1,7,9,10-Tetrasubstituted PMIs Accessible through Decarboxylative Bromination: Synthesis, Characterization, Photophysical Studies, and Hydrogen Evolution Catalysis

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dc.bibliographicCitation.firstPage4081eng
dc.bibliographicCitation.issue12eng
dc.bibliographicCitation.lastPage4088eng
dc.bibliographicCitation.volume27eng
dc.contributor.authorCostabel, Daniel
dc.contributor.authorSkabeev, Artem
dc.contributor.authorNabiyan, Afshin
dc.contributor.authorLuo, Yusen
dc.contributor.authorMax, Johannes B.
dc.contributor.authorRajagopal, Ashwene
dc.contributor.authorKowalczyk, Daniel
dc.contributor.authorDietzek, Benjamin
dc.contributor.authorWächtler, Maria
dc.contributor.authorGörls, Helmar
dc.contributor.authorZiegenbalg, Dirk
dc.contributor.authorZagranyarski, Yulian
dc.contributor.authorStreb, Carsten
dc.contributor.authorSchacher, Felix H.
dc.contributor.authorPeneva, Kalina
dc.date.accessioned2022-05-05T05:28:16Z
dc.date.available2022-05-05T05:28:16Z
dc.date.issued2020
dc.description.abstractIn this work, we present a new synthetic strategy for fourfold-substituted perylene monoimides via tetrabrominated perylene monoanhydrides. X-ray diffraction analysis unveiled the intramolecular stacking orientation between the substituents and semicircular packing behavior. We observed the remarkable influence of the substituent on the longevity and nature of the excited state upon visible light excitation. In the presence of poly(dehydroalanine)-graft-poly(ethylene glycol) graft copolymers as solubilizing template, the chromophores are capable of sensitizing [Mo3S13]2− clusters in aqueous solution for stable visible light driven hydrogen evolution over three days. © 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbHeng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/8854
dc.identifier.urihttps://doi.org/10.34657/7892
dc.language.isoengeng
dc.publisherWeinheim : Wiley-VCHeng
dc.relation.doihttps://doi.org/10.1002/chem.202004326
dc.relation.essn1521-3765
dc.relation.ispartofseriesChemistry - A European Journal 26 (2021), Nr. 12eng
dc.rights.licenseCC BY-NC-ND 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/eng
dc.subjecthydrogen evolutioneng
dc.subjectorganic dyeseng
dc.subjectperylene monoimideseng
dc.subjectphotosensitizerseng
dc.subjecttransient absorptioneng
dc.subject.ddc540eng
dc.subject.ddc660eng
dc.title1,7,9,10-Tetrasubstituted PMIs Accessible through Decarboxylative Bromination: Synthesis, Characterization, Photophysical Studies, and Hydrogen Evolution Catalysiseng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleChemistry - A European Journaleng
tib.accessRightsopenAccesseng
wgl.contributorIPHTeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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