(tert-Butylimido)bis(η5-cyclopenta-dienyl) pyridinezirconium(IV)
| dc.bibliographicCitation.issue | 9 | |
| dc.bibliographicCitation.volume | 66 | eng |
| dc.contributor.author | Kaleta, K. | |
| dc.contributor.author | Arndt, P. | |
| dc.contributor.author | Spannenberg, A. | |
| dc.contributor.author | Rosenthal, U. | |
| dc.date.accessioned | 2020-08-11T08:32:48Z | |
| dc.date.available | 2020-08-11T08:32:48Z | |
| dc.date.issued | 2010 | |
| dc.description.abstract | The title compound, [Zr(C5H5)2(C 4H9N)(C5H5N)], was obtained from the reaction of (C5H5)2Zr(py)(η2- Me3SiC2SiMe3) (py is pyridine) and tBuN=C=NtBu alongside the formation of (C 5H5)2Zr(CNtBu)(2-Me 3SiC2SiMe3). The zirconium atom is coordinated in a distorted tetrahedral geometry by two cyclopentadienyl ligands, a pyridine ligand, and a tertbutylimido ligand via a Zr=N double bond. The tertbutyl group is disordered over two positions in a 0.634 (5):0.366 (5) ratio. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4046 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5417 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536810033556 | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 66 (2010), 9 | eng |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject | Crystal structure | eng |
| dc.subject | Chemistry | eng |
| dc.subject | Crystallography | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | (tert-Butylimido)bis(η5-cyclopenta-dienyl) pyridinezirconium(IV) | eng |
| dc.type | article | eng |
| dc.type | Text | eng |
| dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |