to be evaluated, thereby hindering their real-world application. Here, the efficiency and cost effectiveness of thermomagnetic materials are evaluated for the usage in motors, oscillators, and generators for converting waste heat to electricity. The analysis reveals that up to temperature differences of several 10 K, the best thermomagnetic materials have the potential to compete with thermoelectric materials. Importantly, it is found that the price per watt of some thermomagnetic materials is much lower compared to that of present-day thermoelectrics, which can become competitive with conventional power plants. This materials library enables the selection of the best available thermomagnetic materials for harvesting waste heat and gives guidelines for their future development.
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    Can gadolinium compete with La-Fe-Co-Si in a thermomagnetic generator?
    (Abingdon : Taylor & Francis, 2021) Dzekan, Daniel; Diestel, Anett; Berger, Dietmar; Nielsch, Kornelius; Fähler, Sebastian
    A thermomagnetic generator is a promising technology to harvest low-grade waste heat and convert it into electricity. To make this technology competitive with other technologies for energy harvesting near room temperature, the optimum thermomagnetic material is required. Here we compare the performance of a state of the art thermomagnetic generator using gadolinium and La-Fe-Co-Si as thermomagnetic material, which exhibit strong differences in thermal conductivity and type of magnetic transition. gadolinium is the established benchmark material for magnetocaloric cooling, which follows the reverse energy conversion process as compared to thermomagnetic energy harvesting. Surprisingly, La-Fe-Co-Si outperforms gadolinium in terms of voltage and power output. Our analysis reveals the differences in thermal conductivity are less important than the particular shape of the magnetization curve. In gadolinium an unsymmetrical magnetization curve is responsible for an uncompensated magnetic flux, which results in magnetic stray fields. These stray fields represent an energy barrier in the thermodynamic cycle and reduce the output of the generator. Our detailed experiments and simulations of both, thermomagnetic materials and generator, clearly reveal the importance to minimize magnetic stray fields. This is only possible when using materials with a symmetrical magnetization curve, such as La-Fe-Co-Si.