Immobilized Ru‐Pincer Complexes for Continuous Gas‐Phase Low‐Temperature Methanol Reforming‐Improving the Activity by a Second Ru‐Complex and Variation of Hydroxide Additives

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dc.bibliographicCitation.firstPage1745eng
dc.bibliographicCitation.issue18eng
dc.bibliographicCitation.journalTitleEuropean journal of inorganic chemistryeng
dc.bibliographicCitation.lastPage1751eng
dc.bibliographicCitation.volume2021eng
dc.contributor.authorSchwarz, Christian H.
dc.contributor.authorKraus, Dominik
dc.contributor.authorAlberico, Elisabetta
dc.contributor.authorJunge, Henrik
dc.contributor.authorHaumann, Marco
dc.date.accessioned2022-01-25T10:20:54Z
dc.date.available2022-01-25T10:20:54Z
dc.date.issued2021
dc.description.abstractRu-pincer complexes were immobilized as supported liquid phase (SLP) materials to allow the methanol reforming reaction as continuous gas phase process. Under reaction conditions, the liquid phase forms from the hydroxide coating. Several hydroxides were screened and CsOH showed highest activity compared to the standard KOH coating. The well-known Ru-pincer complex carbonylchlorohydrido [bis(2-di-i-propylphosphinoethyl)amine]ruthenium(II) is limited in catalyzing the final step of the methanol reforming. Addition of a second complex, having a methylated backbone in the pincer-ligand, could overcome these limitations. Significant enhancement of the overall catalytic activity was observed.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/7914
dc.identifier.urihttps://doi.org/10.34657/6955
dc.language.isoengeng
dc.publisherWeinheim : Wiley-VCHeng
dc.relation.doihttps://doi.org/10.1002/ejic.202100042
dc.relation.essn1099-0682
dc.rights.licenseCC BY-NC-ND 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/eng
dc.subject.ddc540eng
dc.subject.otherAlkali hydroxideeng
dc.subject.otherImmobilizationeng
dc.subject.otherMethanol reformingeng
dc.subject.otherRu-pincer catalysteng
dc.subject.otherSupported liquid phaseeng
dc.titleImmobilized Ru‐Pincer Complexes for Continuous Gas‐Phase Low‐Temperature Methanol Reforming‐Improving the Activity by a Second Ru‐Complex and Variation of Hydroxide Additiveseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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