Nickel-catalysed carbonylative homologation of aryl iodides

dc.bibliographicCitation.firstPage87eng
dc.bibliographicCitation.issue1eng
dc.bibliographicCitation.journalTitleCommunications Chemistryeng
dc.bibliographicCitation.lastPage242eng
dc.bibliographicCitation.volume1eng
dc.contributor.authorPeng, J.-B.
dc.contributor.authorWu, F.-P.
dc.contributor.authorQi, X.
dc.contributor.authorYing, J.
dc.contributor.authorWu, X.-F.
dc.date.accessioned2020-07-13T11:01:16Z
dc.date.available2020-07-13T11:01:16Z
dc.date.issued2018
dc.description.abstractHomologation is an important organic transformation which extends the carbon chain of a parent molecule, and many procedures have been established. However, although carbonylation reactions are now well developed as valuable methods for the synthesis of carbonyl-containing compounds, studies of carbonylative homologation are limited. Here we report a nickel-catalysed carbonylative homologation of aryl iodides. With molybdenum hexacarbonyl as the solid carbon monoxide source and silane as the deoxygenation reagent, benzylic units can be effectively produced. Various (hetero)arenes can be successfully benzylated and give the corresponding products in moderate to excellent yields.eng
dc.description.fondsLeibniz_Fonds
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/3512
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/4883
dc.language.isoengeng
dc.publisherLondon : Springer Natureeng
dc.relation.doihttps://doi.org/10.1038/s42004-018-0091-2
dc.relation.issn2399-3669
dc.rights.licenseCC BY 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/eng
dc.subject.ddc540eng
dc.subject.otherHomologationeng
dc.subject.othercarbon chaineng
dc.subject.othercarbonylative homologationeng
dc.titleNickel-catalysed carbonylative homologation of aryl iodideseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Peng et al 2018, Nickel-catalysed carbonylative homologation of aryl iodides.pdf
Size:
623.29 KB
Format:
Adobe Portable Document Format
Description:
Collections