(+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate
dc.bibliographicCitation.issue | 11 | |
dc.bibliographicCitation.volume | 66 | eng |
dc.contributor.author | Schulz, S. | |
dc.contributor.author | Fischer, C. | |
dc.contributor.author | Drexler, H.-J. | |
dc.contributor.author | Heller, D. | |
dc.date.accessioned | 2020-08-11T08:32:48Z | |
dc.date.available | 2020-08-11T08:32:48Z | |
dc.date.issued | 2010 | |
dc.description.abstract | The title compound, [Rh(C8H12)(C18H 36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate 2, 2-coordinated cyclo-octa-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intra-molecular P-Rh-P bite angle of 83.91 (2)° is observed. The dihedral angle between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) is 14.0 (1)°. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://doi.org/10.34657/4044 | |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5415 | |
dc.language.iso | eng | eng |
dc.publisher | Chester : International Union of Crystallography | eng |
dc.relation.doi | https://doi.org/10.1107/S1600536810039577 | |
dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 66 (2010), 11 | eng |
dc.relation.issn | 1600-5368 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject | Crystal structure | eng |
dc.subject | Chemistry | eng |
dc.subject | Crystallography | eng |
dc.subject.ddc | 540 | eng |
dc.title | (+)-{1,2-Bis[(2R,5R)-2,5-diethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(≠4-cyclo-octa-1,5-diene)rhodium(I) tetra-fluoridoborate | eng |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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