High-Quality Graphene Using Boudouard Reaction
dc.bibliographicCitation.firstPage | 2200217 | eng |
dc.bibliographicCitation.issue | 12 | eng |
dc.bibliographicCitation.volume | 9 | eng |
dc.contributor.author | Grebenko, Artem K. | |
dc.contributor.author | Krasnikov, Dmitry V. | |
dc.contributor.author | Bubis, Anton V. | |
dc.contributor.author | Stolyarov, Vasily S. | |
dc.contributor.author | Vyalikh, Denis V. | |
dc.contributor.author | Makarova, Anna A. | |
dc.contributor.author | Fedorov, Alexander | |
dc.contributor.author | Aitkulova, Aisuluu | |
dc.contributor.author | Alekseeva, Alena A. | |
dc.contributor.author | Gilshtein, Evgeniia | |
dc.contributor.author | Bedran, Zakhar | |
dc.contributor.author | Shmakov, Alexander N. | |
dc.contributor.author | Alyabyeva, Liudmila | |
dc.contributor.author | Mozhchil, Rais N. | |
dc.contributor.author | Ionov, Andrey M. | |
dc.contributor.author | Gorshunov, Boris P. | |
dc.contributor.author | Laasonen, Kari | |
dc.contributor.author | Podzorov, Vitaly | |
dc.contributor.author | Nasibulin, Albert G. | |
dc.date.accessioned | 2022-07-11T07:56:03Z | |
dc.date.available | 2022-07-11T07:56:03Z | |
dc.date.issued | 2022 | |
dc.description.abstract | Following the game-changing high-pressure CO (HiPco) process that established the first facile route toward large-scale production of single-walled carbon nanotubes, CO synthesis of cm-sized graphene crystals of ultra-high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO2 mixture and maintains a high growth rate of graphene seeds reaching large-scale monocrystals. Unique features of the Boudouard reaction coupled with CO-driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene-catalyst composite production. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/9710 | |
dc.identifier.uri | https://doi.org/10.34657/8748 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/advs.202200217 | |
dc.relation.essn | 2198-3844 | |
dc.relation.ispartofseries | Advanced science 9 (2022), Nr. 12 | eng |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject | Boudouard reaction | eng |
dc.subject | carbon monoxide | eng |
dc.subject | chemical vapor deposition | eng |
dc.subject | copper | eng |
dc.subject | graphene | eng |
dc.subject.ddc | 500 | eng |
dc.subject.ddc | 600 | eng |
dc.subject.ddc | 624 | eng |
dc.title | High-Quality Graphene Using Boudouard Reaction | eng |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | Advanced science | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | IFWD | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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