Trans-Di-μ-acetato-[μ-N,N-bis-(diphenyl-phosphino)aniline] bis-[chlorido-molybdenum(II)](Mo - Mo)-dichloro-methane-tetra-hydro-furan (1/0.3/1.7)
| dc.bibliographicCitation.issue | 4 | |
| dc.bibliographicCitation.volume | 65 | eng |
| dc.contributor.author | Hapke, M. | |
| dc.contributor.author | Wöhl, A. | |
| dc.contributor.author | Peitz, S. | |
| dc.contributor.author | Spannenberg, A. | |
| dc.contributor.author | Rosenthal, U. | |
| dc.date.accessioned | 2020-08-11T08:32:49Z | |
| dc.date.available | 2020-08-11T08:32:49Z | |
| dc.date.issued | 2009 | |
| dc.description.abstract | The mol-ecular structure of the title compound, [Mo2(CH 3COO)2Cl2(C30H25NP 2)]·0.3CH2Cl2·1.7C 4H8O, features an Mo - Mo dumbbell bridged by two acetate groups which are trans to each other. Perpendicular to the plane spanned by the acetate groups, the Ph2PN(Ph)PPh2 ligand bridges both Mo atoms, having a P - N - P angle of 114.09 (19)°. In a trans position to the PNP ligand are two Cl atoms, one on each molybdenum centre. The Mo - Mo bond distance is 2.1161 (9) Å, within the range known for Mo - Mo quadruple bonds. The Mo complex is located on a crystallographic twofold rotation axis which runs through the N - C bond of the ligand. The site occupation factors of the disordered solvent molecules were fixed to 0.15 for dichloromethane and 0.85 for tetrahydrofuran. © 2009. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4060 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5431 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536809007016 | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 65 (2009), 4 | eng |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject | Crystal structure | eng |
| dc.subject | Chemistry | eng |
| dc.subject | Crystallography | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | Trans-Di-μ-acetato-[μ-N,N-bis-(diphenyl-phosphino)aniline] bis-[chlorido-molybdenum(II)](Mo - Mo)-dichloro-methane-tetra-hydro-furan (1/0.3/1.7) | eng |
| dc.type | article | eng |
| dc.type | Text | eng |
| dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| local.doifilter.override | ja | |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |