Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters

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dc.bibliographicCitation.firstPage7531
dc.bibliographicCitation.issue26
dc.bibliographicCitation.journalTitleAngewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International editioneng
dc.bibliographicCitation.lastPage7534
dc.bibliographicCitation.volume56
dc.contributor.authorvan Putten, Robbert
dc.contributor.authorUslamin, Evgeny A.
dc.contributor.authorGarbe, Marcel
dc.contributor.authorLiu, Chong
dc.contributor.authorGonzalez-de-Castro, Angela
dc.contributor.authorLutz, Martin
dc.contributor.authorJunge, Kathrin
dc.contributor.authorHensen, Emiel J. M.
dc.contributor.authorBeller, Matthias
dc.contributor.authorLefort, Laurent
dc.contributor.authorPidko, Evgeny A.
dc.date.accessioned2023-01-19T09:43:50Z
dc.date.available2023-01-19T09:43:50Z
dc.date.issued2017-4-21
dc.description.abstractCatalytic hydrogenation of carboxylic acid esters is essential for the green production of pharmaceuticals, fragrances, and fine chemicals. Herein, we report the efficient hydrogenation of esters with manganese catalysts based on simple bidentate aminophosphine ligands. Monoligated Mn PN complexes are particularly active for the conversion of esters into the corresponding alcohols at Mn concentrations as low as 0.2 mol % in the presence of sub-stoichiometric amounts of KOtBu base.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/10925
dc.identifier.urihttp://dx.doi.org/10.34657/9951
dc.language.isoeng
dc.publisherWeinheim : Wiley-VCH
dc.relation.doihttps://doi.org/10.1002/anie.201701365
dc.relation.essn1521-3773
dc.relation.issn1433-7851
dc.rights.licenseCC BY-NC 4.0 Unported
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.subject.ddc540
dc.subject.otheralcoholseng
dc.subject.otheresterseng
dc.subject.otherhomogeneous catalysiseng
dc.subject.otherhydrogenationeng
dc.subject.othermanganeseeng
dc.titleNon-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esterseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKAT
wgl.subjectChemieger
wgl.typeZeitschriftenartikelger
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