Salts of HCN-Cyanide Aggregates : [CN(HCN)2]− and [CN(HCN)3]−
dc.bibliographicCitation.firstPage | 10508 | eng |
dc.bibliographicCitation.issue | 26 | eng |
dc.bibliographicCitation.lastPage | 10513 | eng |
dc.bibliographicCitation.volume | 59 | eng |
dc.contributor.author | Bläsing, Kevin | |
dc.contributor.author | Harloff, Jörg | |
dc.contributor.author | Schulz, Axel | |
dc.contributor.author | Stoffers, Alrik | |
dc.contributor.author | Stoer, Philip | |
dc.contributor.author | Villinger, Alexander | |
dc.date.accessioned | 2021-09-02T09:26:15Z | |
dc.date.available | 2021-09-02T09:26:15Z | |
dc.date.issued | 2020 | |
dc.description.abstract | Although pure hydrogen cyanide can spontaneously polymerize or even explode, when initiated by small amounts of bases (e.g. CN−), the reaction of liquid HCN with [WCC]CN (WCC=weakly coordinating cation=Ph4P, Ph3PNPPh3=PNP) was investigated. Depending on the cation, it was possible to extract salts containing the formal dihydrogen tricyanide [CN(HCN)2]− and trihydrogen tetracyanide ions [CN(HCN)3]− from liquid HCN when a fast crystallization was carried out at low temperatures. X-ray structure elucidation revealed hydrogen-bridged linear [CN(HCN)2]− and Y-shaped [CN(HCN)3]− molecular ions in the crystal. Both anions can be considered members of highly labile cyanide-HCN solvates of the type [CN(HCN)n]− (n=1, 2, 3 …) as well as formal polypseudohalide ions. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6660 | |
dc.identifier.uri | https://doi.org/10.34657/5708 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/anie.201915206 | |
dc.relation.essn | 1521-3773 | |
dc.relation.ispartofseries | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition 59 (2020), Nr. 26 | eng |
dc.relation.issn | 0570-0833 | |
dc.relation.issn | 1433-7851 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject | hydrogen bonding | eng |
dc.subject | hydrogen cyanide | eng |
dc.subject | solvates | eng |
dc.subject | structure elucidation | eng |
dc.subject.ddc | 540 | eng |
dc.title | Salts of HCN-Cyanide Aggregates : [CN(HCN)2]− and [CN(HCN)3]− | eng |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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